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    The chemistry of coordination polymers has received much attention during the last decade not only due to their fascinating architectures but also due to their applications in many fields like: catalysis, gas storage, magnetism, ion exchange and non linear optics. The objectives of this work focused on studying the coordination chemistry towards transition metals of polycarboxylate multidentate ligands which present a semiflexible behavior such as 1,4 phenylenebis(oxy)diacetic acid, 1,2 phenylenebis(oxy)diacetic acid and the hybrid multidentate ligands 1,2 phenylenebis(thio)diacetic acid and N,N,N’N’ 1,2 phenylene diaminetetraacetic acid which contain different donor sites (S, O and N, O respectively) being in this way suitable for selective coordination to specific transition metals. The synthesis of mononuclear building blocks for the rational preparation of coordination polymers was also taken into account.

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    The chemistry of coordination polymers has received much attention during the last decade not only due to their fascinating architectures but also due to their applications in many fields like: catalysis, gas storage, magnetism, ion exchange and non linear optics. The objectives of this work focused on studying the coordination chemistry towards transition metals of polycarboxylate multidentate ligands which present a semiflexible behavior such as 1,4 phenylenebis(oxy)diacetic acid, 1,2 phenylenebis(oxy)diacetic acid and the hybrid multidentate ligands 1,2 phenylenebis(thio)diacetic acid and N,N,N’N’ 1,2 phenylene diaminetetraacetic acid which contain different donor sites (S, O and N, O respectively) being in this way suitable for selective coordination to specific transition metals. The synthesis of mononuclear building blocks for the rational preparation of coordination polymers was also taken into account.

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    Attribution Non-Commercial (BY-NC)
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    13 tayangan1 halaman

    Cover Simple

    Diunggah oleh

    oedip74
    The chemistry of coordination polymers has received much attention during the last decade not only due to their fascinating architectures but also due to their applications in many fields like: catalysis, gas storage, magnetism, ion exchange and non linear optics. The objectives of this work focused on studying the coordination chemistry towards transition metals of polycarboxylate multidentate ligands which present a semiflexible behavior such as 1,4 phenylenebis(oxy)diacetic acid, 1,2 phenylenebis(oxy)diacetic acid and the hybrid multidentate ligands 1,2 phenylenebis(thio)diacetic acid and N,N,N’N’ 1,2 phenylene diaminetetraacetic acid which contain different donor sites (S, O and N, O respectively) being in this way suitable for selective coordination to specific transition metals. The synthesis of mononuclear building blocks for the rational preparation of coordination polymers was also taken into account.

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    pdf 1 10/13/2010 2:23:11 PM

    Coordination Polymers of Polycarboxylates: Design, Synthesis and Structures


    The chemistry of coordination polymers has received much attention during the last decade
    not only due to their fascinating architectures but also due to their applications in many fields
    like: catalysis, gas storage, magnetism, ion exchange and non linear optics.

    The objectives of this work focused on studying the coordination chemistry towards transition
    metals of polycarboxylate multidentate ligands which present a semiflexible behavior such as
    1,4 phenylenebis(oxy)diacetic acid, 1,2 phenylenebis(oxy)diacetic acid and the hybrid
    multidentate ligands 1,2 phenylenebis(thio)diacetic acid and
    N,N,N’N’ 1,2 phenylene diaminetetraacetic acid which contain different donor sites
    (S, O and N, O respectively) being in this way suitable for selective coordination to specific
    transition metals.

    The synthesis of mononuclear building blocks for the rational preparation of coordination
    polymers was also taken into account.

    CM

    MY

    CY

    CMY

    Coordination Polymers
    of Polycarboxylates:
    Design, Synthesis and Structures
    PhD Thesis - Ioana Grosu

    Faculty of Chemistry and Chemical Engineering Institute of Inorganic Chemistry


    “Babes-Bolyai” University Universität Leipzig
    2010

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