Engineering
Instructor for KAEA3152 :
Dr. Nuruol Syuhadaa Mohd
n_syuhadaa@um.edu.my
Phone: 03-79677650
Office: Block F
Class time & location:
Lecture Days: W Time: 9am 10am
ThTime: 9am 11am
Venue: BK202
Venue: BK201
ASSESSMENT
Assignments
Lab Classes
Test
Final
10%
10%
20% (Date: TBD)
60% (Date: TBD)
Pollution
Can be defined as an undesirable change in the physical, chemical or
biological
characteristics of the air, water and land that can harmfully affect the
health,
survival or activities of humans or other living organisms
The American Heritage dictionary defines environment as:
The act or process of polluting or being polluted, especially the contamination
of soil, water, or the atmosphere by the discharge of harmful substances.
Slide No. 2
Water-Air-Land Interactions
Definitions
Environmental engineering
Abatement Processes
Definitions
Environment
Environmentalism
Environmental science
is an
interdisciplinary
field, drawing on
many diverse
disciplines.
Figure 1.6
Ecosystem Components
Limiting factors determines distributions
11
Producers (autotrophs)
Consumers (heterotrophs)
Herbivores, carnivores,
omnivores
Decomposers and
detritivores
detritus = dead
organic material
12
13
Atmosphere
Thin membrane of air
Troposphere
11 miles
Stratosphere
12-30 miles
Lower portion (ozone)
filters out harmful sun
rays
Allows life to exist on
earth
Lithosphere
Earths crust
Hydrosphere
water
Biosphere
Living and dead
organisms
14
Pollution
Point source
Single identifiable source that discharges pollutants into the
environment. ( smoke stack, exhaust pipes, industrial discharge)
Non-point source
Large or dispersed land areas such as crop fields, streets, and lawns
that discharge pollutants into the environment over a large area.
(stormwater, septic tanks)
15
Environmental Problems
16
17
18
19
http://www.sei.ie/uploadedfiles/Education/Unit2_2C_speed_boats1
http://www.greenscreen.org/articles_sr/energy/images_potential_kinetic_energy/potential_kinetic.jpg
http://www.citruscollege.edu/pic/46/c05_05.jpg
Basic Vocabulary
Matter: Anything that has mass and volume
Mass: Amount of matter in an object
More Vocabulary
Atoms: Smallest particle of an element that has all the
properties of matter:
Protons- particles in the nucleus with positive charge
Electrons- particles orbiting around nucleus with negative charge
Neutrons- particles in the nucleus with no charge
Sub-Atomic Particles
Part of
Atom
Charge
Location
Electron
- negative
outside
nucleus
Proton
+ positive
inside nucleus
Neutron
no charge
inside nucleus
Periodic Table
Atomic Number
Equal to # protons = # electrons
Periodic Table is arranged by this number
Cl
35.5
Symbol
Shorthand for the element Note 2nd letter is
always lowercase
Shell #1
Shell #2
Shell #3
Shell #4
Shell #5
Shell #6
2 electrons
8 electrons
8 electrons
18 electrons
32 electrons
50 electrons
Atomic Structure
Total # of protons and electrons (in a neutral atom)
17 protons in nucleus
17 electrons orbiting nucleus
17
Cl
Element Name
Chlorine
35.5
Chemical Reactions
H2 + O2 --> H2O
Reactants
Products
Chemical Equations
Concise representations of chemical
reactions
Using Moles
2 MgO
IS NOT
2 grams Mg + 1 gram O2 makes 2 g MgO
Types of Reactions
Romance Chemistry :)
SynthesisA + B = AB
DecompositionAB= A + B
Single-ReplacementA + BC = AC + B
Double-ReplacementAB + CD = AC + BD
Combination Reactions
Two or more
substances
react to form
one product
Examples:
N2 (g) + 3 H2 (g) 2 NH3 (g)
C3H6 (g) + Br2 (l) C3H6Br2 (l)
2 Mg (s) + O2 (g) 2 MgO (s)
Decomposition Reactions
One substance breaks
down into two or more
substances
Examples:
CaCO3 (s) CaO (s) + CO2 (g)
2 KClO3 (s) 2 KCl (s) + O2 (g)
2 NaN3 (s) 2 Na (s) + 3 N2 (g)
Combustion Reactions
Rapid reactions that
produce a flame
Most often involve
hydrocarbons
reacting with oxygen
in the air
Examples:
CH4 (g) + 2 O2 (g) CO2 (g) + 2 H2O (g)
C3H8 (g) + 5 O2 (g) 3 CO2 (g) + 4 H2O (g)
Cartoon Chemistry
Cartoon Chemistry
Cartoon Chemistry
Conservation of Mass
Atoms cannot be created or destroyed in a
chemical reaction.
What goes in must come out.
So we must balance equations to
conserve mass.
Balancing Equations
Rules:
We can not add or subtract subscripts from either side
of the equation
We can only add coefficients to the front of each
compound
Ex. 2H2 + O2 --> 2H2O
H=4
O=2
Before
H=4
O=2
must match
After
CO2 + H2O
NOT
C4H12
3.7
2 carbon
on left
C2H6 + O2
6 hydrogen
on left
C2H6 + O2
CO2 + H2O
1 carbon
on right
multiply CO2 by 2
2CO2 + H2O
2 hydrogen
on right
multiply H2O by 3
2CO2 + 3H2O
3.7
2 oxygen
on left
2CO2 + 3H2O
4 oxygen
(2x2)
+ 3 oxygen
(3x1)
7
O
2 2
2CO2 + 3H2O
2C2H6 + 7O2
4CO2 + 6H2O
C2H6 +
multiply O2 by
7
2
= 7 oxygen
on right
remove fraction
multiply both sides by 2
3.7
4CO2 + 6H2O
4 C (2 x 2)
4C
12 H (2 x 6)
12 H (6 x 2)
14 O (7 x 2)
14 O (4 x 2 + 6)
Reactants
Products
4C
4C
12 H
12 H
14 O
14 O
3.7
Stoichiometric Calculations
From the mass of
Substance A you can
use the ratio of the
coefficients of A and
B to calculate the
mass of Substance B
formed (if its a
product) or used (if
its a reactant)
Given
5.17 g Fe(C5H5)2
Goal
units match
mol
185.97 g
= 0.0278
moles Fe(C5H5)2
Fe(C5H5)2
2 x 5 x 1.001 = 10.01
2 x 5 x 12.011 = 120.11
1 x 55.85 = 55.85
185.97 g
mol
2 moles of HCl react with 1 mole of Ba(OH)2 to form 2 moles of H2O and
1 mole of BaCl2
= 8.6
2mol N 2O 5
moles NO2
1mol O 2
2mol N 2O 5
? mol
= 2.2
60
mole O2
210 g NO2
mol NO 2
46.0g NO 2
Units match
2mol N 2O 5
4mol NO 2
= 2.28
moles N2O5
b. How many grams of N2O5 are needed to produce 75.0 grams of O2?
2N2O5(g) 4NO2(g) + O2(g)
75.0 g
? grams
75.0
g O2 mol O 2
32.0 g O 2
2mol N 2O 5
1mol O 2
108g N 2O 5
mol N 2O 5
506
grams N2O5
2 Al(s) + 6HCl(aq)
AlCl
2 3(aq) +
H23(g)
3 H2(g)
3 H2(g)
Units match
3.45 g Al
mol Al
27.0 g Al
Letsmust
We
Now
use
workthe
always
themolar
problem.
convert
ratio. to
mass
to moles.
convert
to grams.
17.0 g AlCl3
Limiting
Reactants
Limiting Reactants
The limiting reactant
is the reactant
present in the
smallest
stoichiometric
amount
Limiting Reactants
The limiting reactant is the reactant present in
the smallest stoichiometric amount
In other words, its the reactant youll run out of first (in
this case, the H2)
Limiting Reactants
In the example below, the O2 would be the
excess reagent
Solution Chemistry
Mixtures: Matter that consists of two or more substances mixed
but not chemically combined
Solutions: Homogeneous Mixture in which one substance is
dissolved into another
Solute = Substance that gets dissolved (ex. Kool-Aid powder)
Solvent = Substance that does the dissolving (ex. Water)