Kelas : Kimia 4B
NIM
: 122014086
TERMODINAMIKA 1
1. Water is in the first storage tank at an elevation 150 ft above. The water goes through
a heat exchanger. The rate 80.000 Btu/min and is delivered to the second storage tank.
What is the temperature of the water in the storage tank if temperature of water in the
first storage of ___ F and the rate 100 lbm/min?
T1 = 086 + 100 = 186C = 366,8F
Penyelesaian :
Diketahui
: T1 = 366,8 F
m = 100 lbm / min
H1 (air pada suhu 366,8F) = 339,51 Btu/lbm
TANK 1
H = 150 ft
Q = 80.000 btu/min
TANK 2
T2=?
Jawab :
H + EK + EP = Q + W
- Aliran steady, sehingga beda laju aliran dapat diabaikan (Ek = 0)
- Tidak ada usaha yang terjadi sehingga W = 0
Q=
ft
g
s2
1 Btu
EP=
H=
x 150 ft x
gC
ft
778.16lb . ft .lbf
32,174 lbm
s2
lbf
32,174
0,1927
Btu
lbm
H + EK + EP=Q+W
H=Q+W EK EP
800
Btu
Btu
+ 000.1927
lbm
lbm
H=H 2H 1
H 2= H + H 1
800,1927
Btu
Btu
+339,51
lbm
lbm
460,68 Btu
lbm
460,68 Btu
lbm
T 475 1,98
=
5
5,78
5,78 T 2745,5 = 9,9
T2 = 476,71
Jadi nilai T2 adalah 476,71F
2. Find the molar volume of saturated vapor and saturated liquid dioxide at these conditions
as given by Redlich Kwong. P = 58,68 bar
Penyelesaian
Diketahui :
P = 58,68 bar
Pc = 78,84 bar
T = 476,71F = 247,06 C= 520,06 K
Tc = 430,34 K
(Tr) =
Tr1/ 2
= 0.08664
Ditanya
= 0,4278
Volume vapor ?
Volume liquid ?
Jawab
Tr=
T 520,06
=
=1,2085
T c 430,34
Pr=
q=
p 58,6 8
=
=0.7443
Pc 78,84
( Tr )
= Tr
Tr
3
2
3
2
0,4278 (
)= 0,08664
1,2085 )=3,7139
Pr 0,7443
=
x 0.08664=0,0534
Tr 1,2085
Volume Vapor :
Z
Z (z + )
)
Z =1+ q
Iterasi 1
Z0 = 1
Iterasi 2
Z
Z ( z+)
)
Z 1=1+ q
1+ 0,05343,7139 x 0,0534
(10,0534)
1(1+ 0,0534)
Z1 = 0,8752
Iterasi 3
Z 2=1+0,0534(3,7139 x 0,0534)
(0,87520,0534)
0,8752(0,8752+ 0,0534)
Z2 = 0,8529
Iterasi 4
Z 3=1+ 0,0534(3,7139 x 0,0534)
( 0,85290,0534)
0,8529 (0,8529+0,0534)
Z3 = 0,8483
Iterasi 5
Z 4=1+0,0534(3,7139 x 0,0534)
Z4 = 0,8473
Iterasi 6
( 0,84830,0534)
0,8483( 0,8483+0,0534)
( 0,84730,0534)
0,8473 (0,8473+0,0534)
Z5 = 0,8471
Itrerasi 7
Z 6=1+ 0,0534(3,7139 x 0,0534)
(0,84710,0534)
0,8471(0,8471+0,0534)
Z6 = 0,8470
Jadi nilai Z = 0,8470
Volume Vapor
Z . R .T
P
58,68
x 520,06 K
mol . K
0,8470 x 83,14472 cm3