Kim tra bi c

Nu tnh cht ho hc ging v khc nhau gia phnol v anilin.

Chng II: An hit A xt cacboxylic Este

Tit 10: ANEHIT FOMIC

I Cng thc cu to 1. ctpt: HCHO hay CH2O H 2. ctct: H C O

Chng II: An hit A xt cacboxylic Este

Tit 10: ANEHIT FOMIC

I Cng thc cu to 1. ctpt: HCHO hay CH2O H 2. ctct: H C O

T CTCT em hya ra nhn xt v d on tnh cht ho hc

Chng II: An hit A xt cacboxylic Este

Tit 10: ANEHIT FOMIC

I Cng thc cu to 1. ctpt: HCHO hay CH2O H 2. ctct: H C O Nhn xt: Trong nhm phn t Anehit fomic c nhm CHO ( l nhm chc ca anehit) Trong c lin kt C=O gm mt lin kt bn vng v mt lin kt km bn nn anehit d tham gia phn ng ho hc. Nhm C = O gy ra nhng phn ng ho hc c trng.

I.Tnh cht vt l

: SGK
c lp nghin cu sgk

II.Tnh cht ho hc

Phn ng cng H2 (Phn ng kh anehit) H C=O+HH Ni, To CH3 -- CH2--OH H Ru mtylic 2/ Phn ng oxiho anehit: a/ Phn ng trng gng:
NH3, t0

HCOOH+Cu2O + 2Ag Axitfomic trng HocHCHO +2Ag NO3+3HNO3+2H2O HCOOH+2Ag 2NH4NO3. Ag+ b anehit kh to thnh Ag t do. HCHO + Ag2O

b/ Tc dng vi Cu (OH)2 HCHO + 2Cu(OH)2

HCOOH +CU2O +2H2O

Tin

li

V u

Vy c th dng phn ng no nhn bit anehitc fomic

2/ Phn ng oxiho anehit: a/ Phn ng trng gng NH3, t0 HCHO + Ag2O HCOOH+Cu2O + 2Ag Axitfomic
trng HocHCHO +2Ag NO3+3HN3+2H2O HCOOH+2Ag 2NH4NO3. Ag+ b anehit kh to thnh Ag t do. b/ Tc dng vi Cu (OH)2 HCHO + 2Cu(OH)2 HCOOH +Cu2O +2H2O Vy c th dng 2 phn ng trn nhn bit anehit.

3/ Phn ng trng ngng vi phenol.

OH OH | CH2 (n +2) n

OH | |

OH |

CH2 + (n +1 ) CH2O axit To

+(n+1) H2O
phenolfomalanehit

Nha

?T tnh cht ho hc, em hy rt ra ng dng ca anehit fomic

V.ng dng:

tng hp nha fnolfomalhit - Thuc st trng ngm xc ng thc vt ti lu, ty u