I SeriesSSOI

Code No. 56/1 CI5Ts -;j.

RoUNo. W1 ;t.

I

Candidates must write the Code on the title page of the answer-book.

rRt&TTcif q;)g em ~'W~d)1 in ~-TSO 1R~~1

• Please check that this question paper contains 12 printed pages.

• Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate ..

• Please check that this question paper contains 30 questions.

• Please write down the Serial Number of the question before attempting it.

• 15 minutes time : has been allotted to read - this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the student will read the question paper only and will not write any answer on the answer script during this period.

• 'Z''illl ~ CfJ1: ~ fcfi ~ ~,.q;f .q ~ 'rB" 12 ~ I .

• ~-q;f if ~ ~ ctt 3W: fu:Q: ~ ~ ~~ rn;r ~-~ it ~-'rB" lR ~

• 't''-Illj ~ qj{ "# F.f; ~ _~-q;f- if 30 ~ ~ I

• ~ ~ CfiT ~ f#t'lSl."iI. ~ ~ * ~, ~ CfiT ~ ~ Wnj ·1

• ~"j .>!T-1-q;f ~ ~ it full: 15 fi:r;;rc:" "ijif ~ ~ 1"]"711 ~ 1 ~_;-q;:r qjf fcrcRuT ~ if

10.15 ~ ~ ~I 10.15 ~ -B 10.30 ~ (fcf; rn;r ~ ~-~ ~ ~ ~ r ~ ~ .~ ~ ~-~.lR ~. ~ ';f@ ft1&it

CHEMISTRY (Theory) ~:a-Iq~ fa$1I""1 (<ft;a:IRtas)

Time allowed : 3 hours

Maximum Marks : 70

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General Instructions :

(i) All questions are compulsory.

(ii) Marks for each question are indicated against it.

(iii) Questions number 1 to 8 are very short-answer questions and - carry 1 mark each.

(io) Questions number 9 to 18 are short-answer questions and carry 2- marks each.

(v) Questions number 19 to 27 are also short-answer questions andcarry 3 marks each.

(vi) Questions number 28 to 30 are long-answer questions and carry 5 marks each.

(vii) _. UseLog Tables, if necessary. Use of calculators is not allowed.

71ft{P:{ ~: .

(i) 'flm JTH a#rqpj e· I

- (ii) >rritcn JlFT ~. wrR 3fc!i GYrfr!: w: ~ I

(iii) JiN-#&.n 1 "# 8 rrq; 31Frr Cfg-3ffftlr JfF{ $. I ~ JfR it Rw: 1 3fcn W I

(iv) JlFT- ms.m 9 "# 18 rrq; ftj-3"ff7Jzr J[.'R $: I >rritcn J[.'R ~ Rw: 2 a:{Fn ? (

(v) JrR-#&.n 19 -# 27 rrq; 'iff ftj-~ J{Ff e' I ~ JTH it Fc7r!: 3 3fq; #. I

(vi) srR-#mr 28 it 30r{tFf-3ffftlr JlFT ~ I J{fitq; .JT!R ~ Rw: 5 afq; ~ I

(vii) 3114'?4ChdljRI'!. c#Tr ~ q;r m Cfif I JJCjic1z <Y it31P-itrr ctt ~ ;r@'

W I

1. How do metallic and ionic substances differ in conducting electricity ? 1

2. What is the 'coagulation' process? '~' (coagulation) >mill cp;rr mru ~. ?

1

3. What is, meant by. the term 'pyrometallurgf, ? 'm-q_~J ~ q:lff mN<f ~ ~ )

1

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4. Why is red phosphorus less reactive than white phosphorus? ~ !"flIM{tl. ~ ~ BTB !"fllei1{fl Clilf 1%J.1I1i1nd ~ mm ~ ?

1

5. Give the IUPAC name of the following compound :

H2C= CH - CH -, CH2- CH2 - CHa [

OB

RL'lRiRs!f1 ~ enr IUPAC ~ ~

H2C = CH - CH - CH2 - CH2 - CRa I

OB

1

6. Write the structural formula of I-phenylpentan-l-one. 1

l-itR(1q~+l-aiR enr ~ ~ ~ I

7. Arrange the following compounds in an increasing order of basic

strengths in their aqueous solutions: 1

NHa, CHgNH2, (CHg)2NH, (CHg)aN

r1L'1f('tf@d ~ cit rn ~ Rlflll'il if ~ ~ '~ '~ ~ $ll if ~:

NHa, CHaNHz' (CHa)2NH, (CHg)aN

8. What does '6,6' indicate in the' name nylon-6,6 ? 1

~-6,6 -;w:r if ftmn '6,6' tflll ~ qj"{Gf ~ ? .

9.. What type of cell is a lead storage battery? Write the anode and the cathode reactions and the overall cell reaction occurring in the use of a

lead storage battery. 2

'OR

Two half cell reactions of an electrochemical cell are given below MnO~ (aq) + 8 H+ (aq) + 5 e- --7 Mri2+ (aq) + 4 H20 (l), EO' = + 1·51 V

8n2+ (aq) --7 8n4+ (aq) + 2 e", EO = + 0·15 V

Construct the redox equation from the two half cell reactions and predict if this reaction favo-urs formation of reactants or. product

mown in. the equation. 2

3

P.T.D.

mm B~I '*'fl ~. ~ WfiR cpr itfr ~ ? mmB'i:lllJatl ~ if m ~ ~. t-rrs ~ ~ lR· m ifR;ft ~ am: ¥1 fil<1ICh{ iR crrtft iR1 ~ q;) ~I

3l2fCn

~. fmJcl-{I'HllJR<".fl ·iRvr· $ en 31~ itffi ChI 3lMRt;lJl~ ~ ~ ~ :

MnO~ (aq) + 8 H+ (aq) + 5 e - ---7 Mn2+ (aq) + 4 H20 (I), EO = + 1·51 V Sn2+ (aq) . ---7 Sn4+ (aq) + 2 e -, EO = + 0·15 V

?J;IT -wf "ffi1 aTI~3if it WCRi (314'lqijlJ) HI11Cfl{ol f.rmfu:r .~ am ~ ~ fct; 7$ ~ fll:fl Cfl (0 I ~ ~ 3f1!fo'IT ~ W $T ~ ,~I

e,

10. Define the following' :

(i) Elementary step in a reaction

(ii) Rate of a reaction

RyFc'1Md ChI qR'l1ltill~ ~ :

(i) a:rf~ "ChT 5I121fl-iCh (elementary) WI

(ii) ~~

2

11. Describe the underlying principle of each of the following metal

refining methods .: 2

(i) Electrolytic refining of metals

(ii) Vapour phase refining of metals

~ qR!ifl{ul ChI f.p"'-!fc'1R9:d ~ ~ ~ ffl05:l<Ji "ChT quf;J .~ :

(i) ~3# CfiT ~-3lqEl2.;n qR'!ifl{ol

(ii) ~3# CfiT "Cf[5f ~ qR!ifl(ol

12. Complete the following chemical reaction equations :

(i) XeF 2 + H20 ---7

(Ii) PHs + HgCl2 ---7

f.jktfc'1f@d (IHI1If.1Cfl ~B4"ICfl{On q;) 1_Of ~ :

(i) XeF 2 + H20 ---7

(ii) PHs + HgC12 ---7

2

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13. Complete the following chemical reaction equations :

(i) MnO~ (aq) + C20;- (aq) + H+ (aq) ---7

(ii) Cr2 O~- (aq) + Fe2+ (aq) + H+ (aq) ---7

RklFC1R9d {lfllllF;Ojq; ~ wnq;{Oll. if ~ ~

(i) :Mn0~ (aq) + C20;- (aq) + H+ (aq) ---7

(ii) Crz O~- (aq) +_ Fe2+ (aq) + H+ (aq) ---7

2

14. Which one in the following pairs undergoes SN1 substitution reaction

faster and why? 2 .

Cl C1

(i) /I~· or ~

Cl

(ii) ~ or ~Cl

f.1klfc1F@\4 ~ if.it ~ ~ SN1 ~ ~ 3TI~ ~ ~ ~ ~ 31R cpif?

(i)

Cl /I~

Cl

(ii) ~ wrcn ~CI

15. Complete the' following reaction equations: (VCH3

(D V + HI ---7

2

(ii) CH3CHzCH = CHz + HBr ---7

RklrC'iRg\4 ~ flI"ilq;{On en) .~ ~ :

CH3

(i) () + HI ---7

(ii) 'CH3CHzCH = CH_2 + HBr ----7

16.. Name the four bases present in DNA. Which one of these is not

present in RNA? ' 2'

'ijf{ ~ ~ ~ ~ ~ DNA if ~'W11'1 ~ I ~ it ~ ~ RNA if rq;~.Jl-tI'"i'

". ~ ") ,

~Q .

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17. Name two fat soluble vitamins, their sources and the diseases caused

due to their deficiency in diet. . 2

q1J[ if ~2H'{fh.1 ~ Fci·i!lfil;:f'i ~ ~, ~ ~ ~ ~ ~ if ri it ~ ~

"~ .... 4-

¢jILJI~ljl <:fl. ~ ~ I

18. Differentiate between molecular structures and behaviours of thermoplastic and thermosetting polymers. Give one example of each

type. 2

dlq+j<iRi (l44fldlfRq;) aiR mq-~ (214f~filr) ~ ctt ~. ~3TI ~ eqq~l{J

if ~ ~ ~ ~ I ~ '5ICfil1: C!iT ~ 3<;1~{UI ~ 1

19. A first order reaction has a rate constant "of 0·0051 min -1. If we begin with 0·10 M concentration of the reactant, what concentration of the

reactan t will be left after 3 hours ? 3

~ w.m W c€t. ~ qif ~ ~. 0·0051 min-1 ~I <ffi!: ~ ~ ~' 0·10 M ~ ~ m?T ~ cR, "fIT 3 ~ ~ 1%cr.:IT ~ ~ WtT ~ ~?

.20. Silver crystallises with face-centred cubic unit cells. Each side of the unit cell has a length of 409 pm .. What is the radius of an atom of silver ? (Assume that each face atom is touching the four corner

atoms.) 3

~ ~-~ ~ .~ 'ffi1 ifl#l~Fc1d ~ ~ I ~ 'ffi1 t ~. ~ c€t ~ 409 - pm ~ I ~ ~. c€t ~ <FIT ~ ? (~ l:JRCfil: ~ fcn ~

q:;('1Chj~ ~ ~ ~ ~ tWfI1J}a# it ~ Cfl{Qf. ~ I) .

21. A copper-silver cell is set up. The copper ion concentration in it is 0·10 M. ~he concentration of silver ion is not known. - The cell potential measured 0·422 V: Determine the concentration of silver ion in the cell.

Given: EO ;;; + 0·80 v, EO = + 0·34 V. 3

Ag + I AgCu 2+ /Cu

~ tfiTtR-fu"fq{ -iRr ~ 1J<lT ~ 1 ~ W ~ c€t ~ - 0·10 M ~- 1 ~

3WH qit ~ 'Wff ~ ~ I m,- ~ ~ 'R 0·422 V trim 1J<lT1 m-r if ~ 3WH<tt~~~1

fc;:GIT 'lfllT~: s". = + 0·80 V, EO ' = + 0·34 V.

_Ag+ / Ag cu2+ ICu

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22. What happens in the following activities and why?

(0 An electrolyte is added to a hydrated ferric oxide sol in water.

(ii) A beam of light is passed through a colloidal solution.

(iii) An electric current is. passed through a colloidal solution. r~kJr(1R911 ~3lT ~ 'FIT ~. ~m <FIT ?

(i) ~ -ij '5'lM41Md ~341ifHI~s ~ ~ ~ ~~_ &rRr 'ffi'?IT *

(ii) ~ cilMT~il ~ ~ "it. Wllro :fl ~ fcfim ~ ~ I

(iii) ~ cti1MT~,~n ~ ~ ~ ~ ~ ~ ctt ~. * I

23. Giving a suitable example for each, explain the following:

(i) Crystal field .splitting

(ii) Linkage isomerism

(iii) Ambidentate ligand

OR

3

Compare the following complexes with respect to structural shapes of -

units, magnetic behaviour and hybrid orbitals involved in units 3

[Co(NH3)e13+, - [Cr(NH3)6J3+, Ni(CO)4 (At. Nos.: Co:::; 27, Cr == 24, Ni:: 28)

~ t ~ 1;Cfi-~ ~ 3<;IQ{OI ~ ~ H14f(1r~9:Cl ctt ~. ~ :

(i) .~ f$r fcrcnz;J

(ii) ~ Bl1lClllcldi

(iii) "3"~ (QfIkl~<l2:) ~ -31~

FP8f(1f€Rl -wRf (Cfllu:d2R"ll) ctt WRT ~. ~ ctt ~. awpfu, ~cfi111 ~

~ ~ W-R 34T~2('11' it ~ if·~: - , .

[Co(NH3)e]3\ [Cr(NH3)6]3+, Ni(CO)4

-- '1 ~ : Go :::; 27, Cr:::; 24, Ni == 28)

.2_ ~ ';!:am the following observations : 3

., The boiling point of ethanol IS higher than that of methoxymethane.

n Phenol is more acidic than ethanol.

(iii, 0- and p-nitrophenols are more acidic than phenol.

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f.l kjfQi nsHi 31 cH.:11 Cf) •. ;'[ Chl am§!IT ~ :

(0 ~~ q}T q-q~ ~~ ~ ~. it ~ mm ~

(ii) ~ ~ it' 3TI% ~ ~ ~. I

. (iii) 0- am P-"II~~l'q))FilE.1 ~ ~ it am ~ Ql-R ~

25. How: would you account for the following:

(D Many of the transition elements and their compounds can act as good catalysts;

(ii) The metallic radii of the third (5d) 'series of transition elements are virtually the same as those of the corresponding members of the second series.

3

(iii)

There is a greater range of oxidation states among the actinoids

. .

than among the lanthanoids .

. 31T':r RklfE.1fuH1 .~ q<:IT ~. ~ ~ :

0) ~ -?r ~ ~am ~ ~ ~ ~ Cf;f q;p;f "Cfl0 .~ I

(ii) ~ m=qTChl ffi1:m (5d) €tuft ~. mcif cn1 ~ ~ "WfqTf ~ mm % ~ ~ ijuft ~ dffi~<4t m:cif Chl mm % I

(iii) ~f0f2'"lI~sl· if 3QiP·H ~3TI cpT l1""{R1 ct~'"lI$SI Chl ~. aTI'tlCIl· ~ ~

26. Complete the following reaction equations:

3

(D

°

II LiAlH4

R-C-NHz

(ii)

C6H5N2Cl + HsPOz + H20 ~ C6H5NH2 + Brz (aq)~

(iii)

F-iklfflft;m ~~ fl41Cf){On cit· ~ ~ if ~ °

II LiAIH4

.(i) R - C - NH2 H °

. 2

(ii) CsHsNzCl + H3P02 + H20 ~

(iii) C6H5NH2 + Brz (aq) ~

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27. Describe the following substances with one suitable example of each

type: .3

(i) Non-ionic detergents

(ii) Food preservatives

(iii) Disinfectants

~ cnr ~-~ ~ 3C!JQ{UI ~ ~ f.:p:'lr(1r~d ~ CfiT CfU"R ~ :

(i) a:r;:r-awrf.:rq:; 31 q 41 ~q;

(ii) "&ro ~

(iii) _ ~jIIUJ'1I'?fi

28. (a) Define the following terms:

(i) Mole fraction

(ii) Van't Hoff factor

(b) 100 'mg of a protein is dissolved in enough water to make 10·0 m.L of a solution, If this solution has an osmotic pressure of 13·3 mm Hg at .25° C, what is the molar mass of protein?

(R :;:: 0·0821 L atm morl K ~l and 760 mm Hg ;;;: 1 atm.): 5

OR

(a) What is meant by :

(i) Colligative properties

(ii) Molality of a solution

(b) What concentration of nitrogen should be present in a glass of water at room temperature? Assume a temperature of 25° C, a total pressure of 1 atmosphere and mole fraction of nitrogen in

air of 0-78_ fKH for nitrogen » 8-42 x 10~7 Mlmm Hg] 5

(a) f'1yf<1R9d ~ it ~ ~ :

CD ~ am

(ii) qiz ~~.

(b) ~ mtf;r tt 100 rng ~ coT ~ \S'R1 if·~· 10-0 mL ~ ~ lP-TI1 * 25° C "4"{ ~ ~ CfiT 4{IB{On c:.raf 13·-3 rum Hg QT, m ~ CfiT ~S::&141.'1. "C'f!IT Wrrr ?

(R::;; 0-0821 L atm mol~l K-1 am: 760 mm Hg ::;; 1 atm.) 3t~

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(a) r-iyF<:lMd 'it <:FIT ~ ~ :

(i) 31OJB&l ~

(ii) ~ Cfit ~~(1(1dl

(b) ~ ~ mq ~ ~ ~ ~ fiwrm it ~ 'i1~~lGl"i qrr .. ~ <:FIT WIT ? ~ ~ fcE mq 25° C ~ am: ~ <ITS G11if 1~2:4IWhll{ ~, am: ~ it 11~~lGl'i CIlf "4Ta ~ 0·78 ~I HI~~IGl'1 it ~ KH::;: 8·42 X lO~7 .M/mm Hg]

29. (a) Draw the structures of the following :

(i) H2S20s

(li) HCI04

(b) How would you account for the following:

(i) NHs is a stronger base than PHa.

(ii) Sulphur has a greater tendency for catenation than oxygen.

(iii) F 2 is a stronger oxidising .agent than C12.

OR

5

(a) Draw the structures of the following:

(i) HZSZ07

(ii) noio,

(b) Explain the following observations:

(D In the structure of HNDa ' the N - D bond

(121 pm) is shorter than the N- OH bond (140 pm),

(ii) All the P - Cl bonds in PCl5 are not equivalent.

(iii) leI is more reactive than I2.

(a) Ryrdfuld em B(iHI~ ~ ~.:

(1) H2SZOS

(Ii) HCI04

(b) r-iklfdmm ~ .q,l Cj)RUJ ~ g;t; ~ ~ :

(i) PHs qit ~ NH3 am ~ &lR ~ I

(ii) 3l1Cf8IGl'1 ~ ~ ~ it ~ Cfit ~ an~~ ~ I,

(UI) . Clz qft ~ F z ~ ~ 3l1Cf81."flH"fl i I

3lm:rr

5

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(a) f,:p:"'""lR1Rshi ctt €{iHI~ ~ ~ :

(i) H2S207

(ii) HCI03

(b) f'"'lj;jrt1r~~ 3IClc1ICfi"j'j ett '&fT&lT ~ :

(i) HNOa ctt ~- -q, N - ° ~q (121 pm) ~ N - OH ~q (140 pm) ~ ~ ~ I

(ii) - PCIs if.~ P - CI ~ 1!;Cfi it ;@ ~ (iii) 12 <tt aNan ICI~ f¢ll-ljl~ftC"l ~ I

30. (a)

Write chemical equations to illustrate the following name bearing reactions:

(i) Cannizzaro's reaction

(ii) Hell-Volhard-Zslinsky reaction

(b) Give chemical tests to distinguish between the following pairs of compounds:

_ (i) Propanal and Propanone

(ii) Acetophenone and Benzophenone

(iii) Phenol and Benzoic acid

5

OR

(a) How 'will you bring about the following conversions:

(i) Ethanol to 3-hydroxybutanal

(ii) Benzaldehyde to Benzophenone

(b) An organic compound A has the molecular formula CSH1602. It gets hydrolysed with dilute sulphuric acid and gives a carboxylic acid B and an alcohol C. Oxidation of C with chromic acid also produced B._ C on dehydration reaction gives but-l-ene. Writeequations for the reactions involved.

5

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(a) H.klf(.1R9:(1 ~ ~aU <it {.IBlllf-iiOb_ w"llCh{OI ~ ~ ~ :

(i) <%f'"i~lil Chl ~

(ii) ~-~-;iif8w~_

(b) Hklf(.1M(1 ~ ~ if f1:Rmr Chl .~ W ~ .~ ~-~ {FHlllf-iiOb ~ ~:

(i) ~ am ~ it -

(1'1') ~ n ~~" "'~ ~ "' ,," ;>;

:B"2.~I--IH ?11( ~-;sti41I~H 4-1-

(iii) ~ am ~;;;sil~Ch ~ it

a:r~

(a) - HH1(.1~d ¥\qj;;'1{OI a:jl11 tit ~ :

(i) (ii)

(b) ~ ~ ~ A (~ ~ CSH1S02) <it G:I B~2fi ~it ~-3'1qEjR:('j ~ Tf"lIT ~ ~ CfIlaflRruf(1Ch ~ B 31Tt ~ ~("i:h~\11~. C ·\3CtlIf(;d ~3TI I C ~ ~ ~ t m?T \3qillj<] it m B >rfT-(f.~ ~ I C cnr f"~C11Cfl{ol W 'Y\ ~-l-f.r >rfT-(f mm ~ I Br~f%d ~3rf t ~ BIil&i{on <it ~ I

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