** For buffer solutions the weak acid must have a pKa within one pH unit of the desired buffer pH.
**In titrations:
At the halfway point to equivalency HA will equal A-
HA + OH- ↔ H2O + A –
1.0M 0.5M
-0.5 -0.5 +0.5
0.5 0.5
Questions 12-13
a) Lithium b) Nickel c) Bromine
d) Uranium e) Fluorine
9) When equal masses of the following
12) Is a gas in its standard state at 298 K.
compounds are dissolved in water, which is
13) Reacts with water to form a strong base.
expected to conduct electricity the most?
a) MgCl2 b) CH3CH2CH2OH c) SO3
d) KMnO4 e) HCO2H
Written Questions:
1) Calculate the pH of 30.0 mL of 0.200 M acetic acid solution after the following volumes of
0.200 M NaOH have been added. The Ka for acetic acid is 1.8 X10-5.
a) 10.0 mL
b) 15.0 mL
c) 35.0 mL
2) a) The binary acids (HCl, HBr, HI) in aqueous solutions show no difference in acidity.
These three acids in a nonaqueous solvent like acetone or glacial acetic acid are observed to
have the following order of acid strength: HI > HBr > HCl. What accounts for the different
observations in water and nonaqueous solvents?
b) The pH scale can be used to indicate the availability of hydronium ions in aqueous solutions.
The hydronium ion concentration is related to pH by the following equation [H3O+] = 10-pH. A
laboratory worker reports observed pH values of –0.1 and zero. Are these values realistic?
Justify your answer, and give examples that support your answer.
3) NaC2H3O2, Ba(NO3)2, KCl
Aqueous solutions of equal concentration of the three compounds listed above are prepared.
What would an experimenter expect to observe when each of the following procedures is
performed on each of the solutions?
a) The pH of each solution is measured.
b) Pb2+ ions are introduced into each solution.
c) SO42- ions are introduced into each solution.
d) The freezing point of each solution is measured and the three temperatures are compared.
4) Give explanations in terms of Lewis structures, electronegativity differences, and apparent
oxidation numbers.
a) What is the explanation for the decreasing acid strength in the following series of acids:
HClO4, HClO3, HClO2?
b) What are the predicted relative base strengths for ClO41-, ClO31-, ClO21-?
5) Give a brief explanation for each of the following:
a) Water can act either as an acid or a base.
b) HF is a weaker acid than HCl.
c) For the triprotic acid H3PO4, Ka1 is 7.5 X 10-3 whereas Ka2 is 6.2 X10-8.
d) Pure HCl is not an acid.
e) HClO4 is a stronger acid than HClO3, HSO4-, or H2SO3.
b) Discuss at least two ways in which the sketch in (a) differs from the plot that would
result from the titration of a strong, monoprotic, like HCl.
c) The student has a choice between the two indicators: methyl red (pH range 4.8-6.0) or
phenolphthalein (pH range 8.2-10.0). Which should she choose? Justify your response.
d) While the student was performing her first trial, she dispensed 50.0 ml of titrant (base)
from her buret (the maximum), but her analyte (acid) still had not changed color. What
is the most likely source of her error (assume that she did put an indicator in the
analyte)?
e) How would the graph in (a) be different from that of a titration between a weak base
and a strong acid?
12) The solubility of calcium oxalate, CaC2O4, is 6.1 X 10-3 g per liter at 25 oC.
a) Determine the molar solubility of CaC2O4 at 25 oC.
b) Write a balanced equation for the solubility equilibrium.
c) Write the expression for the solubility product constant, Ksp, and calculate its value.
d) If CaC2O4 is placed in a 0.10 M CaCl2 solution, how will this affect the molar
solubility? Explain, and show calculations to support your answer.
e) If 50.0 mL of 0.0025 M CaCl2 is added to 50.0 mL of 1.0 X10-5 M Na2C2O4, will any
calcium oxalate precipitate?
13) Solve the following problem related to the solubility equilibria of some metal hydroxides in
aqueous solution.
a) The solubility of Cu(OH)2(s) is 1.72 X10-6 gram per 100. milliliters of solution at 25 oC.
i) Write the balanced chemical equation for the dissociation of Cu(OH)2(s) in
aqueous solution.
ii) Calculate the solubility (in moles per liter) of Cu(OH)2 at 25 oC.
iii) Calculate the value of the solubility-product constant, Ksp, for Cu(OH)2 at 25
o
C.
b) The value of the solubility-product constant, Ksp, for Zn(OH)2 is 7.7 X10-17 at 25 oC.
i) Calculate the solubility (in moles per liter) of Zn(OH)2 at 25 oC in a
solution with a pH of 9.35.
ii) At 25 oC, 50.0 milliliters of 0.100 M Zn(NO3)2 is mixed with 50.0
milliliters of 0.300 M NaOH. Calculate the molar concentration of Zn2+(aq)
in the resulting solution once equilibrium has been established. Assume
that the volumes are additive.
14) Lead iodide is a dense, golden yellow, slightly soluble solid. At 25 oC, lead iodide dissolves
in water forming a system represented by the following equation.
PbI2(s) ↔ Pb2+ + 2 I- ∆H = +46.5 kilojoules
The solubility-product constant, Ksp, for PbI2 is 7.1 X10-9 at 25 oC.
a) How does the entropy of the system PbI2(s) + H2O(l) change as PbI2(s) dissolves in water
at 25 oC?
b) If the temperature of the system were lowered from 25 oC to 15 oC, what would be the
effect on the value of Ksp? Explain.
c) If additional solid PbI2 were added to the system at equilibrium, what would be the
effect on the concentration of I- in the solution? Explain.
d) At equilibrium, ∆G = 0. What is the initial effect on the value of ∆G of adding a small
amount of Pb(NO3)2 to the system at equilibrium? Explain.
15) HOCl ↔ OCl- + H+
Hypochlorous acid, HOCl, is a weak acid commonly used as a bleaching agent. The acid-
dissociation constant, Ka, for the reaction represented above is 3.2 X 10-8.
a) Calculate the [H+] of a 0.14-molar solution of HOCl.
b) Write the correctly balanced net ionic equation for the reaction that occurs when NaOCl
is dissolved in water and calculate the numerical value of the equilibrium constant for
the reaction.
c) Calculate the pH of a solution made by combining 40.0 milliliters of 0.14-molar HOCl
and 10.0 milliliters of 0.56-molar NaOH.
d) How many millimoles of solid NaOH must be added to 50.0 milliliters of 0.20-molar
HOCl to obtain a buffer solution that has a pH of 7.49? Assume that the addition of the
solid NaOH results in a negligible change in volume.
16) The solubility of silver chromate, Ag2CrO4, is 0.0280 g per liter at 25 oC. The molar mass
of silver chromate is 331.8.
a) Write (1) the chemical equation for the dissociation of silver chromate, and (2) the
equilibrium law for this process.
b) The equilibrium constant for the equilibrium law in part (a) is called the Ksp. Determine
the value of the Ksp.
c) The Ksp for silver chloride, AgCl, is 1.8 X10-10. What is the minimum concentration of
Na2CrO4 needed to form a precipitate of Ag2CrO4 in a saturated AgCl solution?
d) How many grams of silver chromate can dissolve in 750 ml of a solution that is 0.00200
M in Na2CrO4? What does this problem illustrate?