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S e c t i o n III: S u p p l e m e n t a l Literature R e v i e w

Ca-Mg (Calcium-Magnesium)
H. O k a m o t o

The Ca-Mg phase diagram shown in Fig. 1 is redrawn from Cited R e f e r e n c e s


[95Aga]. This phase diagram was obtained by optimization of
37Hau: H.L. Haughton,J. Inst.Met., 61, 241-246 (1937).
thermodynamic data (enthalpy of mixing of liquid Ca-Mg at 750 37Vos: H. Vosskuhler,Z Metallkd.,29, 236-237 (1937)in German.
~ heat content ofCaMg 2 between 477 and 877 ~ [95Aga] and 46Buh W. Bulian and E. Fahrenhorst,Metallforschung, 1(3), 70 (1946)
phase boundary data [37Hau, 37Vos, 47Kle, 55Bur]. inGerman.
The Ca-Mg phase diagram in [Massalski2] was assessed 47Kle: W. Klemm and E Dinkelacker, Z. Anorg. Chem., 255, 2-12
earlier by [88Nay], based primarily on experimental phase (1947)in German.
boundary data that were reported by [37Vos], [46Bul], and 55Bur: E.C. Burke, Trans.AIME, 203, 285-286 (1955).
[47Kle]. [88Nay] also did thermodynamic modeling of this 88Nay: A.A. Nayeb-Hashemiand J.B. Clark,PhaseDiagrams ofBina ry
system. However, the diagram calculated by [95Aga] (Fig. 1) Magnesium Alloys, ASM /nternational, Metals Park, OH, 62-69
may supersede the diagram of [88Nay] because the former is (1988).
9SAga: R. Agarwal, J.J. Lee, H.L. Lukas, and E Sommer,Z. MetaUkd.,
based on more recent thermodynamic data and is in good
86(2), 103-108(1995).
agreement with regard to phase boundary data.

Weight PercentMagnesium
0 10 20 30 40 50 6o 70 so 9o ~oo

842oc:

L
711'C
700,

?
~. 6oo.

(13Ca) 517"C
r 50O.

443"C

200
0 10 20 30 40 50 60 70 80 90 1130

Ca Atomic Percent Magnesium Mg

Fig. 1 The Ca-Mg phase diagram.

490 Journal of Phase Equilibria Vol. 19 No. 5 1998

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