Chemical fuels
Contents
Classification
Calorific value - GCV & NCV
Determination of CV of solids - Bomb calorimeter
Determination of CV of liquids/gases - Boys calorimeter
Coal & its analysis - proximate & ultimate analysis
Liquid & gaseous fuels
Chemical Fuels, Dept. of Chemistry
Learning objectives
Introduction
Chemical fuel: A combustible carbonaceous material which on proper
burning in the presence of oxygen liberates large amount of heat that can
be used for domestic & industrial purposes.
Eg. coal, petrol, water gas
Combustion components
Ignition
Temperature
Time
Turbulence
Chemical Fuels, Dept. of Chemistry
Classification of fuels
Physical state
Primary fuel
Secondary fuel
Solid
Wood, Peat,
Coal, Lignite
Charcoal, Coke
Liquid
Crude petroleum
Petrol, Kerosene,
Diesel, Petrol
Gas
Natural gas
Producer gas,
Water gas, Biogas, LPG
Products of combustion
combustible matter
Low ash content
economical
Calorific value
The amount of heat liberated when unit mass/volume of fuel is
completely burnt in pure oxygen.
Units : S or L fuels : cal/g or kcal/kg or J/kg
G fuels : kcal/m3 or J/m3
Types : * Gross Calorific Value (GCV)
* Net Calorific Value (NCV)
GCV = NCV + Latent heat of condensation of steam
NCV = GCV - Latent heat of condensation of steam
Chemical Fuels, Dept. of Chemistry
Principle:
Burn known mass of fuel completely in excess of oxygen
Heat liberated by burning fuel is the heat absorbed by water &
calorimeter
Measure the increase in temp of calorimeter & water using sensitive
thermometer
Calculate CV of fuel from measured data
Chemical Fuels, Dept. of Chemistry
Bomb calorimeter
6v battery
Beckmann
thermometer
Oxygen
valve
Stirrer
Electrodes
Cu calorimeter
Mg fuse
wires
Fuel
Water jacket
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Numerical Problems
1. Calculate the CV of coal with the following data:
Mass of coal= 0.6 g, water equivalent of
calorimeter 2200 g, specific heat of water = 4.187
kJ kg-1c-1, Increase in temp. = 6.52 0C.
2. Calculate the GCV and NCV of a fuel from the
following data: Mass of fuel = 0.75 g, water
equivalent of calorimeter = 350 g, mass of water =
1150 g, Increase in temp= 3.02 oC, % of hydrogen
in the fuel = 2.8 .
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Principle
Burn known volume of gaseous fuel sample
Heat released is quantitatively absorbed by cooling water
circulated through copper coils.
* Note the mass of cooling water & its rise in temp.
Calculate calorific value from the measured data
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Boys calorimeter
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Numerical Problems
1. The following results were recorded during the
determination of CV of a gaseous fuel. Calculate the GCV
& NCV of the fuel. Vol. of fuel burnt = 0.093 m3, Wt. of
water used = 30.5 Kg, Wt. of steam condensed = 0.031 Kg,
Inlet water temp = 26.1 oC, Outlet water temp. = 36.5 oC.
2. Calculate the GCV & NCV of a gaseous fuel from the
following data: Vol. of gas burnt = 0.05 m3, Temp. of gas =
20 oC, Wt. of water = 4.5 kg, Rise in temp.= 25 oC, Specific
heat of water = 4.2 kJ/kg-K, Wt. of water produced = 0.75
kg, Latent heat of steam = 2.5 kJ/m3.
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Solid fuels
Advantages
Disadvantages
Easy transportation
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3. Ash: Heat coal left in step 2 without lid in a muffle furnace at 750 0C
to complete the combustion & constant weight of residue is obtained.
% Ash = Wt. of ash left
100
4. Fixed carbon: Sum total of the % ages of volatile matter, moisture &
ash subtracted from 100.
i.e. 100 (% moisture + % volatile matter + % ash)
High percentage of fixed carbon greater CV & better the quality
Chemical Fuels, Dept. of Chemistry
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Numerical Problems
1. About 1.5 g of coal was used for nitrogen estimation by
Kjeldahl method. The evolved ammonia was collected in 25
mL of 0.1 N H2SO4. the excess acid was neutralized by 15
mL of 0.1 N NaOH. Calculate the % nitrogen in the sample.
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Liquid fuels
They are combustible molecules that can be harnessed to create
energy
Formed by anaerobic decay of marine plant & animal life under the
influence of high T & P
Complex mixture of hydrocarbons
Refining- separation of crude oil into different useful fractions on the
basis of their boiling points
Petroleum- An important primary liquid fuel
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Petroleum cracking
Decomposition of higher mw into lower mw hydrocarbons.
Cracking
Thermal Cracking
[high T & P, Absence of catalyst]
Catalytic Cracking
Low T & P, Presence of catalyst e.g.
(Al2O3 + SiO2)
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Catalytic cracking
CC is the breaking down of long-chain hydrocarbons into shorter chain
hydrocarbons
Advantages
High octane number & yield of gasoline
Better controlled process
Low production costs - high T & P are not required
External fuel not required
Selective catalysts permit cracking of only high boiling hydrocarbons.
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Petroleum reforming
Upgrading gasoline by increasing its octane number in presence of a
catalyst.
Isomerization
H3C
(CH2)4
CH3
H3C CH CH2
CH2 CH3
CH3
n-hexane
2-methyl petane
Dehydrogenation:
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(CH2)4
CH3
n-Hexane
H2
Cyclohexane
+
Cyclohexane
3H2
Benzene
Hydro cracking:
CH3 (CH2)8
n-Decane
CH3
H2
Cat
2 CH3 (CH2)3
CH3
n-Pentane
Chemical Fuels, Dept. of Chemistry
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Knocking
in ICEs
Sharp sounds caused
by premature combustion of part of the
compressed air-fuel mixture in the cylinder of IC engine (See next slide
for image)
Adverse effects:
* Increases fuel consumption
* Decreased in efficiency
* Causes mechanical damage to the engine parts & spark plug
* Unpleasant driving
* Undesirable rattling sound during travel
Minimization methods:
* Suitable change in engine design
* Using high octane number fuel
* Use of anti-knocking agents
Chemical Fuels, Dept. of Chemistry
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Gaseous fuel
Advantages
Disadvantages
o Highly inflammable
o More expensive than S/L fuels
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Water gas
Mixture of CO & H2
Manufacture :
Produced by passing alternatively steam & air through a bed of red
hot coke maintained at 1000 0C.
C + H2O (steam) CO + H2
H = 131.4 KJ (endothermic)
H = - 221.9 KJ (exothermic)
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Summary
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Review questions
1. What are the differences between ultimate analysis & proximate
analyses of coal?
2. Describe the principle, procedure & calculation steps used to
determine the CV of a gaseous fuel.
3. Explain fluidized bed catalytic cracking technique.
4. How do you carry out catalytic reforming of gasoline?
5. Describe the manufacture & uses of water gas.
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