Marawan, H.
E.G.P.C.
Abstract
Pipeline drag reducers have proven to be an extremely powerful tool in fluid
transportation. High molecular weight polymers are used to reduce the frictiona]
pressure loss ratio in crude oil pipelines, refined fuel and aqueous pipelines.
Chemical structure of the main used pipeline drag reducers is one of the
following polymers and copolymers classified according to the type of fluid to ; low
density polyethylene, copolymer of 1-hexane cross linked with divinyl benzene,
polyacrylamides, polyalkylene oxide polymers and their copolymers, fluorocarbons,
polyalkylmethacrylates and terpo'ymer of styrene, alky] acrylate and acrylic acid .
Drag reduction is the increase in pump ability of a fluid caused by the addition
of small amounts of an additive to the fluid. The effectiveness of a drag reducer is
normally expressed in terms of percent drag reduction.
Frictional pressure loss in a pipeline system is a waste of energy and it costly .
The drag reducing additive minimizes the flow turbulence, increases throughput and
reduces the energy costs. The Flow can be increased by more than 80 % with existing
assets.
The effectiveness of the injected drag reducer in Mostorod to Tanta crude oil
pipeline achieved 35.4 % drag reduction and 23.2 % flow increase of the actual
performance The experimental application of DRA on Arab Petroleum Pipeline
Company (Summed) achieved a flow increase ranging from 9-32 % .
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December 2004
Introduction:
Oil transportation companies are experiencing a need
to increase their
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December 2004
o/oDR
A Po - A Pp
Equation 1
]00
APp
APo is the base frictional pressure drop of the untreated fluid.
Pp is the frictional pressure drop of the fluid containing reducing polymer .
(
)
L 100-%D.R J
]\ * 100
J
Equation 2
comprising a viscous sub layer and a buffer layer, plays a major role in drag
reduction
TESCE, Vol. 30, No.2
^"/
December 2004
The most serious problem in the effectiveness of drag reducers is the chain
degradation of polymers by shear strains in turbulent flow. Ultra high molecular
weight polymers are more susceptible to shear-induced degradation \ and polymers
with linear chain-structure are more vulnerable than branched polymers 6'
and
Cheniicate'
<
' "-
; - <
Description - , , - , -i'/-'
a-Olefins up to 10 mole %
a-olefins are 1-hexene, 1-octene, 1-
decene,and 1-dodecene
Cross linkers are divinylbenzene or
organosiloxanes with pendent vinyl
groups
l4
soluble
drag
reducer
for
emulsions
For asphaltenic crudes oils
Esters with C-10 to C-18 and ionic
Polyalkylmethacrylates15"19
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December 2004
CH2= C H - C
X
N
C H
CH
t O
CH3
o
_.. I
_'/
~C
\ ) _
CH2-Cc
OH
H
Acryl amide
Acrylic acid
CH = CH2
Methacrylic acid
CH=CH 2
fOJ
^rH/v/-^CH3
CH =CH 2
Styrene
1-Hexene
p-Divinylbenzcne
Fig. (1): Monomers for Copolymers of Acrylamide and Acrylic Acid and Styrenics .
'
December 2004
'
December 2004
Time
10:00 PM
12:00 AM
07:00 PM
11:00 PM
12:00 PM
10:00 PM
Event
Start of Crude Oil at Mostorod .
Start DRA (A) injection at Mostorod .
Line Fill to Tanta - DRA (A) .
Trial DRA (A) Complete .
Start DRA (C) injection at Mostorod .
Trial DRA (C) complete .
'
December 2004
December 2004
Time
Event
l day
09:00 PM
Tday
01:00 PM
3 rd day
02:00 PM
3 rd day
Date
sl
day
08:00 PM
4 day
07:00 PM
J
lh
/629 s )
TESCE, Vol. 30, No.2
V'
December 2004
DRA (B).
The enclosed graph shows a Drag Reduction of 19.5 % at Line Fill, resulting in a
flow rate increase of 13.7 % . It was equally obvious that the DRA (A) did not
perform as well in the Fuel Oil as it did in the Crude Oil .
DRA (B)
Drag Reduction : 19.5 % .
Flow Increase : 13.7 % .
DRA(B)
300
DRA(A)
90
l\
/l_A/\/\
%
280
\y
c
c
e
V /
BO
as 250
CL
Q
tf ~ \
70
if
-I 60
-3- Norm DP
220
203 I
U - U X L U X l I ; 11 I I M I I I I i IJU ; H I I i i ljLUOJJlJ.UJ^IJ^JJ-U-U-U.LUj.LUJJ_LI.J-U-U-i.U_lJ.^.iJ
'.3:00
13:00 19:00
Time
December 2004
i
I jg
-e- DR
%Flo
DJR\
.10 i i
i i i i i i i i i i 11 i i i i i i i i i i i
13:00
19:00
01:00
07:00
13:00
inc
(A)
i i i i i i i i i i i i i 11 1 1 . i i i i 1 1 1 1 i i i i
19:00
Time
01:00
07:00
13:00
19:00
Mostorod - Tanta
Fluid Treated
Fuel Oil
Crude Oil
255
328
290
404
13.7%
23.2 %
Drag Reduction, %
19.5
35.4
150
115
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December 2004
Application Result:
DRA Concentration (PPM)
Flow Increase (%)
AM
23
IL
9-11
17
23
AH
28
19-21
34
53
66
53
34
28-32
47
92
118
95
47
AL
IH
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December 2004
17
References
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EP 256979 (1988)
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