9. a. 2.03g, 2.03 eq, 4.06M, 4.06N 10. a. 320g b. 20.0 g, 0.500 mol, 5000 cm}, 0.100N b. 100g ¢. 261g, 3.00 eq, 3000 cm, 0.500M ce. 720g d. 148g, 1.00 mol, 1.33M, 2.67N AL. a. 25.0% e. 49.0g, 1.50eq, 250 cm}, 6.00N b. 9.09% f. 0.143 mol, 0.858 eq, 143 cm3, 1.00M. c. 20.0% 12, a 146g 13. 26.7, 0.435M 16. 6.02 x 103 molecules b. 102g 14. 7.67M 46.1 g, 58.4 cm3 ec. 180g 15. 4.59 mol, 9.17M Chapter 17 1. a, right e. right i. right m. left b. left £ left j. left n. no change ec. left & . Tight o. right no change p. left d. no change h. 6. = 0.0668M 9, HW, = 1, = 0.228M 2. 217 3. 0.0313M 0.0260M HI 4M 4. H,=0.0400M 7. H, = 0.015M 10. PCI, = 0.0295M I, = 0.0400M I, = 0.215M Cl, = 0.0295M HI =0.320M —_ HI = 0.370M PCl, = 0.0205M 5. 6.61 8. one half the original Chapter 18 1. 400cm3? 6. 0.400M ec. 436cm3 d. 33.3cm3 2 6.25cem3 7. 282cm3 d. 681cm3 e. 8.33cm3 3. 800dm3 8 293M e. 1130cm3 4. 0.800N 9% a 330cm3 10. a. 25.0cm3 5. 0.300M b. 1110 cm? b. 12.5cm3 ce. 16.7cm3 Chapter 19 1. a 200m d. 130m 2 a 252g d. 183g b. 240m e. O11 toe oO ee ce 167m £. 133m c 90g 4 6.77 x 103 5. 620g, 6.02 x 10% molecules 9. 80.7g 6. 17.8% 10. a. —3.72°C, 101.02°C 7. —3.72°C, 101.02°C b. —3.71°C, 101.02°C ee ee ore ae eae A 11, 1980g, 1770mL 12, 180g/mol, CH,,0, 13. 460g 14 46.08 15. a 731g 16. a 250g 17, a. 3.94% 18. a. 1.00m b. 146¢ b. 500g b. 4.08% b. 0.80m ar rs ce. 1000 cc. 5.06% c. 1.09 d. 293g 27219, —2.49°C, 84.1°C 23. 110 g/mol 20. 285°C, 189°C 24. 43.5 ¢/mol 21. 160g 25. 138 g/mol, CsH,,0, 22, 255g 26. 218g/mol, CygH,N2O, Chapter 20. 1. a, 2Na + 2H,0 > 2Nat +H, + 20H- b. 6H* + 2P0,- + 3Mg* + 6OH- —> Mg,(PO,), + 6H,0 c. Ba + SO,’ > BaSO, d. 3Mg?+ + 6OH- + 6NH,* + 2P0,> > Mg,(PO,), + 3NH, + 6H,0 e. 2Fe}+ + 3S — Fe,S; g. 2Al + 3Cutt > 2A} + 3Cu f. CO, + 2Ht > CO, + H,0 h. no reaction 2 a 16xX10°S 3, HOt =0.0042M 4. 0.42% b. 1.7.x 10-5 C,H,0,- = 0.00822M 5. a. 7.90 x 10-4 c._ 6.16 x 1071 HCHO. = 10M b. 1.80 x 10-5 SoM 8, a, 254% 10M ce. 1.85 x 10-5 7. 0.035M b. 2.24 x 10°3M d. 6.05 x 10-1 Chapter 24 1. a pH4,pOH 10 -b. 1x 10-°M 4 a pH 11.4, pOH 2.6 b. pH 12,pOH2 © 1X 102M — b. pH 2.30, pOH 11.70 c. pH9,pOH5 3. a 1x 107M c. pH 0.82, pOH 13.18 d. pH2,pOH 12 b. 1x 107M —d._ pH 1.32, pOH 12.68 2 a 1x 103M ee ee ee f._pH 10.2, pOH 38 5. a. H,o* = 3162 x 10M d.H,0* = 1.995 x 105M 3.162 x 10-2M OH- = 5.013 x 10M b. 6.329 x 10-°M e. H,O+ = 2512 x 107M 1.580 x 107M OH- = 3.981 x 10°5M c 1.585 x 10-4M f. H,O* = 1.995 x 104M OH- = 6.310 x 104M OH™ = 5.012 x 10-7" poH H,0+ OH- So lt 6 a 12 16x10M = 6.3.x 10°M ee b. 105 32X10"M = 3.2 x 10-"M = 30 G78 Gs 10M 16 x 10M a. 174 a. 5.5 3.2x10°M —-3.2 x 10°SM e 5.62 e 110 10x 10M 1.0 x 10-IM oe £ 98 63x10m 16x % a 44x 10% g 62 16x 10M = 6.3 x 10-7 : ee oH 4 1 he 35 32K 10MM 3.2 x 10-4 Cleo 2737. poH H,0+ OH- a. 13.00 1.00 x 10"'M 1.00 x 10-3 b. 11.10 1.26 x 10-3M 7.94 x 10-?M ce 2.90 7.9 x 10-?M 13 x 103M d. 12.80 6.31 x 10°°M 1.58 x 10-3M e 5.60 3.98 x 10-°M 2.51 x 10-°M 1.00 1.0 x 10°3M 1.00 x 10-'M f£. Chapter 22 1 a. 0.300M 2. 240M b. 20.0mL c. 3.60% b. 15.0mL 3, 21.41mL ec. 880mL 7 6.82 grams ec 250M 4. 2.92 grams d. 54.0mL 8 7.21mL d._17.5mL 5._a._6.00mL 6, a 201M 9. 0.600NH,PO, 10. a. 0.880N, 0.930N, 0.908N b. 34.2 g/L 0.200M HPO, b. 52.9 g/L, 55.9 g/L, 54.6g/L I. a. O.171M d. 0.333M 5.29%, 5.59%, 5.46% b. 41.2mL e. 12.5mL d. Trial 3, 1.11% error ec. 30.0mL f. 180M 12. 1.28 grams 16. 0.980N c. 1.49 grams 13. 333mL 17. 20.3mL 19. 0.76 g/L 14. 12.0mL 18, a. 0.213 grams 20. 9.80mL 15. 0.667N, 0.333M b. 140mL Chapter 23 1, a. 1.50 x 10-16 d. 153x 10-7 13, a. 3.98 x 107° b. 4.90 x 10-9 e 5.27 x 10-4 b. 354M ce 414 x 1071 f. 1.00 x 10-25 ec. 1.03 x 10-6M d. 296 10-16 7 a 2.51 x 10-'7M 14, a. no, 2.50 x 10-7 e. 3.63 x 10-9 b. 1.08 x 10-5 b. yes, 2.25 x 107!! Ee 2.82 10d ce. 5.83 x 10-°M eno, 1.08 x 10-3° 2 a 2.51 x 10-18 d. 149x 10°°M 15. 1.15 x 10-°M b. 3.97 10-4*M 8 a 891 x 104M 16. 2.95 x 10-3 g/200mL ce 2.61 x 10°M b. 1.17 103M 17. yes d. 1.61 x 103M ec. 3.07x 10-7M 18. 3.83 grams 3. a. 1.35 x 105M d. 2.14 10-°M 19. 2.10 x 10-!! g/mL b. 1.81 x 10°°M e. 1.00 x 10-'M 20. yes, ion product ec. 1.81 x 10-°M f. 6.91 x 10-7 = 417 x 10-7 4 a LAL x 10°M g. 144x 10-*M 21. 7.94 x 10-§M b. 5.50 10-*M 9, a. 3.94 x 10-2mg/100mL ec. 5.50 x 10-7M b. 1.72 x 10-3 mg/100 mL d. 3.71 x 10°3M c. 2.10 x 10-6 mg/100 mL 5. a. 6.54 x 10-5M d. 41.1mg/100mL 22. AgCl b. 7.00 x 10-1°M e. 0.227mg/100mL 23. 5.4 x 10-5M, c, 1.06 x 10-°M f. 3.34mg/100mL 0.054% 6. a 1.07% 10-5! 10, Agl b. 443 x 10-77 11. PbSO, 9 4.57 x 10-8 12, yes, PbCO, 274