DAFTAR ISI

HALAMAN JUDUL ..................................................................................................................i

LEMBAR PENGESAHAN ......................................................................................................ii
SURAT PERNYATAAN ........................................................................................................iii
KATA PENGANTAR .............................................................................................................iv
DAFTAR ISI .............................................................................................................................v
DAFTAR GAMBAR ...............................................................................................................vi
DAFTAR TABEL ...................................................................................................................vii
INTISARI ..............................................................................................................................viii
ABSTRACT .............................................................................................................................ix
BAB I PENDAHULUAN .........................................................................................................1
1.1
1.2
1.3
1.4
1.5
1.6
1.7

Latar Belakang ..............................................................................................................1

Tema Sentral Masalah ...................................................................................................2
Identifikasi Masalah ......................................................................................................3
Premis ............................................................................................................................4
Hipotesis ........................................................................................................................4
Tujuan Penelitian ...........................................................................................................4
Manfaat Penelitian .........................................................................................................5

BAB II TINJAUAN PUSTAKA ...............................................................................................6

2.1 Gas Alam .......................................................................................................................6
2.2 Gas Pengasam ...............................................................................................................6
2.2.1

Karbon Dioksida (CO2) .....................................................................................6

2.2.2

Hidrogen Sulfida (H2S) .....................................................................................7

2.3 Pemisahan CO2 dan H2S dari Gas Alam dengan Proses Absorpsi ................................8
2.3.1

Absorpsi dengan Pelarut Berbasis Amina .........................................................8

2.3.2

Absorpsi dengan Air (Aquasorption) ..............................................................10

2.4 Teknologi Penjumputan Belerang dari Gas Alam ........................................................11

2.4.1

Proses Claus ....................................................................................................11

2.4.1.1 Acid Gas Enrichment ..........................................................................13

2.4.2

Liquid Redox ...................................................................................................14

2.4.3

Bio-desulfurisasi ..............................................................................................15

2.5 Ionic Liquid .................................................................................................................17

2.5.1

1-Propil-3-Metilimidazolium Bromida ([PMIM][Br]) ....................................18

2.6 Analisa
Kuantitatif
Measurement .................................19

Menggunakan

2.7 Analisa
Kuantitatif
............................................19

Menggunakan

Online
Gas

Weight

Chromatography

2.8 Penelitian Terkait .........................................................................................................21

2.8.1 Sifat
Volumetrik
2009) ........................................21
2.8.2 Densitas
dan
2011) ........................21

Viskositas

[PMIM][Br]

(Sadeghi

[BMIM][Br]

dkk.,

(Tshibangu

dkk.,

2.8.3 Interaksi antara CO2 dan Anion dalam Ionic Liquid (Indarto dan Palgunadi,
2009) ................................................................................................................23
2.8.4 Pemisahan H2S CO2 dengan [BMIM][Br] pada Temperatur Ruang (Handy
dkk., 2014) .......................................................................................................24
BAB
III
BAHAN
PENELITIAN ..................................................................26
3.1

DAN

METODE

Bahan Bahan Penelitian ............................................................................................26

3.2
Peralatan

Penelitian ...................................................................................26

Peralatan

3.3

Metode Penelitian ........................................................................................................27

3.4

Prosedur Penelitian ......................................................................................................28

3.4.1

Percobaan Utama .............................................................................................28

3.4.2 Percobaan
Sampling .........................................................................................29
3.4.3 Percobaan
Recovery .........................................................................................30
3.5
Analisis
dan
Data ......................................................................................31
3.5.1

Pengolahan

Metode Analisis Online Weight Measurement ................................................32

3.5.2 Metode
GC .........................................................................................32
3.6
Lokasi
dan
Jadwal
Penelitian .............................................................................34

Analisis
Kerja

DAFTAR GAMBAR

Gambar 2.1

Diagram Skematik Proses Pemisahan Gas Pengasam dengan Pelarut Berbasis

Amin ..................................................................................................................9

Gambar 2.2

Diagram
Skematik
..........................................................11

Gambar 2.3

Diagram Skematik Proses Claus .....................................................................12

Gambar 2.4

Diagram Skematik Proses Acid Gas Enrichment ............................................14

Gambar 2.5

Diagram Skematik Proses LO-CAT ................................................................15

Gambar 2.6

Diagram Skematik Proses Bio-Desulfurisasi ..................................................17

Gambar 2.7

Struktur [PMIM][Br] .......................................................................................19

Gambar 2.8

Skema Sistem GC ............................................................................................20

Gambar 2.9

Skema Instrumen Elektroforesis Kapiler ........................................................21

Proses

Aquasorption

Gambar 2.10 Grafik Densitas [BMIM][Br] Murni terhadap Temperatur .............................22

Gambar 2.11 Grafik Viskositas [BMIM][Br] Murni terhadap Temperatur ..........................23
Gambar 3.1

Skema Rangkaian Alat Penyerapan Gas CO2 dan H2S ...................................27

Gambar 3.2

Diagram Alir Metode Penelitian .....................................................................28

Gambar 3.3

Diagram Alir Perhitungan Komputasi Molekular ...........................................29

Gambar 3.3

Diagram Alir Absorpsi Gas Pengasam ............................................................30

Gambar 3.4

Diagram Alir Prosedur Sampling ....................................................................31

Gambar 3.5

Diagram Alir Percobaan Recovery ..................................................................32

Gambar 3.7

Diagram Alir Proses Metode GC ....................................................................34

DAFTAR TABEL

Tabel 1.1

Konsentrasi H2S dan CO2 Pada Gas Alam di Berbagai Kilang di

Indonesia ...........................................................................................................
...............2

Tabel 2.1

Komposisi Gas Alam dari Berbagai Sumur Pengilangan ..............................6

Tabel 2.2

Sifat Fisik CO2 .................................................................................................7

Tabel 2.3

Sifat Fisik H2S .................................................................................................8

Tabel 2.4

Perbandingan Pelarut Berbasis Amin ............................................................10

Tabel 2.5

Contoh Ionic Liquid ......................................................................................18

Tabel 2.6

Gas Pembawa dan Jenis Detektor yang Sesuai .............................................21

Tabel 2.7

Struktur Ionic Liquid beserta Kelarutan CO2, Volume Molar (VM), dan Energi
Ikatan CO2-anion Menggunakan MP2/6-311+G(d) ..........................24

Tabel 3.1

Variasi dalam Penelitian ..................................................................................28

Tabel 3.2

Jadwal Kerja Penelitian ...................................................................................34