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Industrial Waste Heat Recovery

Industrial Energy RoundTable

Kathey Ferland
Project Manager
Texas Industries of the Future
kferland@mail.utexas.edu

Riyaz Papar, PE, CEM


Director, Energy Assets & Optimization
Hudson Technologies Company
rpapar@hudsontech.com

September 21, 2006


© Hudson Technologies
Welcome & Introductions

Sponsor
US Department of Energy Office
of Energy Efficiency and
Renewable Energy, under a
contract with the State Energy
Conservation Office

© Hudson Technologies
Agenda

‰ Welcome and Introductions

‰ Industrial Waste Heat Recovery Presentation


¾ Concepts & questions
¾ Some ideas and technology examples
9 Sensible preheating
9 Condensing economizers
9 Fumes to fuel / Power generation
9 Mechanical vapor recompression or Thermal compression
9 Industrial heat pumps
9 Chilled water / Refrigeration
¾ Challenges

‰ Round table discussion


© Hudson Technologies
DOE Technology RoadMap

www.eere.energy.gov/industry/energy_systems/pdfs/reduction_roadmap.pdf

© Hudson Technologies
Concepts & Questions

© Hudson Technologies
Concepts & Questions

© Hudson Technologies
Concepts & Questions

‰ What is waste heat recovery?


¾ Industry dependent
9 Glass, metals industry - 750°F
9 PetroChemicals & refining - 300°F
9 Food & beverage industry - 180°F
9 Buildings and facilities - 140°F

‰ How much is it?


¾ Heat content – MMBtuh
¾ Product yield

‰ What is it (substance)?
¾ Contaminated waste steam from fractionating / stripping process
¾ Waste gases from boilers, furnaces, vents, flares, etc.

‰ Can it be recovered?

‰ Can it be used?
© Hudson Technologies
Concepts & Questions

‰ Where is it?
¾ Utility plant
¾ Process unit

‰ What is the environment?


¾ Sensible
¾ Latent
¾ Acidic, etc.
¾ Direct / Indirect contact

‰ When is it available?
¾ Continuous
¾ Batch mode

© Hudson Technologies
Ideas & Technologies

‰ Sensible preheating

‰ Condensing economizers

‰ Fumes to fuel / Power generation

‰ Mechanical vapor recompression or Thermal compression

‰ Industrial heat pumps

‰ Chilled water / Refrigeration

‰ Other ideas from the RoundTable group…..

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Sensible Preheating

‰ Most common form found in the industry

‰ Utility side
¾ BFW preheat
¾ Blowdown / Makeup heat recovery
¾ Combustion air preheat
¾ Compressed air heat recovery
¾ Other…..

‰ Process side – typically some level of pinch or optimization


is done and so the process is highly integrated
¾ Preheat reaction feed streams
¾ Preheat process water
¾ Other…..

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Condensing Economizers

‰ Very predominant in Europe

‰ Relatively recent in the US – less than 5 years in market –


but it has picked up now

‰ Two types
¾ Direct contact
¾ Closed loop

‰ Industrial applications are seeing simple paybacks: 6 months


- 2 years

‰ Several installations, manufacturers, gas companies

© Hudson Technologies
Condensing Economizers

© Hudson Technologies
Condensing Economizers

© Hudson Technologies
Condensing Economizers

© Hudson Technologies
SuperBoiler?

100 25

Not a bigger boiler

Footprint, sq ft per klb/h steam


‰ 80 20
but a better boiler!

Energy Efficiency, %
Higher energy efficiency -

NOx, ppmv
¾ 60 15
more than 95% HHV
¾ Super-low emissions - 40 10
down to 2 ppm NOx
and 5 ppm CO
20 5
¾ Smaller and lighter -
reduce size and weight by
50 percent 0 0
Typical State of the 2020 Super
¾ Competitive performance industrial art* Boiler
¾ Cost-effective boiler

Efficiency Emissions Footprint

* Not all in the same boiler

© Hudson Technologies
1st Generation SuperBoiler

Project Description:
ƒ Gas-fired firetube boiler using
innovative concepts in burner, heat
transfer, heat recovery & control
ƒ Partnered with Cleaver-Brooks

Technical Objectives
¾ 94% efficiency (from 70-83%)
¾ <5 ppm NOx (from 30-100 ppm)

¾ Two sites selected


9 Alabama Rubber Plant
Boiler up and in operation

9 California Fruit Processing Plant


Boiler being built

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Fumes to Fuel Technology

‰ Ford Motor Company & DTE Energy Partnership


‰ VOC concentrator – applicable to chemical plants
‰ Solid Oxide Fuel Cell

© Hudson Technologies
MVR / Thermal Compression

‰ Main intent – Recover latent energy of low pressure


steam
‰ Mechanical Vapor Recompression
¾ Boost the vented steam pressure via an electric motor
driven compressor
¾ Based on compression ratio, energy used by compressor
could be only 10-15% of boiler energy
‰ Thermal Compression
¾ Use of a converging-diverging nozzle
¾ Needs motive steam
¾ Called an Ejector when used to create vacuum

© Hudson Technologies
Industrial Heat Pumps

http://www1.eere.energy.gov/industry/bestpractices/pdfs/heatpump.pdf
© Hudson Technologies
Industrial Heat Pumps

‰ Heat Amplifier
¾ Will need
9 Motive heat (high temperature)
9 Waste heat
¾ Will provide
9 Medium temperature heat
9 Amount of heat provided will be sum of waste heat &
motive heat
‰ Temperature Amplifier
¾ Will need
9 Waste heat
9 Ambient temperature heat rejection
¾ Will provide
9 High temperature heat
9 Amount of heat provided will be difference between waste
heat & heat rejected to ambient

© Hudson Technologies
Waste Heat fired Absorption Chillers

‰ Commercially available – LiBr/water machines


‰ Provide chilled water only
‰ Can use waste heat, low pressure steam

‰ http://www.ornl.gov/sci/engineering_science_technology/cooling_heating_power/pdf/ISHPC-095-2005.pdf
© Hudson Technologies
Refrigeration From Engine Waste Heat

Courtesy: Energy Concepts Company

‰ 160 tons refrigeration at 25F


‰ waste heat from 830 kW gas-fired reciprocating engine
‰ uses both exhaust heat and jacket heat
‰ 8 ft by 8 ft footprint, 9000 pounds

© Hudson Technologies
Waste Heat Refrigeration

‰ Installed in 1997
‰ Recovers 200 barrels LPG per day
‰ Double lift cycle, -25oF from 280oF liquid
stream

Courtesy: Energy Concepts Company


© Hudson Technologies
Ammonia Absorption Refrigeration

‰ At comparable production levels, cost approximates vapor


compression $/ton

‰ Custom units start at $1000 per ton

‰ Subzero temperature industrial systems show cost advantage


over mechanical vapor compression

‰ Ammonia absorption is built to industrial standards. This


means that AA can be directly integrated into the process,
which makes a lot more things possible.

‰ More attractive paybacks (1 to 3 years) are obtained with


debottleneck applications and increased recovery applications.

© Hudson Technologies
Adsorption Chiller

HIJC USA, INC.

© Hudson Technologies
Adsorption Chiller

HIJC USA, INC.

© Hudson Technologies
Challenges

‰ Diverse industrial processes and site specific conditions

‰ Energy price and supply uncertainties

‰ Regulatory uncertainties

‰ Materials durability – Metallurgy

‰ Equipment fouling

‰ Reliability

‰ Safety

‰ Economic feasibility

© Hudson Technologies
Other Comments

‰ Mechanical vapor recompression and thermal


recompression to reuse the waste heat in
distillation overhead as a heat source for reboiling

‰ Useful applications for waste steam at low


pressures, less than 20 psig

‰ Understand where recovery of low level heat has


proven cost effective

© Hudson Technologies
RoundTable Discussion

© Hudson Technologies

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