Anda di halaman 1dari 54

Feed Oil

41666.6667 kg/h

41.6667

Feed Oil

41666.6667
0.500%
99.500%

FFA
Trigliserida
Feed Metanol

17.000%
Fresh Metanol
Metanol Recovery
Air

7083.3333
49.500%
49.500%
1.000%

Feed Sod. Methylate

3.000%
Sod. Methylate
Metanol
Air

1250.0000
30.000%
65.000%
5.000%

TRANSESTERIFI
Konversi Reaksi

90.000%

BM
Massa Mula-mula
Reaksi
Sisa

C3H5(OOC18H33)3
Trigliserida
884.0000
46.8986
42.2087
4.6899

C17H33COOH
FFA
BM
Mula-mula
Reaksi
Sisa

282.0000
0.7388
0.6649
0.0739

IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
TOTAL

3 CH3OH
Metanol

+
g/mol
kmol
kmol
kmol

32.0000
244.5313
126.6261
117.9051

NaOCH3
Sodium Methylate
54.0000
6.9444
0.6649
6.2796

+
g/mol
kmol
kmol
kmol

IN
41458.3333
208.3333
7825.0000
133.3333
375.0000
50000.0000

kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI I
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

IN
4145.8333
20.8333
3794.2404
133.3333
339.0957
37481.3348
3883.2014
202.1277
50000.0000

kg
kg
kg
kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI I
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

IN
4125.1042
10.4167
3225.1043
66.6667
169.5479
37479.4608
1553.2805
2.0213
46631.6023

kg
kg
kg
kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI I (SE
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

IN
4104.4786
5.2083
2741.3387
33.3333
84.7739
37477.5868
621.3122
0.0202
45068.0522

kg
kg
kg
kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI II
Feed Light

44106.7931 kg
1.473% Metanol

0.295% Sod. Methylate

98.232%

1.500%
Fresh Metanol
Metanol Recovery
Air

661.6019
49.500%
49.500%
1.000%

0.300%

132.3204

Sod. Methylate
Metanol
Air
Konversi Reaksi

90.000%
C3H5(OOC18H33)3
Trigliserida
884.0000
4.6199
4.1579
0.4620

BM
Mula-mula
Reaksi
Sisa

C17H33COOH
FFA
BM
Mula-mula
Reaksi
Sisa

282.0000
0.0092
0.0083
0.0009

MOL
4.6199
0.0092
95.9729
1.6610
1.5201
126.6071
1.6883
0.0000

30.000%
65.000%
5.000%

IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

3 CH3OH
Metanol

+
g/mol
kmol
kmol
kmol

32.0000
95.9729
12.4736
83.4993
2671.9761
NaOCH3
Sodium Methylate
54.0000
1.5201
0.0083
1.5117

+
g/mol
kmol
kmol
kmol

IN
4083.9563
2.6042
3071.1320
29.8987
82.0831
37475.7129
155.3281
0.0002
44900.7154

kg
kg
kg
kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI II
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

IN
408.3956
0.2604
2672.2421
29.8987
81.6343
41167.9050
537.8525
2.5268
44900.7154

kg
kg
kg
kg
kg
kg
kg
kg
kg

TRANSESTERIFIKASI II
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

IN
406.3536
0.1302
2271.4058
14.9494
40.8171
41165.8467
215.1410
0.0253
44114.6690

kg
kg
kg
kg
kg
kg
kg
kg
kg

WASHING & DRYING (SE


Feed Light

43612.8101 kg
Wash Water

5.500%

2398.7046

Asam Fosfat
Air
Air Recovery

IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
TOTAL

82.000%
8.000%
4.000%

IN
404.3219
0.0651
1930.6949
295.3192
20.4086
41163.7884
86.0564
0.0003
1966.9377
45867.5924

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

-7.4747

WASHING & DRYING


IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
TOTAL

IN
402.3003
0.0326
1641.0907
147.6596
10.2043
41161.7302
21.5141
0.0000
983.4689
44368.0005

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

WASHING & DRYING (SE


Feed Light

43383.3461 kg
Wash Water

5.500%
Asam Fosfat
Air
Air Recovery

IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
TOTAL

IN
402.3003
0.0326
656.4363
338.5463
201.0910
41161.7302
21.5141
0.0000
2940.0578
45721.7085

2386.0840
82.000%
4.000%
4.000%

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

WASHING & DRY


IN

IN

Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
TOTAL

400.2888
0.0163
557.9708
169.2732
100.5455
41159.6721
5.3785
0.0000
1470.0289
43863.1740

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

REAKTOR H
Feed Heavy

10539.2385 kg
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl

69.9839
18.4733
2593.7194
456.0235
468.6843
13.8549
4260.3472
204.6543
2453.4978
1.000%

kg
kg
kg
kg
kg
kg
kg
kg
kg
105.3924
32.000%
68.000%

HCl
Air

BM
Mula-mula
Reaksi
Sisa

C17H33COONa
Sabun
304.0000
0.6732
0.6732
0.0000

IN
Trigliserida
FFA
Metanol

+
g/mol
kmol
kmol
kmol

HCl
Asam Klorida
36.5000
0.9240
0.6732
0.2508

IN
69.9839 kg
18.4733 kg
2593.7194 kg

Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
TOTAL

527.6903
468.6843
13.8549
4260.3472
204.6543
2453.4978
33.7256
10644.6309

kg
kg
kg
kg
kg
kg
kg
kg

SETLING (S
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam
TOTAL

IN
69.9839
208.3171
2593.7194
527.6903
468.6843
13.8549
4260.3472
0.0000
2453.4978
9.1536
39.3825
10644.6309

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

RECTIFICATIO
IN

IN

Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam
TOTAL

0.3499
1.0416
389.0579
263.8451
234.3421
0.0014
2982.2431
0.0000
1226.7489
9.0621
39.3431
5146.0352

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

RECTIFICATION
IN
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam
TOTAL

IN
0.3499
1.0416
19.4529
250.6529
234.3421
0.0014
2982.2431
0.0000
1226.7489
9.0621
39.3431
4763.2379

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

ton/day

1000.0000 ton/day

1000000.0000 kg/day

kg
208.3333 kg
41458.3333 kg
kg
3506.2500 kg
3506.2500 kg
70.8333 kg
kg
375.0000 kg
812.5000 kg
62.5000 kg

TRANSESTERIFIKASI I (REAKTOR)

g/mol
kmol
kmol
kmol

3 C17H33COOCH3
Metil Ester
296.0000
0.0000
126.6261
126.6261

g/mol
kmol
kmol
kmol

C17H33COONa
Sabun
304.0000
0.0000
0.6649
0.6649

OUT
OUT
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

4145.8333
20.8333
3794.2404
133.3333
339.0957
37481.3348
3883.2014
202.1277

+
g/mol
kmol
kmol
kmol

C3H5(OH)3
Gliserol
92.0000
0.0000
42.2087
42.2087

g/mol
kmol
kmol
kmol

+
g/mol
kmol
kmol
kmol

CH3OH
Metanol
32.0000
0.0000
0.6649
0.6649

g/mol
kmol
kmol
kmol

kg
kg
kg
kg
kg
kg
kg
kg

4.6899
0.0739
118.5700
6.2796
126.6261
42.2087
0.6649

TOTAL

50000.0000 kg

TRANSESTERIFIKASI I (KOLOM SEPARATOR I)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

4125.1042
10.4167
3225.1043
66.6667
169.5479
37479.4608
1553.2805
2.0213

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

46631.6023 kg
20.7292
10.4167
569.1361
66.6667
169.5479
1.8741
2329.9208
200.1064

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
3368.3977 kg
50000.0000 kg

TOTAL

TRANSESTERIFIKASI I (KOLOM SEPARATOR II)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

4104.4786
5.2083
2741.3387
33.3333
84.7739
37477.5868
621.3122
0.0202

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA

0.500%
50.000%

45068.0522 kg
20.6255 kg
5.2083 kg

Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

483.7657
33.3333
84.7739
1.8740
931.9683
2.0011

kg
kg
kg
kg
kg
kg

TOTAL HEAVY
1563.5501 kg
46631.6023 kg

TOTAL

TRANSESTERIFIKASI I (SEPARATOR CENTRIFUGAL)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
25.000%
1.000%

4083.9563
2.6042
2330.1379
16.6667
42.3870
37475.7129
155.3281
0.0002

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
75.000%
99.000%
TOTAL

44106.7931 kg
20.5224
2.6042
411.2008
16.6667
42.3870
1.8739
465.9842
0.0200

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
45068.0522 kg

961.2591 kg

TRANSESTERIFIKASI II (KOLOM SEPARATOR III)


Metanol
Air
kg
327.4929 kg
327.4929 kg
6.6160 kg
kg

740.9941
13.2320

39.6961 kg
86.0082 kg
6.6160 kg

g/mol
kmol
kmol
kmol
kg

g/mol
kmol
kmol
kmol

3 C17H33COOCH3
Metil Ester
296.0000
0.0000
12.4736
12.4736

C17H33COONa
Sabun
304.0000
0.0000
0.0083
0.0083

OUT
OUT
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
TOTAL

+
g/mol
kmol
kmol
kmol

+
g/mol
kmol
kmol
kmol

C3H5(OH)3
Gliserol
92.0000
0.0000
4.1579
4.1579

g/mol
kmol
kmol
kmol

CH3OH
Metanol
32.0000
0.0000
0.0083
0.0083
0.2660

g/mol
kmol
kmol
kmol
kg

MOL
408.3956
0.2604
2672.2421
29.8987
81.6343
41167.9050
537.8525
2.5268
44900.7154

kg
kg
kg
kg
kg
kg
kg
kg
kg

0.4620
0.0009
83.5076
1.6610
1.5117
139.0808
5.8462
0.0083

TRANSESTERIFIKASI II (KOLOM SEPARATOR III)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

406.3536
0.1302
2271.4058
14.9494
40.8171
41165.8467
215.1410
0.0253

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

44114.6690 kg
2.0420
0.1302
400.8363
14.9494
40.8171
2.0584
322.7115
2.5015

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
44900.7154 kg

TOTAL

786.0464 kg

TRANSESTERIFIKASI II (KOLOM SEPARATOR IV)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

404.3219
0.0651
1930.6949
7.4747
20.4086
41163.7884
86.0564
0.0003

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%
TOTAL

2.0318
0.0651
340.7109
7.4747
20.4086
2.0583
129.0846
0.0250

kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
44114.6690 kg

WASHING & DRYING (SEPARATOR CENTRIFUGAL)

kg

43612.8101 kg

501.8589 kg

1966.9377 kg
191.8964 kg
95.9482 kg

OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
25.000%
1.000%
50.000%

402.3003
0.0326
1641.0907
147.6596
10.2043
41161.7302
21.5141
0.0000
983.4689

kg
kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
75.000%
99.000%
50.000%

44368.0005 kg
2.0216
0.0326
289.6042
147.6596
10.2043
2.0582
64.5423
0.0003
983.4689

kg
kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
1499.5919 kg
45867.5924 kg

TOTAL

WASHING & DRYING (METANOL FLASHER)


OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

OUT
100.000%
100.000%
40.000%
100.000%
100.000%
100.000%
100.000%
100.000%
100.000%

402.3003
0.0326
656.4363
147.6596
10.2043
41161.7302
21.5141
0.0000
983.4689
TOTAL LIGHT

Gas

kg
kg
kg
kg
kg
kg
kg
kg
kg
43383.3461 kg

Metanol

60.000%

984.6544 kg
TOTAL GAS

TOTAL

984.6544 kg
44368.0005 kg

WASHING & DRYING (SEPARATOR CENTRIFUGAL)

kg
1956.5889 kg
95.4434 kg
95.4434 kg

OUT
OUT
Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

OUT
99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
25.000%
1.000%
50.000%

400.2888
0.0163
557.9708
169.2732
100.5455
41159.6721
5.3785
0.0000
1470.0289

kg
kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
75.000%
99.000%
50.000%
TOTAL

2.0115
0.0163
98.4654
169.2732
100.5455
2.0581
16.1356
0.0000
1470.0289

OUT

kg
kg
kg
kg
kg
kg
kg
kg
kg

TOTAL HEAVY
1858.5344 kg
45721.7085 kg

WASHING & DRYING (PME DRYER)


OUT

43863.1740 kg

OUT

Light Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat

100.000%
100.000%
10.000%
30.000%
100.000%
100.000%
100.000%
100.000%
50.000%

400.2888
0.0163
55.7971
50.7820
100.5455
41159.6721
5.3785
0.0000
735.0144

kg
kg
kg
kg
kg
kg
kg
kg
kg

TOTAL LIGHT
Gas
Metanol
Air
Asam Fosfat

90.000%
70.000%
50.000%

42507.4946 kg
502.1737 kg
118.4912 kg
735.0144 kg

TOTAL GAS
TOTAL

1355.6794 kg
43863.1740 kg

REAKTOR HEAVY PHASE

kg
33.7256 kg
71.6668 kg

g/mol
kmol
kmol
kmol

OUT
Trigliserida
FFA
Metanol

C17H33COOH
FFA
282.0000
0.0000
0.6732
0.6732

+
g/mol
kmol
kmol
kmol

NaCl
Garam
58.5000
0.0000
0.6732
0.6732

OUT
69.9839 kg
208.3171 kg
2593.7194 kg

0.168%
0.500%
6.225%

g/mol
kmol
kmol
kmol

Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam
TOTAL

527.6903
468.6843
13.8549
4260.3472
0.0000
2453.4978
9.1536
39.3825
10644.6309

kg
kg
kg
kg
kg
kg
kg
kg
kg

1.266%
1.125%
0.033%
10.225%
0.000%
5.888%
0.022%
0.095%

SETLING (SPLIT TANK)


OUT
OUT
Fatty Mater
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam

OUT
99.500%
99.500%
85.000%
50.000%
50.000%
99.990%
30.000%
1.000%
50.000%
1.000%
0.100%

69.6340
207.2755
2204.6615
263.8451
234.3421
13.8535
1278.1042
0.0000
1226.7489
0.0915
0.0394
TOTAL FATTY MATER

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

0.3499
1.0416
389.0579
263.8451
234.3421
0.0014
2982.2431
0.0000
1226.7489
9.0621
39.3431

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg

0.500%
0.500%
15.000%
50.000%
50.000%
0.010%
70.000%
99.000%
50.000%
99.000%
99.900%
TOTAL

5498.5957 kg

TOTAL HEAVY
5146.0352 kg
10644.6309 kg

RECTIFICATION II (DISTILASI)

BM
Metanol
Air

OUT
Refluk
Metanol
Air

Feed (Kmol)
32.0000
18.0000

OUT

XF
12.1581
14.6581
26.8161

OUT
95.000%
5.000%

369.6050 kg
13.1923 kg
TOTAL Refluk

Gly-Water
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun
Asam Fosfat
HCl
Garam

Distilat (Kmol)
0.4534
11.5502
0.5466
0.7329
1.0000
12.2831

100.000%
100.000%
5.000%
95.000%
100.000%
100.000%
100.000%
100.000%
100.000%
100.000%
100.000%
TOTAL

382.7973 kg

0.3499
1.0416
19.4529
250.6529
234.3421
0.0014
2982.2431
0.0000
1226.7489
9.0621
39.3431
TOTAL Gly-Water
5146.0352

kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
kg
4763.2379 kg

kg

RECTIFICATION II (EVAPORASI)
OUT
Water
Metanol
Air

OUT

OUT
90.000%
70.000%

17.5076 kg
175.4570 kg
TOTAL WATER

Gliserol
Trigliserida
FFA
Metanol
Air
Sod. Methylate
Metil Ester
Gliserol
Sabun

100.000%
100.000%
10.000%
30.000%
100.000%
100.000%
100.000%
100.000%

192.9646 kg
0.3499
1.0416
1.9453
75.1959
234.3421
0.0014
2982.2431
0.0000

kg
kg
kg
kg
kg
kg
kg
kg

Asam Fosfat
HCl
Garam

100.000%
100.000%
100.000%
TOTAL

1226.7489
9.0621
39.3431
TOTAL GLISEROL
4763.2379

kg
kg
kg
4570.2733 kg

kg

9.900%
0.025%
7.740%
0.160%
0.407%
89.951%
3.728%
0.005%

0.050%
0.025%
1.366%
0.160%
0.407%
0.004%
5.592%
0.480%

9.851%
0.013%
6.579%
0.080%
0.203%
89.946%
1.491%
0.000%

0.050%
0.013%

1.161%
0.080%
0.203%
0.004%
2.237%
0.005%

9.801%
0.006%
5.592%
0.040%
0.102%
89.942%
0.373%
0.000%

0.049%
0.006%
0.987%
0.040%
0.102%
0.004%
1.118%
0.000%

0.975%
0.000%
5.451%
0.036%
0.098%
98.798%
0.516%
0.000%

0.005%
0.000%
0.962%
0.036%
0.098%
0.005%
0.775%
0.006%

0.970%
0.000%
4.634%
0.018%
0.049%
98.793%
0.207%
0.000%

0.005%
0.000%
0.818%
0.018%
0.049%
0.005%
0.310%
0.000%

0.966%
0.000%
3.939%
0.354%
0.024%
98.788%
0.052%
0.000%
2.360%

0.005%
0.000%
0.695%
0.354%
0.024%
0.005%
0.155%
0.000%
2.360%

0.966%
0.000%
1.575%
0.354%
0.024%
98.788%
0.052%
0.000%
2.360%

2.363%

0.961%
0.000%
1.339%
0.406%
0.241%
98.783%
0.013%
0.000%
3.528%

0.005%
0.000%
0.236%
0.406%
0.241%
0.005%
0.039%
0.000%
3.528%

0.961%
0.000%
0.134%
0.122%
0.241%
98.783%
0.013%
0.000%
1.764%

1.205%
0.284%
1.764%

0.942%
0.000%
0.131%
0.119%
0.237%
96.829%
0.013%
0.000%
1.729%
100.000%

0.167%
0.497%
5.291%
0.633%
0.562%
0.033%
3.067%
0.000%
2.944%
0.000%
0.000%

1.266%
3.770%
40.095%
4.798%
4.262%
0.252%
23.244%
0.000%
22.310%
0.002%
0.001%
100.000%

0.001%
0.002%
0.934%
0.633%
0.562%
0.000%
7.157%
0.000%
2.944%
0.022%
0.094%

0.007%
0.020%
7.560%
5.127%
4.554%
0.000%
57.952%
0.000%
23.839%
0.176%
0.765%
100.000%

XD
Bottom (Kmol) XB
0.9403
0.6079
0.0418
0.0597
13.9252
0.9582
1.0000
14.5331
1.0000

0.001%
0.002%
0.047%
0.602%
0.562%
0.000%
7.157%
0.000%
2.944%
0.022%
0.094%

0.007%
0.022%
0.408%
5.262%
4.920%
0.000%
62.610%
0.000%
25.755%
0.190%
0.826%
100.000%

0.001%
0.002%
0.005%
0.180%
0.562%
0.000%
7.157%
0.000%

0.008%
0.023%
0.043%
1.645%
5.128%
0.000%
65.253%
0.000%

2.944%
0.022%
0.094%

26.842%
0.198%
0.861%
100.000%

Feed Oil

41,666.6667 kg/h

41.6667 ton/day

Feed Oil

41,666.6667 kg
0.500%
99.500%

FFA
Trigliserida
Metanol

17.000%
Fresh Metanol
Metanol Recovery
Air

7,083.3333 kg
49.750%
49.750%
0.500%

Sod. Methylate

3.000%
Sod. Methylate
Metanol
Air

1,250.0000 kg
30.000%
65.000%
5.000%

BM
FFA
Trigliserida

Mol
282.0000 kg/kmol
884.0000 kg/kmol

58,750.0000 Kmol
36,649,166.6667 Kmol

Fresh Metanol
Metanol Recovery
Air

32.0000 kg/kmol
32.0000 kg/kmol
18.0000 kg/kmol

112,766.6667 Kmol
112,766.6667 Kmol
637.5000 Kmol

Sod. Methylate
Metanol
Air

54.0000 kg/kmol
32.0000 kg/kmol
18.0000 kg/kmol

20,250.0000 Kmol
26,000.0000 Kmol
1,125.0000 Kmol

1,000.0000 ton/day

1,000,000.0000 kg/day

208.3333 kg
41,458.3333 kg

74.9411
5
374.7055

3,523.9583 kg
3,523.9583 kg
35.4167 kg

375.0000 kg
812.5000 kg
62.5000 kg
Delta T
C
63.0000 C
63.0000 C

Delta T

C
25.0000 C
25.0000 C

Delta T
K
336.1500 K
336.1500 K

Delta T
K
298.1500 K
298.1500 K

63.0000 C
63.0000 C
63.0000 C

25.0000 C
25.0000 C
25.0000 C

336.1500 K
336.1500 K
336.1500 K

298.1500 K
298.1500 K
298.1500 K

63.0000 C
63.0000 C
63.0000 C

25.0000 C
25.0000 C
25.0000 C

336.1500 K
336.1500 K
336.1500 K

298.1500 K
298.1500 K
298.1500 K

Delta T
38.0000 K
38.0000 K

Cp
Kalor Q
559.5674 J/mol.K
1,249,234,220.5000
1,700.8656 J/mol.K
2,368,741,660,376.0000

38.0000 K
38.0000 K
38.0000 K

85.5618 J/mol.K
85.5618 J/mol.K
74.9411 J/mol.K

366,643,721.2400
366,643,721.2400
1,815,448.1475

38.0000 K
38.0000 K
38.0000 K

65.3700 J/mol.K
85.5618 J/mol.K
74.9411 J/mol.K

50,302,215.0000
84,535,058.4000
3,203,732.0250

Cp
Komponen
FFA (Asam Oleat)

Rumus
C17H33COOH

Trigliserida (Tri Olein) C3H5(OOC18H33)3


Metanol

CH3OH

Hf
Komponen
FFA (Asam Oleat)

Rumus
C17H33COOH

Trigliserida (Tri Olein) C3H5(OOC18H33)3


Metil Ester

C17H33COOCH3

CH2JUMLAH
14.0000 28.2054 394.8756
CH2JUMLAH
44.0000 28.2054 1,241.0376
CH3JUMLAH
1.0000 41.6114
41.6114

CH31.0000
CH33.0000
OH1.0000

CH2JUMLAH
14.0000 -20.6400 -288.9600
CH2JUMLAH
44.0000 -20.6400 -908.1600
CH2JUMLAH
16.0000 -20.6400 -330.2400

CH31.0000 -76.4500
CH33.0000 -76.4500
CH32.0000 -76.4500

41.6114
41.6114
43.9504

JUMLAH COOHJUMLAH
CH=
41.6114 1.0000
78.7300
78.7300
2.0000
JUMLAH COOJUMLAH
CH=
124.8342 3.0000
59.0126
177.0378
6.0000
JUMLAH
43.9504 85.5618 J/mol.K

JUMLAH
22.1752 44.3504
559.5674
JUMLAH >CH22.1752 133.0512
1.0000

JUMLAH COOHJUMLAH
CH=
JUMLAH
-76.4500 1.0000 -426.7200
-426.7200
2.0000 37.9700 75.9400 -716.1900
JUMLAH COOJUMLAH
CH=
JUMLAH >CH-229.3500 3.0000 -337.9200 -1,013.7600
6.0000 37.9700 227.8200
1.0000
JUMLAH COOJUMLAH
-152.9000 1.0000 -337.9200
-337.9200 -821.0600 kJ/mol.K 68.2900 -752.7700

J/mol.K
JUMLAH
24.9048 24.9048 1,700.8656 J/mol.K

kJ/mol.K

68.2900 -647.9000
JUMLAH
29.8900 29.8900 -1,893.5600 kJ/mol.K

68.2900 -1,825.2700

Feed Oil

41666.6667 kg/h
Feed Oil
FFA
Trigliserida
Feed Metanol

41.6667 ton/day
41666.6667 kg
0.0050
0.9950

17.000%
Fresh Metanol
Metanol Recovery
Air

7083.3333 kg
0.4950
0.4950
0.0100

Feed Sod. Methyl


3.000%
Sod. Methylate
Metanol
Air

1250.0000 kg
0.3000
0.6500
0.0500

TRANSESTERIFIKASI I (REAK

Konversi Reaksi

90.000%

C3H5(OOC18H33)3
Trigliserida
+
BM
884.0000 g/mol
Massa Mula-mula
46.8986 kmol
Reaksi
42.2087 kmol
Sisa
4.6899 kmol

BM
Mula-mula
Reaksi
Sisa

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

C17H33COOH
FFA
282.0000
0.7388
0.6649
0.0739

+
g/mol
kmol
kmol
kmol

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
46.8986
282.00
0.7388
32.00
244.5313
18.00
7.4074
54.00
6.9444
296.00
0.0000
92.00
0.0000
304.00
0.0000

3 CH3OH
Metanol
32.0000
244.5313
126.6261
117.9051

g/mol
kmol
kmol
kmol

NaOCH3
Sodium Methylate
54.0000
6.9444
0.6649
6.2796

g/mol
kmol
kmol
kmol

Massa (kg)
41458.3333
208.3333
7825.0000
133.3333
375.0000
0.0000
0.0000
0.0000

TOTAL

306.5204

50000.0000

TRANSESTERIFIKASI I (KOLOM SEP

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
4.6899
282.00
0.0739
32.00
118.5700
18.00
7.4074
54.00
6.2796
296.00
126.6261
92.00
42.2087
304.00
0.6649
TOTAL
306.5204

Massa (kg)
4145.8333
20.8333
3794.2404
133.3333
339.0957
37481.3348
3883.2014
202.1277
50000.0000

TRANSESTERIFIKASI I (KOLOM SEP

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
4.6664
282.00
0.0369
32.00
100.7845
18.00
3.7037
54.00
3.1398
296.00
126.6198
92.00
16.8835
304.00
0.0066
TOTAL
255.8413

Massa (kg)
4125.1042
10.4167
3225.1043
66.6667
169.5479
37479.4608
1553.2805
2.0213
46631.6023

TRANSESTERIFIKASI I (SEPARATOR C

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
4.6431
282.00
0.0185
32.00
85.6668
18.00
1.8519
54.00
1.5699
296.00
126.6135
92.00
6.7534
304.00
0.0001
TOTAL
227.1170

Massa (kg)
4104.4786
5.2083
2741.3387
33.3333
84.7739
37477.5868
621.3122
0.0202
45068.0522

TRANSESTERIFIKASI II (KOLOM SEP

Feed Light

44106.7931 kg
Metanol

1.500%
Fresh Metanol

661.6019 kg
49.500%

Sod. Methylate

Konversi Reaksi

Metanol Recovery
Air

49.500%
1.000%

0.300%
Sod. Methylate
Metanol
Air

132.3204 kg
30.000%
65.000%
5.000%

90.000%

C3H5(OOC18H33)3
Trigliserida
+
BM
884.0000 g/mol
Massa Mula-mula
4.6199 kmol
Reaksi
4.1579 kmol
Sisa
0.4620 kmol

BM
Mula-mula
Reaksi
Sisa

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

Komponen
Trigliserida
FFA
Metanol

C17H33COOH
FFA
282.0000
0.0092
0.0083
0.0009

+
g/mol
kmol
kmol
kmol

3 CH3OH
Metanol
32.0000
95.9729
12.4736
83.4993

g/mol
kmol
kmol
kmol

NaOCH3
Sodium Methylate
54.0000
1.5201
0.0083
1.5117

g/mol
kmol
kmol
kmol

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
4.6199
282.00
0.0092
32.00
95.9729
18.00
1.6610
54.00
1.5201
296.00
126.6071
92.00
1.6883
304.00
0.0000
TOTAL
232.0786

Massa (kg)
4083.9563
2.6042
3071.1320
29.8987
82.0831
37475.7129
155.3281
0.0002
44900.7154

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
0.4620
282.00
0.0009
32.00
83.5076

Massa (kg)
408.3956
0.2604
2672.2421

Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

18.00
54.00
296.00
92.00
304.00
TOTAL

1.6610
1.5117
139.0808
5.8462
0.0083
232.0786

29.8987
81.6343
41167.9050
537.8525
2.5268
44900.7154

TRANSESTERIFIKASI II (KOLOM SEP

Komponen
Trigliserida
FFA
Metanol
Air
Sodium
Methylate
Metil Ester
Gliserol
Sabun

INPUT
BM (kg/kmol)
Mol (kmol)
884.00
0.4597
282.00
0.0005
32.00
70.9814
18.00
0.8305
54.00
0.7559
296.00
139.0738
92.00
2.3385
304.00
0.0001
TOTAL
214.4403

Massa (kg)
406.3536
0.1302
2271.4058
14.9494
40.8171
41165.8467
215.1410
0.0253
44114.6690

1000.0000 ton/day

1000000.0000 kg/day

208.3333 kg
41458.3333 kg

3506.2500 kg
3506.2500 kg
70.8333 kg

375.0000 kg
812.5000 kg
62.5000 kg

RANSESTERIFIKASI I (REAKTOR)

3 C17H33COOCH3
Metil Ester
296.0000
0.0000
126.6261
126.6261

C17H33COONa
Sabun
304.0000
0.0000
0.6649
0.6649

Komponen
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

+
g/mol
kmol
kmol
kmol

C3H5(OH)3
Gliserol
92.0000
0.0000
42.2087
42.2087

g/mol
kmol
kmol
kmol

+
g/mol
kmol
kmol
kmol

CH3OH
Metanol
32.0000
0.0000
0.6649
0.6649

g/mol
kmol
kmol
kmol

OUTPUT
BM
Mol (kmol)
Massa (kg)
(kg/kmol)
884.00
4.6899 4145.8333
282.00
0.0739
20.8333
32.00
118.5700 3794.2404
18.00
7.4074
133.3333
54.00
6.2796
339.0957
296.00
126.6261 37481.3348
92.00
42.2087 3883.2014
304.00
0.6649
202.1277

TOTAL

306.5204 50000.0000

ESTERIFIKASI I (KOLOM SEPARATOR I)

Komponen
Light Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

BM
(kg/kmol)

OUTPUT
Effisiesi

Mol (kmol) Massa (kg)

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL

99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

4.6664 4125.1042
0.0369
10.4167
100.7845 3225.1043
3.7037
66.6667
3.1398
169.5479
126.6198 37479.4608
16.8835 1553.2805
0.0066
2.0213
255.8413 46631.6023

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL
JUMLAH

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

0.0234
20.7292
0.0369
10.4167
17.7855
569.1361
3.7037
66.6667
3.1398
169.5479
0.0063
1.8741
25.3252 2329.9208
0.6582
200.1064
50.6792 3368.3977
306.5204 50000.0000

STERIFIKASI I (KOLOM SEPARATOR II)

Komponen
Light Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun
Heavy Phase

BM
(kg/kmol)

OUTPUT
Effisiesi

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL

99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

Mol (kmol) Massa (kg)


4.6431 4104.4786
0.0185
5.2083
85.6668 2741.3387
1.8519
33.3333
1.5699
84.7739
126.6135 37477.5868
6.7534
621.3122
0.0001
0.0202
227.1170 45068.0522

Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL
JUMLAH

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

0.0233
20.6255
0.0185
5.2083
15.1177
483.7657
1.8519
33.3333
1.5699
84.7739
0.0063
1.8740
10.1301
931.9683
0.0066
2.0011
28.7242 1563.5501
255.8413 46631.6023

ERIFIKASI I (SEPARATOR CENTRIFUGAL)

Komponen
Light Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

BM
(kg/kmol)

OUTPUT
Effisiesi

Mol (kmol) Massa (kg)

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL

99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
25.000%
1.000%

4.6199 4083.9563
0.0092
2.6042
72.8168 2330.1379
0.9259
16.6667
0.7849
42.3870
126.6071 37475.7129
1.6883
155.3281
0.0000
0.0002
207.4523 44106.7931

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL
JUMLAH

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
75.000%
99.000%

0.0232
20.5224
0.0092
2.6042
12.8500
411.2008
0.9259
16.6667
0.7849
42.3870
0.0063
1.8739
5.0650
465.9842
0.0001
0.0200
19.6648
961.2591
227.1170 45068.0522

STERIFIKASI II (KOLOM SEPARATOR III)

327.4929 kg

327.4929 kg
6.6160 kg

39.6961 kg
86.0082 kg
6.6160 kg

3 C17H33COOCH3
Metil Ester
296.0000
0.0000
12.4736
12.4736

C17H33COONa
Sabun
304.0000
0.0000
0.0083
0.0083

Komponen
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

Komponen
Light Phase
Trigliserida
FFA
Metanol

+
g/mol
kmol
kmol
kmol

C3H5(OH)3
Gliserol
92.0000
0.0000
4.1579
4.1579

g/mol
kmol
kmol
kmol

+
g/mol
kmol
kmol
kmol

CH3OH
Metanol
32.0000
0.0000
0.0083
0.0083

g/mol
kmol
kmol
kmol

OUTPUT
BM
Mol (kmol)
Massa (kg)
(kg/kmol)
884.00
0.4620
408.3956
282.00
0.0009
0.2604
32.00
83.5076 2672.2421
18.00
1.6610
29.8987
54.00
1.5117
81.6343
296.00
139.0808 41167.9050
92.00
5.8462
537.8525
304.00
0.0083
2.5268
TOTAL
232.0786 44900.7154

BM
(kg/kmol)

OUTPUT
Effisiesi

884.00
282.00
32.00

99.500%
50.000%
85.000%

Mol (kmol) Massa (kg)


0.4597
0.0005
70.9814

406.3536
0.1302
2271.4058

Air
Sodium Methylate
Metil Ester
Gliserol
Sabun
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

18.00
54.00
296.00
92.00
304.00
TOTAL

50.000%
50.000%
99.995%
40.000%
1.000%

0.8305
14.9494
0.7559
40.8171
139.0738 41165.8467
2.3385
215.1410
0.0001
0.0253
214.4403 44114.6690

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL
JUMLAH

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

0.0023
2.0420
0.0005
0.1302
12.5261
400.8363
0.8305
14.9494
0.7559
40.8171
0.0070
2.0584
3.5077
322.7115
0.0082
2.5015
17.6382
786.0464
232.0786 44900.7154

STERIFIKASI II (KOLOM SEPARATOR IV)

Komponen
Light Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun
Heavy Phase
Trigliserida
FFA
Metanol
Air
Sodium Methylate
Metil Ester
Gliserol
Sabun

BM
(kg/kmol)

OUTPUT
Effisiesi

Mol (kmol) Massa (kg)

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL

99.500%
50.000%
85.000%
50.000%
50.000%
99.995%
40.000%
1.000%

0.4574
404.3219
0.0002
0.0651
60.3342 1930.6949
0.4153
7.4747
0.3779
20.4086
139.0669 41163.7884
0.9354
86.0564
0.0000
0.0003
201.5873 43612.8101

884.00
282.00
32.00
18.00
54.00
296.00
92.00
304.00
TOTAL
JUMLAH

0.500%
50.000%
15.000%
50.000%
50.000%
0.005%
60.000%
99.000%

0.0023
2.0318
0.0002
0.0651
10.6472
340.7109
0.4153
7.4747
0.3779
20.4086
0.0070
2.0583
1.4031
129.0846
0.0001
0.0250
12.8531
501.8589
214.4403 44114.6690