CHEM
PAPER 1
HONG KONG EXAMINATIONS AND ASSESSMENT AUTHORITY
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HONG KONG CERTIFICATE OF EDUCATION EXAMINATION 2007
CHEMISTRY PAPER 1
Candidate Number
Question-Answer Book
Section A
Marks Marks
Question No.
1. Write your Candidate Number in the space provided 1
on Page 1. 2
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2007-CE-CHEM I-1 1
SECTION A
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Answer ALL questions. Write your answer in the space provided.
1. A is a compound formed from oxygen and magnesium, while B is a compound formed from oxygen and
fluorine.
(a) Draw the electronic diagram of A, showing electrons in the outermost shells only.
(1 mark)
(b) Draw the electronic diagram of B, showing electrons in the outermost shells only.
(1 mark)
2. A student performed an experiment to crack paraffin oil and collect the gaseous products by using a
boiling tube.
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(a) Draw a labelled diagram to show how this experiment can be performed in thePage Total
laboratory.
(3 marks)
(b) (i) The student added a few drops of bromine water into the boiling tube containing the gaseous
products. The brown colcur of bromine water disappeared immediately. Why?
3. The diagram below shows the set-up used in performing a microscale experiment. A drop of hydrochloric
acid was added to the drop of chlorine bleach in a petri dish and the dish was immediately covered with its
lid. Chlorine gas formed by the reaction between chlorine bleach and hydrochloric acid eventually filled
up the whole set-up.
(b) State the expected observation at position C and position D. In each case, write a
relevant chemical equation if a reaction occurred.
(i) Position C
(c) Suggest one advantage of replacing test tube experimnets with microscale experiments.
(1
mark)
multimeter
4. A student learnt from a book that an ancient chemical cell could be made by immersing an aron rod in a
liquid placed inside a copper can. The liquid used was vineagr but not wine. The diagram below shows the
set-up designed by him in silulating the cell.
iron rod
vineagr
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copper can
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(a) Explain, in terms of structure and property of particles, why the liquid inside the ancient
chemical cell was vinegar but not wine.
(2
marks)
(i) Write a half equation, involving iron, for the reaction that at the iron rod.
(ii) Write a half equation for the reaction that occurred on the inner wall of the copper
can.
(2 marks)
(c) The student found that colourless gas bubbles were also given out at the surface of the
iron rod that immersed in vinegar. Explain the observation.
(1
mark)
5. A solid sample contains zinc and copper only. The composition of the solid sample was analysed
experimentally as outlined below:
(b) How can one know that the reaction has been completed? (1 mark)
(e) Assuming negligible experimental errors, calculate the percentage of zinc by mass in the
solid sample. (2
marks)
6. Read the paragraph below and answer the questions that follow.
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steps. In the first step, magnesium oxide reacts with chlorine and carbon to form
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magnesium chlorine. In the second step, the magnesium chlorine formed reacts with
potassium to give magnesium. In 1951, some scienists adopted another chemical
process to obtain magnesium from magnesium chlorine. Potassium is not used in
this process, and there is even no need to use any other chemicals.
(a) Write a chemical equation for the reaction that occurred in the first step of the method used by
the scienists in 1828.
(1 mark)
(b) Name the type of reaction between potassium and magnesium chloride. Why can potassium
react with magnesium chloride to give magnesium?
(2 marks)
(c) (i) What would be the chemical process that can obtain magnesium from magnesium chlorine,
without using potassium or other chemicals, in 1951?
7. This question involves how to distinguish four unlabelled test tubes, each containing one of the following
colourless liquids:
(b) By applying a flame directly to a small amount of each of the colourless liquids, TWO of the
liquids would catch fire.
(ii) For the two liquids that would catch fire, the observations involved during
combustion are different. Suggest the difference in these observations, and explain
your answer.
8. (a) Teflon is a plastic that can be used to make artifical hip joints. Teflon is an addition polymer
of linear structure consisting of carbon and fluorine only. The ratio of the number of carbon
atoms to the number of fluorine atoms in the polymer is 1 : 2.
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(ii) Write the repeating unit of teflon, and suggest a possible monomer of teflon.
Repeating Unit:
Monomer: (3 marks)
(b) Nylon is a polymer that can used to make carpets. A portion of the nylon structure is shown
below:
H H H H
∣ ∣ ∣ ∣
––C––(CH2)4––C––N––(CH2)6––N––C––(CH2)4––C––N––(CH2)6––N––C––(CH2)4––C––
(i) With reference to the given structure, explain whether nylon is a thermoplastic or a
thermosetting plastic.
(ii) Suggest one reason why recycling of used carpets to recover nylon is difficult.
For question 9, candidates are required to give answers in paragraph form. For this
question, 6 marks will be awarded for chemical knowledge and 3 marks for effective
communication.
9. A certain brand of rust remover contains an acid of high concentration. The rust remover can be used for
removing tough rust stains; while the rust remover, after dillution, can be used for removing
comparatively light rust stains.
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SECTION B
(a) Describe briefly how 10.0 cm3 of phosphoric acid can be diluted to 250.0 cm3 with distilled
water in the laboratory.
(2 marks)
(b) Phosphoric acid reacts with sodium hydroxide in the titration according to the following
equation:
Explain why the time needed for the solution to become colourless is different at the two
stages mentioned above.
(2 marks)
(d) In the titration, the 0.025 M sodium hydroxide solution was used as a standard solution.
11. In a chemical plant, extraction of copper from ores involves roasting copper(I) sulphide with air inside a
high temperature furnace. Copper(I) sulphide reacts with oxygen in air according to the following
equation:
Cu2S + O2 2Cu + SO2
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The copper so extracted contains impurities including metals such as silver, iron, zincPage
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gold. The
impure copper is then purified by electrolysis as illustrated in the diagram below:
(a) With reference to the reaction between copper(I) sulphide and oxygen, identify the species
undergoing oxidation and the species undergoing reduction. Explain your answers in terms of
changes in oxidation numbers.
(2 marks)
(b) Explain briefly how impure copper can be purified by electrolysis as illustrated in the diagram
(c) Insoluble impurities deposit under impure copper anode as ‘anode sludge’. According to the
information given, suggest what substances the anode sludge would contain. Explain your
answer.
(2 marks)
(d) ‘The concentration of copper(II) ions in copper(II) sulphate solution remains UNCHANGED
in the above electrolysis.’ Is this statement correct? Explain your answer.
(2 marks)
(e) State TWO advantages of building a factory in which contact process is carried out near the
chemical plant mentioned adove.
(2 marks)
12. Organic compound Z contains carbon, hydrogen and oxygen only. Analysis of Z gives the following
results:
(I) 1.0 g of Z contains 0.401 g of carbon, 0.068 g of hydrogen and 0.531 g of oxygen.
(II) 1.0 g of Z, upon complete vapourisation, occupies 400 cm3 at room temperature and pressure.
(IV) Brown colour of bromine remains unchanged when several drops of bromine in organic solvent are
added to Z.
(ii) Give the systematic name for the compound represented by the structure you suggested
in (i).
(4 marks)
For question 13, candidates are required to give answers in paragraph form. For this
question, 6 marks will be awarded for chemical knowledge and 3 marks for effective
communication.
13. Discuss the similarities and differences between soapy detergents and soapless detergents with reference
to their raw materials, structure and properties.
(9 marks)
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END OF PAPER
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