Chemical
Resistance Guide
F I R S T
E D I T I O N
F P M C H E M I CA L R E S I S TA N C E G U I D E
Elastomers:
Fluoropolymer (FPM)
A BOUT IPEX
At IPEX, we have been manufacturing non-metallic pipe and fittings since 1951. We formulate our own compounds and
maintain strict quality control during production. Our products are made available for customers thanks to a network of
regional stocking locations throughout North America. We offer a wide variety of systems including complete lines of piping,
fittings, valves and custom-fabricated items.
More importantly, we are committed to meeting our customers needs. As a leader in the plastic piping industry, IPEX
continually develops new products, modernizes manufacturing facilities and acquires innovative process technology. In addition,
our staff take pride in their work, making available to customers their extensive thermoplastic knowledge and field experience.
IPEX personnel are committed to improving the safety, reliability and performance of thermoplastic materials. We are involved in
several standards committees and are members of and/or comply with the organizations listed on this page.
For specific details about any IPEX product, contact our customer service department.
INTRODUCTION
Elastomers have outstanding resistance to a wide range of chemical reagents. Selecting the correct elastomer for an
application will depend on the chemical resistance, temperature and mechanical properties needed.
Resistance is a function both of temperatures and concentration, and there are many reagents which can be handled for
limited temperature ranges and concentrations. In borderline cases, it will be found that there is limited attack, generally
resulting in some swelling due to absorption. Resistance is often affected (and frequently reduced) when handling a number
of chemicals or compounds containing impurities. For this reason, when specific applications are being considered, it may be
worthwhile to carry out tests using the actual product that will be encountered in service. The listing that follows does not
address chemical combinations.
The following publication tabulates the classes of chemical resistance of FPM elastomeric material used in IPEX valves for the
conveyance of industrial fluids. It is generally know that pipes, valves and fittings in thermoplastic material, are widely used in
industries where conveyance of highly corrosive fluids requires high-quality construction materials, featuring excellent
corrosion resistance.
The listed data is taken from the ISO TR 7471-1981(E),ISO TR 7472-1981(E), ISO TR 7473-1981(E),ISO TR 7474-1981(E)
schedules which are based upon immersion test results.
Variations in the analysis of the chemical compounds as well as in the operating conditions (pressure and temperature) can
significantly modify the actual chemical resistance of the materials in comparison with this guide indicated value.
It is therefore deemed advisable, in special cases to carry out experimental tests on pilot plants so as to verify the real
performance of the thermoplastic materials under real operating conditions.
It should be stressed that this publication is only a guide to be used for initial information on the material to be selected. No
guarantee can be given in respect of the listed data. FIP S.pA reserves the right to make any modification whatsoever, based
upon further researches and experiences.
All Chemical Resistance data for Fluoropolymer (FPM) contained within this manual has been provided, with written
consent, by FIP - Kemy 1.
NOTES
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ii
FLUOROPOLYMER (FPM)
All Chemical Resistance data forFluoropolymer (FPM) contained within this manual has been provided, with written
consent, by FIP - Kemy 1.
Compound Compatibility Rating
Four different classes of chemical resistance are used in this guide i.e.:
Limited Resistance
The materials belonging to this class are partially attacked by the
conveyed chemical compound. The average life of the material is
therefore shorter, and it is advisable to use a higher safety factor
the one adopted for Class 1 materials
No Resistance
All material belonging to this class are subject to corrosion by
the conveyed fluid and they should therefore not be used
Insufficient Data
The absence of any class indication means that no data are
available concerning the chemical resistance of the material in
respect of the conveyed fluid
Chemical resistance for FPM applies to IPEX valve products using FPM seals.
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
120C
(248F)
A
Acetaldehyde
CH3CHO
Acetaldehyde 40%
CH3CHO
(CH3CO)2O
Acetone
CH3COCH3
Acetone 10%
CH3COCH3
CH3CN
CH3COC6H5
CH3COCH2COCH3
C2H2
Acid, Acetic
CH3COOH
CH3COOH
CH3COOH
CH3COOH
CH3COOH
HOOC(CH2)4COOH
H3AsO4
C6H5SO3H
C6H5COOH
H3BO3
HBrO3
2
Acid, Butyric
CH3CH2CH2COOH
CH3CH2CH2COOH
Acid, Caprylic
CH3(CH2)6COOH
H2CO3
HClO3
HClO3
HClSO3
CrO3+H2O
CrO3+H2O
CrO3+H2O
C3H4(OH)(COOH)3
Acid, Dichloroacetic
Cl2CHCOOH
Cl2CHCOOH
HOOCCH2OCH2COOH
Acid, Fatty
R>C6
Acid, Fluoboric
HBF4
HBF4
H2SiF6
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
20C
(68F)
40C
(104F)
Acid, Formic
HCOOH
HCOOH
(OH)3C6H2COOH
HOCH2COOH
HI
HBr
60C
(140F)
80C
(176F)
100C
(212F)
1
3
HBr
Acid, Hydrochloric
HCl
HCl
HCl
HCl
Acid, Hydrochloric 5%
HCl
Acid, Hydrocyanic*
HCN
HCN
HF
HF
HF
120C
(248F)
HClO
CH3CHOHCOOH
HOOC-CH=CH-COOH
HOOCCH2CHOHCOOH
Acid, Methanesulfonic
CH3SO3H
CH3SO3H
H2CrO4/H2SO4/H2O
H2SO4/HNO3/H2O
H2SO4/HNO3/H20
H2SO4/HNO3/H2O
1
1
ClCH2COOH
C5H4NCOOH
Acid, Nitric
HNO3
HNO3
HNO3
HNO3
HNO2
Acid, Oleic
C17H33COOH
HOOCCOOH
HOOCCOOH
CH3(CH2)14COOH
CH3(CH2)14COOH
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
HClO4
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
HClO4
H3PO4
H3PO4
H3PO4
Acid, Phthalic
C6H4(COOH)2
1
2
100C
(212F)
2
1
C6H4(COOH)2
Acid, Picric 1%
C6H2(OH)(NO2)3
CH3CH2COOH
H2SiO3
Acid, Stearic
C17H35COOH
COOH(CH2)2COOH
HSO3NH2
Acid, Sulphuric
H2SO4
H2SO4
H2SO4
H2SO4
120C
(248F)
H2SO4
H2SO4
H2SO4
H2SO3
C76H52O46
COOH(CHOH)2COOH
CH3C6H4COOH
Acid, Trichloroacetic
CCl3COOH
CCl3COOH
C5H4N4O3
Acrylonitrile
CH2=CH-CN
CH2=CH-CH2OH
Alcohol, Amyl
CH3(CH2)3CH2OH
Alcohol, Benzyl
C6H5CH2OH
Alcohol, Butyl
CH3(CH2)3OH
Alcohol, Diacetone
(CH3)2COHCH2COCH3
CH3CH2OH
Alcohol, Furfuryl
C5H6O2
Alcohol, Isobutyl
(CH3)2CHCH2OH
Alcohol, Isopropyl
(CH3)2CHOH
Alcohol, Methyl
CH3OH
(-CH2CHOH-)n
C3H7OH
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
20C
(68F)
Formula
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
120C
(248F)
CH2=CHCH2Cl
Alum, Saturated
Al2(SO4)3K2SO4 4H2O
Alum, Diluted
Al2(SO4)3K2SO4 4H2O
(CH3COO)3Al
AlBr3
AlCl3
AlF3
Al(OH)3
Al(NO3)3
Al2(SO4)3
Al2(SO4)3
Ammonia Gas
NH3
Ammonia, Saturated
NH3
Ammonia, Diluted
NH3
CH3COONH4
NH4FHF
Ammonium Carbonate
(NH4)2CO3
NH4Cl
NH4F
NH4OH
NH4OH
2
2
1
1
(NH4)4P4O12
NH4NO3
(NH4)2S2O8
(NH4)2SO4
NH4OH(NH4)2SO4
NH4OH(NH4)2SO4
(NH4)2S
(NH4)2S
Amyl Acetate
CH3COO(CH2)4CH3
Amyl Borate
(C5H11)3BO3
Amyl Chloride
CH3(CH2)4Cl
Aniline
C6H5NH2
C6H5NH2HCl
SbCl3
Aqua Regia
3HCl+1HNO3
Asphalt, Common
2
1
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
120C
(248F)
B
Barium Carbonate, All
BaCO3
BaCl2
Ba(OH)2
Ba(NO3)2
BaSO4
BaS
Beer
Benzaldehyde, Saturated
C6H5CHO
Benzene
C6H6
3
1
C5H12C12H26
Benzyl Chloride
C6H5CH2Cl
Borax, All
Na2B4O7
Bromine, Liquid
Br2
Br2
Brine, Common
Butadiene
CH2=CH-CH=CH2
Butane Gas
CH3CH2CH2CH3
Butanediol, Concentrated
OHCH2CH2CH2CH2OH
Butanediol 10%
OHCH2CH2CH2CH2OH
Butyl Acetate
CH3COOCH2CH2CH2CH3
Butyl Acrylate
CH2=CHCOOC4H9
CH3(CH2)3NH2
Butyl Ether
(CH3(CH2)3)2O
Butyl Phenol
C4H9C6H4OH
Butyl Phthalate
HOOCC6H4COOC4H9
Butylene Glycol
OHCH2-CH=CH-CH2OH
Butylene*
CH2=CH-CH2CH3
Ca(CH3COO)2
Ca(HSO3)2
CaCO3
Ca(ClO3)2
CaCl2
Ca(OH)2
Ca(ClO)2
Ca(NO3)2
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
CaSO4
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
CaS
Carbon Dioxide
CO2
CO2+H2O
Carbon Disulfide
CS2
Carbon Monoxide
CO
Carbon Tetrachloride
CCl4
Chloramine, Diluted
C6H5SO2NNaCl
Chlorine
Cl2
Chlorine 10%
Cl2
Chlorine Dioxide
ClO2
Cl2
Chlorine Liquid
Cl2
Chloro Benzene
C6H5Cl
Chlorobiphenyl
C6H5C6H4Cl
Chloroform
CHCl3
KCr(SO4)2
KCr(SO4)2
120C
(248F)
Cu(COOCH3)2
CuBF4
CuCO3
CuCl2
Cu(CN)2
CuF2
Cu(NO3)2
CuSO4
CuSO4
Cresol, Diluted
CH3C6H4OH
Cresol >=90
CH3C6H4OH
Croton Aldehyde
CH3-CH=CH-CHO
Cryolite, Saturated
Na3AlF6
Cyclohexane
C6H12
Cyclohexanol
C6H11OH
Cyclohexanone
C6H10O
C10H18
D
Decalin (Decahydronaftalene)
Detergents, Common
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
Dextrine, Common
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
Dextrose, All
C6H12O6
Dibutyl Amine
(C4H9)2NH
Dibutyl Ether
(CH3(CH2)3)2O
Dibutyl Phthalate
C6H4(COOC4H9)2
Dibutyl Sebacate
C8H16(COOC4H9)2
Dichloro Benzene
C6H4Cl2
Cl2CHCOOCH3
Dichloroethylene
CHCl=CHCl
Diethylamine
(C2H5)2NH
Diethylether
C2H5OC2H5
Di-Isobutyl Ketone
(CH3)2CHCH2COCH2CH(CH3)2
120C
(248F)
Diisobutylene
C8H16
Di-Isopropyl Ketone
((CH3)2CH)2CO
Dimethyl Amine
(CH3)2NH
Dimethyl Formamide
HCON(CH3)2
Dimethyl Phthalate
C6H4(COOCH3)2
Dinonyl Phthalate
C6H4(COOC9H19)2
Dioctyl Phthalate
C6H4(COOC8H17)2
Dioxane
(CH2)4O2
C3H5ClO
E
Epichlorohydrin
Ethyl Acetate
CH3COOCH2CH3
Ethyl Acetoacetate
CH3COCH2COOCH2CH3
Ethyl Acrylate
CH2=CHCOOCH2CH3
Ethyl Benzene
C6H5C2H5
Ethyl Chloride
CH3CH2Cl
Ethyl Ether
CH3CH2OCH2CH3
Ethylene Chlorohydrin
ClCH2CH2OH
Ethylene Diamina
NH2CH2CH2NH2
Ethylene Dichloride
CH2ClCH2Cl
Ethylene Glycol
HOCH2-CH2OH
Ethylene Oxide
C2H4O
FeCl3
FeCl3
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
Fe(NO3)2
FeSO4
Formula
Fe(NO3)3
Fe2(SO4)3
FeCl2
Fe(OH)2
F2
Formaldehyde 37%
CH2O
Formamide
HCONH2
Freon F-11
CCl3F
Freon F-12
CCl2F2
Freon F-21
CHCl2F
Freon F-22
CHClF2
Freon F-113
CClF2-CCl2F
Freon F-114
CClF2-CClF2
Fructose, Saturated
C6H12O6
Furfural
120C
(248F)
G
Gas Exhaust Acid, Not Diluted
Gas Exhaust with Nitrous Vapours, Trace
Gas Illuminating
Gas Natural
Gelatine
Gin, Common
Glucose, All
C6H12O6
Glycerine, All
C3H5(OH)3
Glycocoll 10%
NH2CH2COOH
Heptane
C7H16
Hexane
C6H14
Hydrazine
NH2-NH2
NH2-NH2 H2O
Hydrogen Gas
H2
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
H2O2
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
H2O2
H2O2
H2S
H2S
Hydroquinone, Saturated
C6H4O2
(NH2OH)2-H2SO4
I2
Iodine Tincture 3%
I2
Iso-Octane
C8H18
120C
(248F)
Hydrosulphite <=10%
100C
(212F)
1
1
Isopropyl Acetate
CH3COOCH(CH3)2
(CH3)2CHCl
Isopropyl Ether
(CH3)2CHOCH(CH3)2
K
Kerosene
L
Lanoline, Common
Pb(CH3COO)2
PbCl2
Pb(NO3)2
PbSO4
Lead Tetraethyl
Pb(C2H5)4
Liqueurs, Common
LiBr
NaClO+NaCl
MgCO3
MgCl2
10
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
Mg(OH)2
100C
(212F)
Mg(NO3)2
MgSO4
MnSO4
HgCl2
Hg(CN)2
HgSO4
HgNO3
Mercury
Hg
Methane
CH4
Methyl Acetate
CH3COOCH3
Methyl Acrylate
CH2=CHCOOCH3
CH3NH2
Methyl Bromide
CH3Br
Methyl Chloride
CH3Cl
CH3OCH3
CH3COCH2CH3
CH3COCH2CH(CH3)2
CH3COCH(CH3)2
Methylene Bromide
CH2Br2
Methylene Chloride
CH2Cl2
CH2I2
Milk
Molasses, Common
ClCH2COOCH2CH3
120C
(248F)
N
Naphtha, Common
Naphthalene
C10H8
(CH3COO)2Ni
NiCl2
Ni(NO3)2
NiSO4
NiSO4
C10H14N2
Nitrobenzene
C6H5NO2
Nitroethane
CH3CH2NO2
Nitromethane
CH3NO2
Nitrotoluene
CH3C6H4NO2
2 - Limited Resistance
3 - No Resistance
11
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
NOx
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
120C
(248F)
O
Oil, Camphor, Common
Oil, Diesel
Oil, Fuel
Oleum 10%
H2SO4+SO3
H2SO4+SO3
H2SO4+SO3
Oxygen, All
O2
Ozone, Saturated
O3
O3
P
Paraffin, Common
Petroleum
2
2
Petroleum Ether
Phenol 90%
C6H5OH
Phenol 1%
C6H5OH
Phenylhydrazine
C6H5NHNH2
COCl2
12
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
20C
(68F)
40C
(104F)
60C
(140F)
Formula
Phosphorous Penta-Trichloride
PCl5-PCl3
Phosphorous Pentoxide
P2O5
80C
(176F)
100C
(212F)
120C
(248F)
(CH3COOCHCH2-)n
CH3COOK
KHCO3
K2Cr2O7
KHSO4
K3BO3
KBrO3
KBr
K2CO3
KClO3
KCl
K2CrO4
KCN
K4Fe(CN)63H2O
KF
KOH
Potassium Hypochlorite, ND
KClO
KI
KNO3
KBO3
KClO4
KMnO4
KMnO4
K2S2O8
K2HPO4 KH2PO4
K2SO4
2 - Limited Resistance
3 - No Resistance
13
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
20C
(68F)
Formula
Propane Gas
CH3CH2CH3
Propane Liquid
CH3CH2CH3
Propyl Acetate
CH3COOCH2CH2CH3
Propylene Glycol
CH3CHOHCH2OH
Propylene Oxide
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
2
1
120C
(248F)
Pyridine
C5H5N
S
Silver Cyanide, All
AgCN
AgNO3
Ag2SO4
CH3COONa
NaAl(SO4)2
C6H5COONa
NaHCO3
Na2Cr2O7
NaHSO4
Sodium Bisulfite
NaHSO3
Na2B4O7
NaBrO3
NaBr
Na2CO3
NaClO3
NaCl
NaCl
NaClO2
Na2CrO4
NaCN
Na2S2O5
Na4FeCN6
3
1
NaF
NaOH
NaOH
NaOH
NaClO
Sodium Hypochlorite 3%
NaClO
Na2S2O4
NaI
14
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
Chemical & Concentration
Formula
20C
(68F)
40C
(104F)
60C
(140F)
80C
(176F)
100C
(212F)
Na2SiO3
NaNO3
NaNO2
Na2C2O4
NaBO3
NaClO4
1
Na2O2
Na2S2O8
Na3PO4
NaH2PO4
Na2HPO4
Sodium Silicate
Na2SiO3
Na2SO4
Na2S
1
2
Na2S
Na2SO3
NaSCN
Na2S2O3
SnCl4
SnCl2
Styrene
C6H5CH=CH2
2
1
120C
(248F)
Sulphur
S2Cl2
SCl2
SO2
SO2
SO2
Sulphur Trioxide
SO3
CHCl2CHCl2
T
Tallow Emulsion, Common
Tetrachloroethane
Tetrachloroethylene
Cl2C=CCl2
Tetrahydrofurane
(CH2)4O
Tetrahydronaphthalene
C10H12
Thionyl Chloride
SOCl2
Thiophene
C4H8S
Ti(SO4)2
2 - Limited Resistance
3 - No Resistance
15
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
20C
(68F)
40C
(104F)
C6H5CH3
(C4H9)3PO4
Trichlorethylene
ClCH=CCl2
Trichloroethane
CH3CCl3
Tricresylphosphate
(CH3C6H4O)3PO4
Formula
Ti2(SO4)3
Toluene
Tributylphosphate
Triethanolamine
N(CH2CH2OH)3
Triethylamine
N(CH2CH3)3
Trioctylphosphate
(C8H17)3PO4
Turpentine Oil
60C
(140F)
80C
(176F)
100C
(212F)
120C
(248F)
U
Urea 33%
NH2CONH2
Urea <=10%
NH2CONH2
V
Vinyl Acetate
CH2=CHOOCCH3
Vinyl Chloride
CH2=CHCl
Water
H2O
Br2+H2O
Cl2+H2O
Water, Condensed
H2O
Water, Demineralizate
H2O
Water, Distilled
H2O
Water, Potable
H2O
Water, Rain
H2O
H2O+NaCl
Whisky, Common
Wines, Common
Water, Sea
16
2 - Limited Resistance
3 - No Resistance
FLUOROPOLYMER (FPM)
CHEMICAL RESISTANCE DATA
20C
(68F)
40C
(104F)
60C
(140F)
C6H4(CH3)2
Zn(CH3COO)2
ZnCl2
ZnCl2
ZnCrO4
Zn(CN)2
Zn(NO3)2
Formula
80C
(176F)
100C
(212F)
1
1
120C
(248F)
X
Xylene
ZnSO4
ZnSO4
1 - High Resistance
2 - Limited Resistance
3 - No Resistance
17
NOTES
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19
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20