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  • CHP 303-Chemical Reaction Engineering Lab: Reaction Kinetics From An Adiabatic Batch Reactor

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    Kapil Jain
    15 tayangan5 halaman
    This document contains data from an experiment measuring the reaction kinetics of an adiabatic batch reactor. The data includes temperature measurements over time as well as calculations of the rate of temperature change and activation energy. Based on the data, the reaction was exothermic. For stoichiometric ratios, the experimentally determined rate constant was 19.2 L/mol/s and the activation energy was 210.62 kJ/mol. For non-stoichiometric ratios, the rate constant was 0.811 L/mol/s and activation energy was 175.5 kJ/mol. Sources of error included potential heat leakage and manual errors in measuring fast initial temperature changes.

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    This document contains data from an experiment measuring the reaction kinetics of an adiabatic batch reactor. The data includes temperature measurements over time as well as calculations of the rate of temperature change and activation energy. Based on the data, the reaction was exothermic. For stoichiometric ratios, the experimentally determined rate constant was 19.2 L/mol/s and the activation energy was 210.62 kJ/mol. For non-stoichiometric ratios, the rate constant was 0.811 L/mol/s and activation energy was 175.5 kJ/mol. Sources of error included potential heat leakage and manual errors in measuring fast initial temperature changes.

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    Attribution Non-Commercial (BY-NC)
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    15 tayangan5 halaman

    CHP 303-Chemical Reaction Engineering Lab: Reaction Kinetics From An Adiabatic Batch Reactor

    Diunggah oleh

    Kapil Jain
    This document contains data from an experiment measuring the reaction kinetics of an adiabatic batch reactor. The data includes temperature measurements over time as well as calculations of the rate of temperature change and activation energy. Based on the data, the reaction was exothermic. For stoichiometric ratios, the experimentally determined rate constant was 19.2 L/mol/s and the activation energy was 210.62 kJ/mol. For non-stoichiometric ratios, the rate constant was 0.811 L/mol/s and activation energy was 175.5 kJ/mol. Sources of error included potential heat leakage and manual errors in measuring fast initial temperature changes.

    Hak Cipta:

    Attribution Non-Commercial (BY-NC)
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 5

    CHP 303- Chemical Reaction

    Engineering Lab
    Reaction Kinetics from an adiabatic batch reactor

    2/19/2010
    Subgroup 1 of group 4
    Sharoon, Abhishek Anand, Rahul Gupta, Aditya Pant
    ln(1/(t‐
    Time (s) Temp (K) Temp ( C ) dT/dt t)^2*Dt/dt) 1/T

    5 292.95 19.8 0.02 ‐10.8434948 0.003414


    10 293.75 20.6 0.16 ‐8.71341765 0.003404
    15 295.05 21.9 0.26 ‐8.14279061 0.003389
    20 296.65 23.5 0.32 ‐7.82515789 0.003371
    25 298.55 25.4 0.38 ‐7.51431205 0.00335
    30 300.45 27.3 0.38 ‐7.36493026 0.003328
    35 303.05 29.9 0.52 ‐6.82689974 0.0033
    40 305.55 32.4 0.5 ‐6.62369331 0.003273
    45 307.75 34.6 0.44 ‐6.51079932 0.003249
    50 310.05 36.9 0.46 ‐6.17925122 0.003225
    55 312.55 39.4 0.5 ‐5.72854013 0.003199
    60 314.95 41.8 0.48 ‐5.33913936 0.003175
    65 317 35
    317.35 44 2
    44.2 0 48
    0.48 ‐4 79026567
    ‐4.79026567 0 003151
    0.003151
    70 318.95 45.8 0.32 ‐4.72295322 0.003135
    75 319.95 46.8 0.2 ‐4.82831374 0.003125
    80 321.05 47.9 0.22 ‐4.23608084 0.003115
    85 322.35 49.2 0.26 ‐3.25809654 0.003102
    90 322.85 49.7 0.1 ‐3.78645978 0.003097
    95 323.45 50.3 0.12 ‐2.93119375 0.003092
    100 323.85 50.7 0.08 ‐2.716349 0.003088
    105 324.15 51 0.06 ‐2.36712361 0.003085
    110 324.35 51.2 0.04 ‐2.19722458 0.003083
    115 324.55 51.4 0.04 ‐1.38629436 0.003081
    120 324.65 51.5 0.02 ‐1.5040774 0.00308
    125 324.75 51.6 0.02 ‐0.69314718 0.003079
    130 324 85
    324.85 51 7
    51.7 0 02
    0.02 0 69314718
    0.69314718 0 003078
    0.003078
    135 324.85 51.7 0 0.003078
    140 324.95 51.8 0.02 0.003077
    145 324.95 51.8 0 0.003077
    150 324.95 51.8 0 0.003077
    155 324.95 51.8 0 0.003077
    160 324.95 51.8 0 0.003077
    165 324.85 51.7 ‐0.02 0.003078
    170 324.85 51.7 0 0.003078
    175 324.85 51.7 0 0.003078
    180 324.85 51.7 0 0.003078
    210 324.75 51.6 ‐0.00333 0.003079
    240 324.65 51.5 ‐0.00333 0.00308
    270 324 65
    324.65 51 5
    51.5 0 0 00308
    0.00308
    300 324.55 51.4 ‐0.00333 0.003081
    330 324.45 51.3 ‐0.00333 0.003082
    0.983182
    330

    325

    320

    315
    Temp (K)

    310

    305

    300

    295

    290
    0 50 100 150 200 250 300 350
    Time (s)
    Y=A+B*X

    2 Parameter Value Error


    ------------------------------------------------------------
    A 63.97657 5.67396
    0
    B -21544.63512 1774.67442
    ------------------------------------------------------------
    -2
    R SD N P
    ln(1/(t-t)^2*Dt/dt)

    ------------------------------------------------------------
    -4 -0.92734 1.06189 26 <0.0001
    ---------------------------------------------------
    -6

    -8

    -10

    -12
    0.00305 0.00310 0.00315 0.00320 0.00325 0.00330 0.00335 0.00340 0.00345
    1/T
    Results

    1. The reaction between hydrogen peroxide and sodium thiosulphate is exothermic.


    2. For stoichiometric ratio, experimentally k1= 19.2 litre/molsec-1 and, activation
    energy=210.62kj/mol.
    3. For non stoichiometric ratio, experimentally k1=0.811litre/molsec1 and activation
    energy=175.5 KJ/mol.

    Sources of error

    1. Heat leakage may take place.


    2. Rise in temperature is initially very fast so, manual error may occur in noting the
    data.
    3. Graph has curve which continually changes, so calculation depends upon point
    selection.

    Precaution

    1. Initially, data noting should be highly coordinated.


    2. Average slope should be taken.

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