CERAMICS
REFF:
Materials Science & Engineering; An Introduction
Callister, W. D, Jr, 2007, John Wiley & Sons
Fundamental of Ceramics, Barsoum, M. W., 2003,
McGraw-Hill
Engineering Materials 2; An Introduction to
Microstructures, Processing and Design, Ashby, M. F and
Jones, D. R. H, 1986, Pergamon Press
Introduction
CERAMICS: Greek keramikos = burn stuf
solid compounds formed by heat (&/P) applications
followed by cooling
desirable properties are achieved through high-T
process (firing)
Firing causes irreversible transformation resulting a
material that has lost its plasticity & no longer
capable to rehydrate
at least 2 elements; 1 is a non-metal, the other may
be (a) metal(s) or (an)other non
Atom arrangement
Coordination number
Table: Coordination
numbers and
geometries for various
rc/ra
blue cation
red anion
Common coordination
numbers for ceramic: 4,
6 and 8
rc/ra>1 coordinate
no. 12
2. charge on an ion
Removing e from atom/ion, the remaining valence electrons
become more tightly bound to the nucleus decrease ionic
radius
Ionic size increases when electrons are added to an atom or
ion
Radii for Fe: Fe2+: Fe3+ = 0.124: 0.077: 0.069
Crystal structure
Single crystal
Polycrystalline material