_______6. Aldehydes
_______7. Ketones
_______8. Organic acids
_______9. Amine
______10. Amide
_______6. Naphthalene
_______7. Anthracene
_______8. Phenanthrene
_______9. O-cresol
_______10. Nitrobenzene
+
+
Cu
CO2
CO2
H2
H2O
H2O
C.
How many ml of a 12 N HCl solution is needed to neutralize 100 ml of a 1.2M Ba (OH) 2 solution?
a. RCOOR
b. solutions of metallic oxides
c. ROR
d. methanol
e. alkyl-aryl sulfonate
f. substances that keep pH constant
g. same atomic mass different atomic number
h. molecular modifications
i. chemically different but the same atomic mass
j. Extraction of solids from solution by diffusion through membrane
k. RCHO
l. RCOOH
a. wine
b. soap
c. paper making
d. paint
e. coconut oil
f. baking
g. mining / metallurgy
h. alcohol
i. Powder detergent
j. caustic/ chloride
k. glass making
l. flour milling
m. pulp making
n. fertilizer
________6. Chloroform
________2. Urea
________3. Ethanol
________4. Glucose
________5. Methane
In the analysis of a feldspar sample weighing 0.42g mixture of KCl and NaCl is obtained which was found to weigh 0.072g. The same
feldspar was found to contain 0.16g K2PtCl6. Calculate the Na2O in the feldspar.
50. Board Problem, May 1983
A sample weighing 0.6234g that might contain a mixture of NaOH + Na 2CO3 or Na2CO3 + NaHCO3 is titrated with 0.1062M HCl by the two
indicator method. With phenolphthalein end point, 40.38ml of acid was used. The titration is continued after adding methyl orange, and an additional
12.38ml of acid was used.
a. Identify the mixture of bases in the sample
b. Calculate the % of each base in the sample
51. Board Problem, May 1984
A sample of impure magnetite (Fe 3O4) weighing 0.5g was converted by chemical reaction to Fe 2O3. The iron oxide, Fe 2O3, was found to weigh
0.41g. Determine the % Fe3O4 n the magnetite.
52. Board Problem, May 1984
A sample containing only ferric oxide (Fe 2O3) and aluminum oxide (Al2O3) weighs 10g. This sample is heated with sufficient amount of
hydrogen gas to reduce all the iron oxide to elemental iron. The aluminum oxide remained unaffected in the process and the dry sample was found to
weigh 8.58g. Calculate the % Al in the original sample.
Sn
A fuel furnishes 7,000cal of heat per gram. Calculate the maximum work which can be obtained from in this engine which operates with the
water between its boiling point and 40oC.
74. Board Problem, October 1980
Calculate the difference between the heat of combustion of methane at constant pressure and at constant volume at 27 oC when liquid water
forms.
75. Board Problem, May 1980
a. Calculate the energy generated by an electric current of 10A across a voltage of 10V for 10hr, in calories.
b. If this energy is used to heat water, how many grams of water can be heated from 20 oC and 100oC.
76, Board Problem, May 1982
Calculate the change in entropy in entropy units when 100g of ice at 0 oC is converted to steam at 100oC and 1atm.
77. Board Problem, November 1982
The integral heat of solution of MgCl 2 (s) at 18oC is 35,900 cal and that of MgCl 26H2O is -2,950 cal. The heat of vaporization of water is 587
cal/g. Find H at 18oC for the reaction.
78. Board Problem, May 1984
The vapor pressure of acetic acid at 90 oC is 293mmHg and 417mmHg at 100 oC. Assuming the latent heat of vaporization of acetic acid is
given within the given temperature range, calculate:
a. Molar latent heat of vaporization
b. Normal boiling point of acetic acid
79. Board Problem, May 1984
Calculate the degree of dissociation of SO3 at 600oK and 0.5 atm. At 600oK: G= 19,759cal and H= 46,980cal. SO3 (g)
+
O2 (g)
SO2
(g)
b. How many MT of limestone (53% CaO) per month does this represent?
c. Give the analysis of the cement if the clinker analysis is as follows:
CaO= 61.92%, Fe2O3= 6.24%, SiO2= 20.64%, Al2O3= 7.2%
87. Board Problem, April 1979
A fertilizer plant produces 120,000 MT of 10-6-10 fertilizer annually from ammonium sulfate (20%N), diammonium phosphate (18%N, 46%
P2O5), potassium chloride (60% K2O) and gypsum as filler. How much of the materials above are used by the plant annually?
Note: A 10- 6- 10 contains: 10%N, 6%P as P2O5, and 10% potash as K2O.
88. Board Problem, May 1982
Oil and light solids are removed from 20,000 gal/hr of factory wastewater in a froth floatation plant. Treatment requires 0.04 ft 3 (STP) of air
per gallon of wastewater. Air is fed into the water at a depth of 10ft from the surface, at a pressure equal to the hydrostatic pressure of the water at the
point of entry. The air bubbles enter the water at an average diameter of 1mm. If water temperature is constant at 700 oFand barometric pressure is
29.7 inHg, calculate:
a. Air feed rate at STP
b. Average diameter of the air bubbles as they reach the water surface.
89. Board Problem, November 1983
The dilute sulfur dioxide by-product of the Leyte copper smelter is converted first into sulfuric acid to avoid pollution and get some added
values from the sulfur. The Philippine phosphate plant nearby will use the sulfuric acid to make ammonium sulfate and ammonium phosphate
fertilizers. Calculate the sulfuric acid production per day when the smelter is operating at 60% of its rated capacity (130,000 tons of copper per year
and the Philex concentrate has 40% total sulfur from copper and iron sulfides.).
90. Board Problem, May 1985
A cold process soap is made by mixing 340ml of 35 o Baume (25o) NaOH solution with 660ml coconut oil poured into molds and allowed to
stand and harden. Calculate:
a. % NaOH in 35o Baume NaOH solution.
b. % excess or shortage of NaOH used, if coconut oil has a saponification number of 260. MW= 205, Sp.gr.= 0.9.
Chemical Engineering Calculations II
91. Board Problem, January 1974
A natural gas is known to be composed only of methane, ethane and nitrogen. The volume% of nitrogen is 20% when burned. The Orsat
analysis of the flue gas shows 7.8% CO2, 7.4% O2, and 84.8%N2. Determine:
a. Volume of methane and ethane.
b. % excess air.
92. Board Problem, April 1974
A furnace fires a fuel oil containing 82% carbon, 17% hydrogen and 1% Sulfur using 10% excess air. Assuming that the combustion of C to
CO2 is only 90% complete and that all the sulfur is burned to SO2, calculate the complete analysis of the wet flue gas.
93. Board Problem, October 1978
A rotary drier burns a fuel with dry air at 40 oF and 30.1 inHg. The oil contains only carbon and hydrogen. Analysis of the flue gas shows
12.9% CO2, 3.8% O2 and 83.3%N2. Calculate:
a. % excess air
d. ft3 flue gas (40oF and 30.1 inHg) per lb oil
b. Weight % of carbon in oil
e. Partial pressure of water vapor in the stack gas
c. ft3 air/lb oil
94. Board Problem, October 1979
A furnace coal uses coal which analyzes 70.4%C, 4.8%H 2, 9.4%ash, 11.8%O2, and negligible N and S. If the furnace is fired with 50% excess
air, calculate the flue gas analysis assuming complete combustion.
95. Board Problem, May 1980
Calculate the % heating value lost in the refuse for this certain type of coal (negligible N and S) with a heating value of 14,000 BTU/lb.
Proximate Analysis
Proximate Analysis of Refuse
4.7% moisture
28% FC
24.3% VCM
7% VCM
9.6% Ash
65% Ash
61.4% FC
96. Board Problem, May 1981
A low grade coal with heating value of 11,000 BTU/lb is used to fire a boiler at the rate of 600 lb/hr. With the following analysis presented.
a. Calculate % heating value lost in the refuse
b. Having a heat transfer efficiency of 60%, calculate the 1,150 BTU/lb steam produced/ hr.
Proximate Analysis
Proximate Analysis of refuse
10% Ash
19% FC
30% VCM
10% VCM
57% FC
50% ash
V (m3)
The total heat added to the system is 500J, the change in enthalpy of the system is
a. -100J
b. 300J
c. 500J
d. 1100J
Answer:
3.
a. 54%, b. 3, c. 20ml
4.
Na2B4O7
16.
KNO2
17.
Limestone= 144.68 tons, soda ash= 135.2 tons
18.
NaCl= 110.38 tons/day, CaCO3= 94.3 tons/day
19.
51.93 li
20.
V= 27,623 li
21.
Limestone= 31.25 MT, soda ash= 38.75 MT, lime= 32.41 MT
22.
Ammonium sulfate= 893.3MT, Phosphoric acid= 435.9MT, Muriate of potash= 800.9MT, gypsum=869.9MT.
23.
97.0%
24.
a. 7.826kg, b. 434.78 mole, c. 171.9 ft3, d. 4,347.8 li
25.
a. 53.45kg, b. 26.93kg, c. 13.71 li
26.
a. 54.66, b. 4.13
27.
Alcohol= 538 kg, gas= 2.88 x 105 li
28.
a. 155.75%, b. 90.69%
29.
a. 23.77 mmHg, b. 100.038oC, c. -0.136oC, d. 1.79 atm
30.
a. 23.75 mmHg, b. 100.015oC, c. -0.055oC, d. 0.736 atm
31.
155.68 g/mol
32.
28% ethyl alcohol
33.
46,116 g/mol
34.
a. 0.393M, b. 0.786N, c. 7.04 x 10-3
35.
93.33 g/mol
36.
0.0293M
37.
29.69 atm
38.
15.6%
39.
a. 0.103, b. 81.32%, 9.34%, 9.34%
40.
3.7
41.
a. 0.00478M, b. 4.78%, c. 2.32
42.
670 li
43.
a. 17.5 ml, b. 0.001855
44.
b. acidic, c. 36.5g HCl
45.
42.49%
46.
a. 2V1/ (V1+V2), b. 91.85%
47.
a. M=N=0.5, b. 12.25g
48.
a. 10.97% wt, b. 98.98%
49.
2.90%
50.
a. NaOH and Na2CO3, b. 18.77%NaOH and 23.16% Na2CO3
51.
79.26%
52.
27.90%
53.
a. basic, b. 17.1 ml
54.
a. Eo cell= 0.403V, b. Eo O2= 0.403V
55.
a. 0.0508li, b. 8.04hr
56.
b.Fo= 85,291 cal, c. no
57.
tK+= 0.487; tCl-= 0.513
58.
1.7 x 10-10
59.
23.33 mmHg, 0.018
60.
a. 39.36g/mol, b. 48,617 cm/s, c. 16,899g
61.
a. 146m3, b. 1.51 x 103g/ml
62.
1,257.44 cal
63.
1.397 li
64.
25.99 g/mol; ethyne
65.
29.94%
66.
67.
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
98.
100.
101.
102.
64.14 g/mol
90.46 g/mol
a. CH3, b. 29.97, c. C2H6, d. ethene; paraffin
a. 6.78 x 1012, b. 677,614, c. 161,954, d. 6,688, and e. 11.37oF
478.13oK
1,216 fps
-11,800 cal
1,126cal/g
-1,192 cal
a. 360,400cal, b. 11,472g
205.28 eu
24,546 cal
a. 9,494.72cal/mol, b. 118.34oC
6.33 x 10-3
COP= 4.27; Q= 3.33 x 106 cal/hr
a. 89.75, b. 0.1938 lb/min
14.1/g ammonia
338.54kg
1,782.53 Handbook/ 1,853.6 Steam table
a. 39.69 lb, b. 136.11
a. 75,000, b. 87,623, c. 63.76%CaO, 20.81%SiO2, 6.29%Fe2O3, 7.26%Al2O3, SO3
Ammonium sulfate= 45,913, diammonium phosphate= 15,652, KCl= 20,000
a. 800 ft3/hr; 22.67 m3/hr, b. 1.09mm
964.20
a. 29%, b. 18% xs
a. 57.24%, b. 50.2%
O2 sg= 1.45 mol, H2O= 8.5 mol
a. 20.72%, b. 87.68%, c. 216.57, d. 227.3, e. 2.95 inHg
CO2= 5.87 lbmol; H2O= 2.4 lbmol
5.92%
a. 6.67%, b. 3,214 lb
c. 7.22 MT
a. 23.3%, b. 4.54%
a. 27,000, b. 10,864.41, c. 21,559.32
11.01
CO2= 2 mol; O2 sg= 0.6 mol