The test data has been split into 6 groups

Data set 1 = 1:1000

Data set 2 = 750:1750
Data set 3 = 1500:2500
Data set 4 = 500:3000
Data set 5 = 2750:3750
Data set 6 = 250:5000

The assumed transfer structures are

By taking one data set at each time the six model structures were obtained and the comparison
graph is also drawn. The best fit is noted down.

For Data set 1

Comparison graph for Data set 1
6
x 10
4.8
ze1; measured
4.7 m1; fit: 67.86%
m2; fit: 68.28%
4.6 m3; fit: 76.67%
m4; fit: 47.08%
4.5 m5; fit: 82.35%
CV Gas(J/K)

m6; fit: 67.5%

4.4

4.3

4.2

4.1

4
100 200 300 400 500 600 700 800 900 1000
Time(sec)

1
 Suitable model (82.35% Fit) =

G11 G12 G13 G14 G15

Kp 1.7906e+006 -1.2939e+005 1.1792e+005 6.6129e+008 1.9399e+007
 162.22 5.7743 6.8106 2.0042e+006 1.671e+005
Tw 1.9893 0.76345 0.71527 320.19 407.13

For Data set 2

Comparison graph for Data set 2
6
x 10
4.8 ze2; measured
4.7 m1; fit: 78.68%
m2; fit: 82.98%
4.6 m3; fit: 88.28%
m4; fit: 37.8%
4.5
m5; fit: 56.11%
CV Gas(J/K)

4.4 m6; fit: 91.2%

4.3

4.2

4.1

4
3.9

800 900 1000 1100 1200 1300 1400 1500 1600 1700
Time(sec)

Suitable model :1 (82.98% Fit) =

G11 G12 G13 G14 G15

Kp -3.1664e+005 -1.3587e+005 1.3202e+005 2.3589e+009 -5.6058e+008
Tp1 0.0010007 5.2894 5.9514 3.0854e+008 59354
Tp2 18.728 3.8791 5.9431 0.001 0.4485

Suitable model :2 (88.28% Fit) =

G11 G12 G13 G14 G15

Kp 4.1721e+006 -1.4751e+005 1.5475e+005 1.9787e+005 1.0676e+006
Tp1 894.26 9.6881 13.535 18.279 908.06
Tz1 -3.8832 -1.1184 -2.022 -6.3234 -65.387

Suitable model :3 (91.2% Fit) =

G11 G12 G13 G14 G15

Kp 2.6514e+006 -1.3942e+005 1.3483e+005 7.9376e+005 1.2947e+006
Tw 125.98 4.6532 5.5875 122.73 8.243e+007
 2.5822 1.0174 0.98618 3 45658
Tz 7.3598 -0.13474 -1.4685 165.15 8.3424e+007

2
 For Data set 3

Comparison graph for Data set 3

6
x 10

4.7 ze3; measured

m1; fit: 85.52%
4.6 m2; fit: 82.5%
m3; fit: 88.19%
4.5 m4; fit: 73.18%
m5; fit: 74.4%
4.4
CV Gas(J/K)

m6; fit: 77.92%

4.3

4.2

4.1

3.9

1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 2500
Time(sec)

Suitable model :1 (85.52% Fit) =

G11 G12 G13 G14 G15

Kp -5.6597e+006 -1.5733e+005 1.6778e+005 2.3434e+005 9.5329e+006
Tp1 1687.2 12.13 16.332 19.068 897.23

Suitable model :2 (88.195% Fit) =

G11 G12 G13 G14 G15

Kp 1.3092e+009 -1.4336e+005 1.4039e+005 1.0117e+005 -1.603e+009
Tp1 1.0685e+009 6.8778 6.9117 12.259 72.445
Tp2 0.0010142 3.0664 5.3097 3.742 3.4604e+007

Suitable model :3 (85.52% Fit) =

G11 G12 G13 G14 G15

Kp -2.1242e+008 -1.4809e+005 1.4939e+005 2.2264e+005 1.1306e+007
Tp1 1.2364e+005 10.601 13.221 16.292 1259.8
Tz1 -19.985 -0.82113 -1.6125 -3.6618 -5.6213

For Data set 4

Comparison graph for Data set 4

3
 6
x 10
4.8 ze4; measured
4.7 m1; fit: 74.77%
m2; fit: 80.47%
4.6 m3; fit: 78.8%
4.5 m4; fit: 75.28%
m5; fit: 23.14%
CV Gas(J/K)

4.4 m6; fit: 54.91%

4.3
4.2
4.1
4
3.9
3.8
500 1000 1500 2000 2500 3000
Time(sec)

Suitable model :1 (80.47% Fit) =

G11 G12 G13 G14 G15

Kp 9.3624e+005 -1.4098e+005 1.3545e+005 1.6607e+006 3.2838e+005
Tp1 194.21 5.9672 7.8335 0.001 632.49
Tp2 15.28 3.5808 3.9319 802.27 0.04123

For Data set 5

Comparison graph for Data set 5

6
x 10
ze5; measured
4.8
m1; fit: 83.06%
4.7 m2; fit: 89.72%
m3; fit: 89.34%
4.6
m4; fit: 83.12%
4.5 m5; fit: 92.95%
CV Gas(J/K)

m6; fit: 49.87%

4.4

4.3
4.2

4.1
4

3.9
2800 2900 3000 3100 3200 3300 3400 3500 3600 3700
Time(sec)

Suitable model :1 (83.06% Fit) =

G11 G12 G13 G14 G15

Kp 1.103e+005 -1.538e+005 1.4996e+005 2.0758e+006 1.1703e+005
Tp1 16.831 11.733 15.503 1371.1 53.433

Suitable model :2 (89.72% Fit) =

G11 G12 G13 G14 G15

Kp -2.7313e+008 -1.36e+005 1.5333e+005 1.5187e+005 -1.0031e+005
Tp1 2.6638e+006 5.9158 13.905 0.0010994 2.8981
Tp2 368.94 3.7535 0.0019776 16.432 0.0012061

4
Suitable model :3 (89.34% Fit) =

G11 G12 G13 G14 G15

Kp 16770 -1.433e+005 1.4957e+005 1.2885e+005 6.3329e+006
Tp1 286.89 9.6865 12.266 12.848 1970.2
Tz1 1471.4 -1.4733 -1.5797 -6.0691 -14.7

Suitable model :4 (83.12% Fit) =

G11 G12 G13 G14 G15

Kp -7.1534e+007 -1.3857e+005 1.1786e+005 57891 -74811
Tp1 2.9352e+007 12.601 0.001 0.0045179 121.42
Tp2 3.8922 12.947 8.1399 0.052871 81.076
Tz1 -54226 15.725 -4.2937 -1.1196 138.39

Suitable model :5 (92.95% Fit) =

G11 G12 G13 G14 G15

Kp -2.349e+008 -1.3714e+005 1.3641e+005 1.2435e+005 -20334
Tw 26303 4.6955 6.0563 10.93 2.6101
 37.328 1.0123 0.95138 0.52484 0.001

For Data set 6

Comparison graph for Data set 6

6
x 10
6 ze6; measured
m1; fit: 72.02%
5.5 m2; fit: 75.22%
m3; fit: 74.67%
5 m4; fit: 49.39%
m5; fit: -246.7%
CV Gas(J/K)

4.5 m6; fit: 81.4%

3.5

500 1000 1500 2000 2500 3000 3500 4000 4500 5000
Time(sec)

Suitable model :1 (81.4% Fit) =

G11 G12 G13 G14 G15

Kp 22046 -1.4357e+005 1.26e+005 -2.9285e+005 8.0575e+006
Tw 192.33 4.3799 5.8201 614.69 115.64
 0.081555 1.1052 0.87428 0.001 12.675
Tz 2601.1 -0.36769 -1.407 -1759 -19.724

5
 Comparison table -% Fit

Dataset 1 Dataset 2 Dataset 3 Dataset 4 Dataset 5 Dataset 6 Avg

67.86 78.68 85.52 74.77 83.06 72.02 76.99

68.28 82.98 82.5 80.47 89.72 75.22 79.86

76.67 88.28 88.19 78.8 89.34 74.67 82.66

47.08 37.8 73.18 75.28 83.12 49.39 60.98

82.35 56.11 74.4 23.14 92.95 -246.7 13.71

67.5 91.2 77.92 54.91 49.87 81.4 70.47

As the model m3 provides the maximum fit % it could the best model structure. The
parameters for this structure for all data set is given in the following table

Parameters for m3 for all the datasets

Dataset 1 Dataset 2 Dataset 3 Dataset 4 Dataset 5 Dataset 6

Kp -2.8099e+6 4.1721e+6 -2.1242e+8 6.1255e+6 16770 1.3717e+6

G11 Tp1 158.26 894.26 1.2364e+5 958.26 286.89 248.07
Tz1 7.4636 -3.8832 -19.985 2.3211 1471.4 -1.7434
Kp -1.4465e+5 -1.4751e+5 -1.4809e+5 -1.375e+5 -1.433e+5 -1.3927e+5
G12 Tp1 10.116 9.6881 10.601 8.9478 9.6865 8.9814
Tz1 -0.7835 -1.1184 -0.82113 -1.2149 -1.4733 -1.5484
Kp 1.6591e+6 1.5475e+5 1.4939e+5 1.3577e+5 1.4957e+5 1.2157e+5
G13 Tp1 447.6 13.535 13.221 10.946 12.266 9.7945
Tz1 13.322 -2.022 -1.6125 -2.1212 -1.5797 -2.8547
Kp 3.0911e+5 1.9787e+5 2.2264e+5 1.5526e+5 1.2885e+5 7.6893e+5
G14 Tp1 25.935 18.279 16.292 14.165 12.848 613.79
Tz1 -3.0107 -6.3234 -3.6618 -7.6892 -6.0691 35.15
Kp -8.6425e+6 1.0676e+6 1.1306e+7 -48623 6.3329e+6 3.0503e+6
G15 Tp1 1046.1 908.06 1259.8 3266.4 1970.2 1311.4
Tz1 -31.714 -65.387 -5.6213 1796.4 -14.7 -36.898