SECTION A . do wf accept ~ haty fe lene” Ly (a) (4) hair not tied up/ reagent bottle too close to bench edge/ bottle not stoppered/blurred(unclear) label (any 2) (4i) (1) Gopper(IT) sulphate/hydrated copper(II) sulphate/ copper (77) sulphate-5-water/copper(II) sulphate crystal/copper(II) sulphate pentahydrate [Do not accept anhydrous copper(iI) sulphate or copper sulphate. | (2) .No.-of moles of H,S0, used = ~5°. x2 G OOS = 0.2 cud + H,S0, 4 CuSO, + H,0 OY No. of moles of the salt formed = 0.1 Mass of CuS0,.5H,0 formed = 0.1(63.5 + 32 + 16x44 5 X18) ¢ el x 249.5 = 24.95°9 OR Mass of CuSO, formed 0.1(63.5 + 32 + 16 xX 4) = 15.95 {No/wrong unit, deduct 1 mark.) (iii) to speed up the reaction (iv) The filtrate is not concentrated enough(is not saturated) / not enough heating in step II/the filtrate is not concentrated by evaporation after collection in step III (b) (4) (1). A. because -of its very good electrical conductivity -of its low cost =it can be protected from corrosion by the plastic coating [Accept rusting in place of corrosion. } or © because -of its very good electrical conductivity Tits slow rate of corrosion -it can last longer despite its high cost {Award 0 mark for choosing B_and the explanations» SCS—™S (2) B because -of -its' good metaltic strength _ rof-its low cost/fast rate of corrosion ‘overcome by. painting et ~ orc’ because {of its slow tate of cétrosion ‘-it can Rast longer despite it is more expensive. te Sea [2 sing A and the . SEE). explanations. J" > (aay Coating/plating/paint ing/sacri ficial: peokection/ galvanizing/tin-plating, gresshy 7 alecivoe (214) >Metals” have: mobile/ freé/delocalizédj“elettrons to conduct “""s elettricity."- het OS tt [Do not accept metallic bond.] . + Correct. Lling@fequired for the-mark to be given. shward the mark if the method 1s correct. 141 q@) a (yy 1 1 emarks marks(ce) ths Some dit 2 Lecdlad me we mele. (a) (i) 2CHyp + 250, + 16C0, + 18H,0 * Acgeot, Cay = — me oe LoS ts hihty exothermic/produces a large amount of heat, the volume of the qaseous products is greater than that of the resctants/there is an expansion of gases, so the Sfatbhti*Giched dows rapidly during the power stroke. loss of power/carbon soct formed/carbon monoxide produced/ incomplete combustion of fuel (2) (1) Petrol with TEL(tetraethyl lead) added. {Do not accept lead compound or lead. ] (11) To prevent knocking/increase octane number/ to prevent preignition (2) to eliminate toxic(poisonous) /damage to_nervous ” system(brain) by ——__/qvasd “ta podem" 2 lead compound in car exhaust os a at OR to eliminate lead poisoning camry convey, 2 7A {Bot Act accept, Les8 pollytion/narnful to, REAKIAG. ] www Affect” it (3) The hydrocarbons in unleaded petrol have a higher octane number/unleaded petrol contains a higher ” proportion of branch-chain hydrocarbons(alkanes) to e-Ai (ve prevent the engine from knocking/another antiknocking (a) oR Additive (benzene) has been added /MT oe Wedlhy) teat ety! athey ei Lowering the temperature eee The formation of sulphur trioxide in the reaction ‘$3 exothermic, lowering the, reaction temperature will shift the equiljbrium to produce more sulphur trioxide. Increasing the pressure Increase in pressure will shift the equilibrium to produce more sulphur trioxide because the total no. of moles (volume) of reactants is qreater than the no. of mole (volume) of product. case A: = High temperature does not favour the yield of sulphur trioxide, - High pressure causes high production cost Case B: - excess SO, is more expensive = the cost of Pt(the catalyst) is much higher/ Pt is poisoned easily. 1 J marks (1) qa) or 6 marksSECTION B . 2. {a) Label B and Label D Chek ewe J rel oe z Label B because conc. HNO, is corrosive’ 1 Label D because conc. HNO, is an oxidizing agent 1 {Both labels wrong, no mark for the whole part (a).) {To obtain full mark, reasons must match the labels.) {e.g- B & D: nitric acid is corrosive and oxidizing(respectively). B & D: nitric acid is oxidizing and corrosive. =2 & B: nitric acid is oxidizing and corrosive. & B: nitric acid is corrosive and oxidizing. A A (b) (4) Tron(IZ) solution changes from pale green to brown/vellow because conc. nitric acid oxidizes {ron(II) te iron(III)/ NO(g) forms Complex with FeSO, 3Fe** + NO; + 4Ht +4 3Fe™* + NO + 2H,0 1 de OR $Fe6r + Dito, A GaSOr— Pe SOG + HOA ED [Also accept FeSO, + NO + FeSO,.NO} eS T 1OBX we (de wr Gicepr bam rey) 3 Fe art 3 eine), FBURE (ii) A brown fume is evolved 5 1 because conc. nitric acid is reduced by the zinc i granules to give nitrogen dioxide Zn + 4HNO, —+ Zn(NO,); + 2NO, + 2H,0 OR zn + 4H* + 2NO, + Zn* + 2NO, + 2H,0 3marke 6. marke (eG) : i. also | accept att [open system/dangerous set-up=0; reaction vessel=1 but do not accept flask fitted with tap funnel or test tube in place of the flask or test tube holding the acid inside the flask; collection of gas using syringe=1.} (44) No. of moles of nitric acid = 7h0, x0.2 2 = 0.005 caco, # 2H* + Ca + HO + CO, No. of moles of CO, = 0.005/2 ae = 0.0025 ’ Vol. of CO, formed at room temperature and pressure = 0.0025 x 24 = 0.06 dm (60 cm) (we war =1) 1 (144) some CO, dissolves/leaks out before the flask is stoppered [Do not accept experimental error.} 6 marks