FEED

Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Flow

6000

mol%
0.24
0.46
0.2
0.08
0.02
1.00
kmolh-1

kmol
1440
2760
1200
480
120
6000

DIRECT SEQUENCE

0.6369

FEED

FEED
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Flow

6000

mol%
0.24
0.46
0.2
0.08
0.02
1.00
kmolh-1

10
ba
r
kmol
1440
2760
1200
480
120
6000

BOTTOMS
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Flow

4428

mol%
0.0033
0.592
0.2692
0.1084
0.0271
1.00
kmolh-1

kmol
14.6124
2621.376
1192.0176
479.9952
119.9988
4428

Product 1
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Product 1
Methane

Flow

1572

mol%
0.907
0.088
0.005
0.000
0.000
1.00

kmol
1425.804
138.336
7.86
0
0
1572

(99% Rec)
(~5% Rec)

kmolh-1

Product 2
Ethylene
6000
Product 2
Methane
Ethylene
Ethane
Propylene
Propane

10
bar

6001

Flow

Product 3
Ethane
Product 3
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Flow

1788

Keys
Light

CH4

0.0033

(1% of Initial for >= 99% Recovery)

Heavy

C2H4

0.088

(>= ~5% Recovery)

Product 2
CH4
C2H4
C2H6
C3H6
C3H8

mol%
0.0055
0.9895
0.005
0
0
1.00

kmol
14.5255
2613.2695
13.205
0
0
2641

2641

kmolh-1

mol%
0
0.005
0.6594
0.2685
0.0671
1.00

kmol
0
8.94
1179.0072
480.078
119.9748
1788

kmolh-1

Keys
Light

C2H4

0.005

Heavy

C2H6

0.005

INDIRECT SEQUENCE

TOPS
Methane
Ethylene
Ethane
Propylene
Propane

CH4
C2H4
C2H6
C3H6
C3H8

Flow

4307

FEED

FEED
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

Flow

6000

mol%
0.24
0.46
0.2
0.08
0.02

kmol
1440
2760
1200
480
120

1.00

6000

kmolh-1

Cooling Duty (MJ/h)

Heating Duty (MJ/h)
Min. Reflux Ratio
External Reflux Ratio

Direct
Column 1
Column 2
-12260
-101800
17020
103400
0.578
2.299
0.637
2.519

Methane
Ethylene
Ethane
Propylene
Propane

CH4
C2H4
C2H6
C3H6
C3H8
Total

mol%
0.3344
0.6378
0.0278
0
0
1.00

Product 1
Methane

kmol
1440.2608
2747.0046
119.7346
0
0
4307

Product 1
Methane
Ethylene

kmolh-1

Ethane
Propylene
Propane

10
ba
r

Flow

Keys

10
ba
r

Light

C2H4

0.00769923

Heavy

C2H6

0.0278

Product 2
Ethylene

6000

Product 3
Ethane
6000

Product 3
Methane
Ethylene
Ethane
Propylene
Propane

CH4
C2H4
C2H6
C3H6
C3H8

mol%
0
0.0077
0.638
0.2835
0.0709
1.00

Flow

1693

kmolh-1

kmol
0
13.0361
1080.134
479.9655
120.0337
1693.1693

Indirect
Column 1 Column 2
-59370
-40570
96780
9335
1.093
2.023
1.202
2.225

Feed
mol%
0.24
0.46
0.20
0.08
0.02
1.00

kmol
1440.00
2760.00
1200.00
480.00
120.00
6000

Distillate
mol%
0.33
0.64
0.03
0.00
0.00
1.00

kmol
1440.26
2747.00
119.73
0.00
0.00
4307

Product 1
mol%
0.91
0.09
0.00
0.00
0.00
1.00

kmol
1426.34
137.72
0.94
0.00
0.00
1565

Product 2
mol%
0.005
0.952
0.043
0.00
0.00
1.00

kmol
13.71
2609.5614
118.7286
0.00
0.00
2742

Product 1
Methane

Product 1
CH4
C2H4

mol%
0.911
0.088

kmol
1426.341
137.72

C2H6
C3H6
C3H8

0.001
0.000
0.000
1.00

0.939
0
0
1565

1565

kmolh-1

Keys

(99% Rec)
(~5% Rec)

Product
Methane
Ethylene
Ethane
Propylene
Propane

Flow

Light
Heavy

2
CH4
C2H4
C2H6
C3H6
C3H8

mol%
0.005
0.952
0.043
0
0
1.00

2742

kmolh-1

kmol
13.71
2609.5614
118.7286
0
0
2742

Product 3
mol%
0.00
0.01
0.64
0.28
0.07
1.00

kmol
0.00
13.04
1080.13
479.97
120.03
1693

Keys
CH4
C2H4

0.005
(1% of Initial for >= 99% Recovery)
0.088

(>= ~5% Recovery)

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

DU 1
12.26
-101.9
17.02
-43.43
0.578
0.637

Indirect
DU 2
101.8
-52.93
103.4
-20.37
2.299
2.519

DU 1
59
-62.92
97
-19.68
1.093
1.202

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Reflux Ratio

DU 1
12.26
-101.9
17.02
-43.43

DU 2
41
-103.4
9
-52.31
2.023
2.225

Indirect
DU 2
101.8
-52.93
103.4
-20.37

DU 1
59
-62.92
97
-19.68

DU 2
41
-103.4
9
-52.31

Wideal = Qc(Th-Tc/Tc)
Wactual = Wideal/n
COP = Qcool/W
comp n = 0.85
dTmin = 5

Direct
Condenser Duty (GJ/h)

DU 1
12.26

Indirect
DU 2
101.8

DU 1
59

DU 2
41

Condenser Temperature (C)

Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)

-101.9
-106.9
166.1
308
10.47
17.46

-52.93
-57.93
215.07
308
43.99
73.31
90.77

-62.92
-103.4
-67.92
-108.4
205.08
164.6
308
308
29.80
35.34
49.66
58.91
108.57

10 bar 5 bar

comp. 15 bar 15 bar

Condenser Duty (GJ/h)

Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

comp. 20 bar 20 bar

Condenser Duty (GJ/h)

Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

10 bar 5 bar

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

DU 1
10.59
-113.4
7.93
-64.1
0.578
0.637

DU 2
99.77
-72.3
93.91
-42.9
1.937
2.131

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)

comp. 15 bar 15 bar 15 bar

DU 1
10.59
-113.4
-118.4
154.6
308
10.51
17.52

DU 2
99.77
-72.3
-77.28
195.72
308
57.23
95.39
112.91

Indirect
DU 1
64.75
-79.8
97.43
-42.3
0.919
1.011

Indirect
DU 1
64.75
-79.8
-84.8
188.18
308
41.23
68.72
127.63

Direct
DU 1
11.84
-94.4
20.90
-29.3
0.621
0.683

Indirect
DU 2
99.77
-39.9
93.91
-5.0
2.782
3.060

DU 1
64.67
-51.7
104.03
-4.3
1.291
1.420

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)
Wfeed (GJ/h)

DU 1
11.84
-94.4
-99.43
173.57
308
9.17
15.29

DU 2
99.77
-39.9
-44.9
228.1
308
34.95
58.24
1.10
74.63

DU 2
36.59
-95.8
7.86
-39.2
2.146
2.361

Indirect
DU 1
64.67
-51.7
-56.7
216.28
308
27.42
45.71
1.10
94.90

comp. 20 bar 20 bar 20 bar

Direct
DU 1
11.89
-88.7
24.77
-18.3
0.694
0.763

DU 2
111.19
-29.8
113.04
7.0
3.297
3.627

Indirect
DU 1
68.85
-43.2
109.81
7.8
1.493
1.642

DU 2
37.19
-90.0
10.83
-29.1
2.286
2.515

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)
Wfeed (GJ/h)

DU 1
11.89
-88.7
-93.7
179.3
308
8.53
14.22

DU 2
111.19
-29.8
-34.75
238.25
308
32.55
54.25
1.76
70.24

Indirect
DU 1
68.85
-43.2
-48.2
224.83
308
25.47
42.45
1.76
89.46

DU1

Keys
Light

CH4

Heavy

C2H4

Indirect
DU 2
40.57
-103.4
9.34
-52.3
2.023
2.225

Keys

Indirect
DU 2
40.57
-103.4
-108.4
164.6
308
35.34
58.91
127.63

Light

C2H4

Heavy

C2H6

Indirect
DU 2
36.59
-95.8
-100.79
172.21
308
28.85
48.09
1.10
94.90

Indirect
DU 2
37.19
-90.0
-94.97
178.03
308
27.15
45.25
1.76
89.46

DU2

Keys

Keys
0.0033

Light

C2H4

0.005

0.088

Heavy

C2H6

0.005

Keys

Keys
0.007699

Light

CH4

0.005

0.0278

Heavy

C2H4

0.088

BASE CASE
Condenser Duty (GJ/h)
Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

Condenser Duty (GJ/h)

Condenser Temperature (C)
Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)

Direct
DU 1
DU 2
12.26
101.8
-101.9
-52.93
17.02
103.4
-43.43
-20.37
0.578
2.299
0.637
2.519

Indirect
DU 1
DU 2
59.4
41
-62.92
-103.4
96.8
9
-19.68
-52.31
1.093
2.023
1.202
2.225

Direct

Indirect
DU 1
DU 2
59
41
-62.92
-103.4
-67.92
-108.4
205.08
164.6
308
308
29.80
35.34
49.66
58.91
108.57

DU 1
DU 2
12.26
101.8
-101.9
-52.93
-106.9
-57.93
166.1
215.07
308
308
10.47
43.99
17.46
73.31
90.77

comp. 20 bar 20 bar 20 bar

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Reboiler Duty (GJ/h)
Reboiler Temperature (C)
Min. Reflux Ratio
External Reflux Ratio

DU 1
11.89
-88.7
24.77
-18.3
0.694
0.763

DU 2
111.19
-29.8
113.04
7.0
3.297
3.627

Direct
Condenser Duty (GJ/h)
Condenser Temperature (C)
Refigerant Temperature (C)
Heat Absorbed/Tc (K)
Heat Rejected/Th (K)
Wideal (GJ/h)
Wactual (GJ/h)
Wfeed (GJ/h)

DU 1
11.96
-84.0
-89.0
184
313
8.39
13.98

DU 2
114.97
-21.4
-26.36
246.64
313
30.93
51.56
2.20
67.73

Feed

1000 kPa

1.76

Comp. Feed

2000kPa

FEED
Methane
Ethylene
Ethane
Propylene
Propane

CH4
C2H4
C2H6
C3H6
C3H8

mol%
0.24
0.46
0.2
0.08
0.02
1.00

Heat Integration Feasibility - SINGLE CYCLE

Column 1
Cooling Water Return
Refigerant Condenser
Cooling Water

Cooling Water

Assuming n=0.6

Reject To Reboiler

Refigeration CondenserQ

DU1 QCooling
DU1 Cooling
Evaporator
Wideal/Q
Wactual
DU1 Qheating
DU1 Heating
Condenser
Wideal/Q
Wactual
Qcond

OK

Product 1
Methane
Ethylene
Ethane
Propylene
Propane

CH4
C2H4
C2H6
C3H6
C3H8

Product 1

GJ/h

From Rig:
Recovery Methane(Feed)

0.99

Recovery Ethylene(Feed)
FULL REFLUX
2000 kPa
From SH:
Min Trays
Actual Trays
Optimal Feed
From Rig:
Reflux Ratio
Feed Tray
No.Trays

kmol
1440
2760
1200
480
120
6000

0.05

4.31
13.07
3.50
0.826
4.00
14.00

Bottoms
SH Qreb
SH Treb
Rig Qreb
Rig Treb

Bottoms
Methane
CH4
Ethylene
C2H4
Ethane
C2H6
Propylene
C3H6
Propane
C3H8

24.77
-18.28
25.68
-18.27

mol%
3.25E-03
0.5919382611
0.2693613696
0.10836423
2.71E-02
1.00

kmol
14.4
2622.0
1193.1
480.0
120.0
4429.4937628

LE CYCLE

Column 1

Colu
308
313

K
K

Cooling Water Return

Refigerant Condenser
Cooling Water

11.96
189.0
184
0.701087
13.976972

GJ/h
K
K

28.42
264.0
269.0
0.4620652
9.2117999
21.17

GJ/h
K
K

Reject To Reboiler

GJ/h
GJ/h

Refigeration CondenserQ

GJ/h

Cooling Water

Assuming n=0.6

DU2 QCooling
DU2 Cooling
Evaporator
Wideal/Q
Wactual
DU2 Qheating
DU2 Heating
Condenser
Wideal/Q
Wactual
Qcond

Too Large Heat Rejection for Re

mol%
0.908
0.088
0.004
0
0
1.00

kmol
1425.626174
138.0131643
6.865493513
0
0
1570.506237

SH Qcond
SH Tcond
Rig Qcond
Rig Tcond

11.89
-88.7
12.81
-88.8

ooling Water Return

efigerant Condenser

Product 2

From Rig:
Recovery Ethylene (Botts)
TOTAL REFLUX
2000 kPa
From SH:
Min Trays
Actual Trays
Optimal Feed
From Rig:
Reflux Ratio
Feed Tray
No.Trays
From Rig:
Recovery Ethylene(Botts)

Product 3
SH Qreb
SH Treb
Rig Qreb
Rig Treb

113.04
7.01
121.22
5.022

Column 2
308
313

K
K

0.9698

28.27
69.32
30.48
4.110
31.00
70.00

0.9904

DU2 QCooling
DU2 Cooling
Evaporator
Wideal/Q
Wactual

114.97
251.6
246.64
0.26905611
51.5554564

GJ/h
K
K

DU2 Qheating
DU2 Heating
Condenser
Wideal/Q
Wactual
Qcond

116.94
289.9
294.9
0.19562926
37.4856958
152.46

GJ/h
K
K

rge Heat Rejection for Reboiler

GJ/h

GJ/h
GJ/h

Product
Methane
Ethylene
Ethane
Propylene
Propane

2
CH4
C2H4
C2H6
C3H6
C3H8

ETHYLENE SPEC

SH Qcond
SH Tcond
Rig Qcond
Rig Tcond

Product
Methane
Ethylene
Ethane
Propylene
Propane

mol%

kmol

0.006

14.37
2542.91
11.49

0.990
0.004
0
0
1.00

0
0
2568.77972

0.9698422

111.19
-29.75
119.53
-29.77

3
CH4
C2H4
C2H6
C3H6
C3H8

ETHANE SPEC

mol%
0
0.04
0.64
0.26
0.06
1.00

0.9903679

kmol
0
79.07
1181.64
480.00
120.00
1860.71404