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6 (a) are listed in the table below

The pK" values o{ four carboxyiic acids

Ko
Fonrrula of acid
u

t
I
and
slrengtlt shown by acids L2
ii) Describe afld sxptair'r th€ t€rrd in ecisic
*^t\ ) :t>t \
fiar\re

{Ii}Giveanexplanationfolt|.led?fferenceinthepKav*luesforacids2and4

add (acid 1}
{iii} Calculste lhe sf a 0.0't0 rnol dmi solu'tion o{ proparroic

i6m)
or| "-.Et rlr^
- r''.r
Pu(' -'{-'1 (rLrl
1l'\T

#Q
hydroxide h*e a lrglnqds3lj{e-$g cf
6(b) The sotubirity produnt,.Kr*, o{ magnesium

$taling its unitc


iilwri!.e an expre*ion for tne@,

tir)UsethevalueofK*giventoca|culatethaooncentrstionofMg(oH}zina
saNrated ealution"

{iii}Ep|ainwhethermagnetiurnhydrcxid*r*ouldbeftlorasol$bleor|8ss
than in water'
solu-ble ln S,t motdm{ Mg$Ortaq} {5m}

6 (c)
fiil Catcula& the mas* of *Wds that needx to be addBd to 450
pradtrce a Eolution with pH
t 9'0
crns of 0.{ 0 rnot dm"3 arnrnonia to
{4mi
Ilt of NH3 = 1'7 x 10'5 rnol dm'] l

7 (a) {b*teliet'r PllociPle- (2m)


St*te Le

7 (b) Re⋼1 to ii:e eryulibririm r:r - $ft( r-r rr


+UH:ig) I <s $NOig) +
5O:{gl oH;O(g} lH=-90SIJumf'

Lrplain
e ts
($ ibe eftk{ c*l the fel d of }{O rafien prEll}tsE rll} equilitniuu urlshu
ull:Ie8$eo
cosJLlol' Id" u'bel teuryaratrue ou tlre
eqtrilihiuor (4ni)
fii'l tbe etlct +tl egtrilibriun
rtlxtrirt is decrea*ed'

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