CHEMISTRY

IIT-JEE 2012
PAPER - 1

Hkkx - II : jlk;u foKku

[k.M

- I : ,d y lgh mkj iz
d kj

bl [k.M esa10 cgqfod Yi iz'u gSA gj iz'u d spkj mkj fod Yi (A), (B), (C) vkSj (D) gS]ft uesals,d gh lgh gSA

21.

;kSfxd ksad k d kSulk?kVrk e ukbVkst u d h?kVrhvkWDlhd j.k voLFkk(oxidation state) d svuql kj gS\
(A) HNO3, NO, NH4Cl, N2

(B) HNO3, NO, N2, NH4Cl

(C) HNO3, NH4Cl, NO, N2

(D) NO, HNO3, NH4Cl, N2

Ans.

(B)

Sol.

;kfSxd

ukbVkst u d kvkWDlhd j.kvoLFkk

HNO3

=+5

NO

= +2

NH4Cl

= 3

N2

=0

vr%lgh e HNO3, NO, N2, NH4Cl gksxkA

22.

,d gkbMkst u ijek.kqesaf}rh; cksj (Bohr) d {kk esaby sDVkWu (electron) d h xfrd t kZ(kinetic energy) gS
[a0 : cks
j f=kT;k (Bohr radius)]
h2

h2

(A) 4 2ma 2
0
Ans.

(B) 162ma2
0

h2

(C) 322ma2
0

h2

(D) 642ma2
0

(C)
mv (4a0) =

Sol.

so,

h
v = 4m a
0

so

h2
h2
1
1
2
KE =
mv =
m. 16m22 a2 =
32m 2 a 02
2
2
0

RESONANCE

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CHEMISTRY
23.

fuEufy f[kr : ikarj.kesa,sYMksy vfHkf ;kvksa (aldol reaction (s)) d hla[;kgS

lkU t y h; NaOH

CH3CHO + 4HCHO

Ans.

(A) 1
(C)

(B) 2

Sol.

24.

Ans.

OH

CH3CHO+HCHO igy
k, YMk
s sy la?kuu

(C) 3

OH / HCHO

nwl jk , YMk
s sy l a?kuu

(D) 4

OH / HCHO

rhljk , YMk
s sy la?kuu

t c b = 0 vkSj T = 300 K gS] rc ,d eksy okaM joky

(van der Walls) xS
l d sfy , PV vs 1/V js[kkfp=kuhps
fn[kk;kx;kgSA oka
M joky fLFkjkad a (atm.liter2 mol2)
d k eku gS%
(A) 1.0

(B) 4.5

(C) 1.5

(D) 3.0

(C)

Sol.

P 2 (V) = RT
V

PV + a/V = RT
PV = RT a(v)
y = RT a(x)

vr% <ky = a =

21.6 20.1
1.5
=
= 1.5
32
1

RESONANCE

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25.

,sy hu (allene ; C3H4) esad kcZu ijek.kqv ksad slad j.k (hybridisation) d sd kj ;g ;s gSgSaA
(A) sp vkS
j sp3
(B) sp vkS
j sp2
(C) d s
oy sp3
(D) sp2 vkS
j sp3

Ans.

(B)

Sol.

C3H4

26.

;kSfxd MP Xq esaX d slanHkZesa?kuh; fufcM+lad qfy r lajpuk(ccp) d h O;oLFkkgSA bld h,d d d ksf"Bd klajpuk (unit
cell structure) fp=kes
afn[kk;hxbZgSbld k ewy kuqikrhlw=k (empirical formula) gSA

(A) MX
Ans.

(B)

Sol.

ijek.kqv ksad h la[;k=

X ijek.kq
v ksad h la[;k=

(B) MX2

(C) M2X

(D) M5X14

1
4+1=1+1=2
4
1
1
6+ 8=3+1=4
8
2

blfy , lw=k= M2X4 = MX2

27.

fn;s;kSfxd d slaiw.kZvkst ksuh&vi?kVu (ozonolysis) gksusij /kzqo.k ?kw.kZd (optically active ) mRiknksad hla[;k gSA

(A) 0
Ans.

(B) 1

(C) 2

(D) 4

(A)

O / Zn / H O

Sol.

3 2 2CH3CHO + 2CH3 CH CHO

|
CHO

lHkhizd kf'kd vf ; mRikn

RESONANCE

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CHEMISTRY
28.

vkb-;w-ih-,-lh-(IUPAC) uke i}fr d svuql kj ;kSfxd (complex) [Co(H2O)4(NH3)2]Cl3 d kuke gS

(A) Vs
V
k,DokMk,s
ehud ks
ckYV (III) Dyks
jkbM [Tetraaquadiaminecobalt (III) chloride]
Vs
V
k,DokMk,s
Eehud ks
ckYV (III) Dyks
jkbM [Tetraaquadiamminecobalt (III) chloride]
(C) Mkb,s
ehuVs
V
k,Dokd ks
ckYV (III) Dyks
jkbM [Diaminetetraaquacoblat (III) chloride]
(D) Mkb,s
EehuVs
V
k,Dokd ks
ckYV (III) Dyks
jkbM [Diamminetetraaquacobalt (III) chloride]
(B)

Ans.

(D)

Sol.

[Co(H2O)4 (NH3)2 ]Cl3

= Mkb,s
ehuVsV
k,Dokd ks
ckYV (III) DyksjkbM

29.

d kcksZfDly vfHky k{kf.kd lew

g (COOH Functional group) fd l es
amifLFkr gS\
(A) fif d vEy (picric acid)
(B) ckfcZ
V~;wfjd vEy (barbituric acid)
(C) ,s
Ld kfcZd vEy (ascorbic acid)
(D) ,s
fLifju (aspirin)

Ans.

(D)

Sol

fif d vEy ;

,sLd kfcZd vEy ;

30.

CuSO4 d st y h;

Ans.

(A)

Sol.

CuSO4 ukja
xh y ky

ckfcZV~;wfjd vEy

,sfLifju

?kksy }kjkvo'kksf"kr izd k'k(light absorbed) d kjax gSA

(A) ukja
xh&yky (organge-red)
(B) uhyk&gjk(blue-green)
(C) ihy k(yellow)
(D) cS
xauh(violet)
jax d k vo'kks"k.k d jsxk rFkk ;g uhy k jax iznf'kZr d jsxkA

RESONANCE

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CHEMISTRY

[k.M

- II :

cgqy l gh mkj izd kj

bl [k.M esa5 cgqfod Yi iz'u gSaA gj iz'u d spkj mkj fod Yi (A), (B), (C) vkSj (D) gS]ft uesals,d ;kvf/kd lghgSA

31.

,d vkn'kZxS
l d sfy,]vkjfEHkd voLFkkX lsva
fre voLFkkZ rd t kusd s
fy , d soy P-V d k;Zd k fopkj d jsaA vafre voLFkk Z rd igqp usd sfy ,
nksi{k gSft uesalsd ksbZHkhiFklaaHko gSt Sl kfd js[kkfp=keasfn[kk;kx;k
gSfuEufy f[kr fod Yiks
aes
ad kSu fod Yi lghgS
@ gSa\ (S d ks,UVkWihcny ko
vkSj w d ksfd ;k x;k d k;Zekusa)
(A) Sxz =Sxy + Syz
(B) wxz = wxy + wyz
(C) wxyz = wxy
(D) Sxyz =Sxy

Ans.

(AC)

Sol.

32.

(A) Sxz = Sxy + Syz

(lR;)

(B) W xy = W xy + W yz

(vlR;)

(C) W xyz = W xy

(lR;)

(D) Sxyz = Sxy

(vlR;)

'kq) : i esa]fn;sx;sv.kqv ksaesals]d ejsd srki ij]d kSu v.kqvfLFkj (unstable) gS@ gSa\

(A)

Ans.
Sol.

(B)

(C)

(D)

(B)

,UVh,sjkseSfVd ,oavLFkk;hgSA

RESONANCE

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CHEMISTRY
33.

fn;sgq, f}vaxh(binary) feJ.kksaesalsd kSu lsfeJ.kuhpsfn[kkbZxbZLd he (scheme) t Sl sfoHksfn fu"d "kZ

.k(differential
extraction) lsvius;kS
fxd ksaesai`Fkd fd ;st k ld rsgSgSa \

(A) C6H5OH vkj

S C6H5COOH

(B) C6H5COOH vkj

S C6H5CH2OH

(C) C6H5CH2OH vkj

S C6H5OH

(D) C6H5CH2OH vkj

S C6H5CH2COOH

Ans.

(BD)

Sol.

(B)

t y
h; .
NaOH
C6H5COOH + C6H5CH2OH
;) + 2 (vfoys;)

1(foys
1

1 (foy s
;) + 2 (vfoy s;)

(D)

t y
h; .
NaOH
C3H5CH2OH + C6H5CH2COOH
;) + 2(foy s
;)

1 (vfoys
1

(1) (vfoy s
;) + 2 (foy s;).
34.

fofojkxh d ksy kbMy d .k (lyophobic colloidal particles) d h fLFkjrk (stability) d slgh d kj.k pqfu,A
(A) bud si`
"B ij vk;uksad kfoy ;u esao.kkZRed (preferential) vfk'kks"k.kgksukA
(B) bud si`
"B ij foy k;d d k foy ;u esao.kkZRed vfk'kks"k.k gksukA
(C) bud si`
"B d .kksad si`"B ij foijhr vkos'kksad schp vkd "kZ.k gksukA
(D) bud spkjks
avkSj fLFkj ijr vkSj folfjr ijr d schp foijhr vkos'kksad sd kj.kfoHkokUrj gksukA

Ans.

(AD)

Sol.

(A) le

35.

fn, gq
, gkbM
kst u gSy kbMl (hydrogen halides) es
alsd kSu AgNO3 (t y h;) lsf ;kij ,s
l kvo{ksi (precipites) ns
rsgS
t ksfd Na2S2O3 (t y h;) esa?kqy t krsgS\

vk;uksad so.kkZUred vf/k'kks"k.kd sd kj.k

(C) iz
frd "kZ.kd sd kj.kukfd vkd "kZ.kd sd kj.k
(D) fd lhHkhd ks
y kbMy d .kd spkjksvkS
j foijhr vkos
f'kr d .kks
ad hijr]lEi.kZfud k; d hfLFkfrt t kZes
ad ehd jrkgS
A

(A) HCl

(B) HF

Ans.

(ACD)

Sol.

AgNO2 + HCl AgCl

(C) HBr

(D) HI

AgNO3 + HBr AgBr

AgNO3 + HI Ag

lHkhvo{ksi gkbiksfoy ;u esafoy s; ;kgksd j Na3[Ag(S2O3)2] cukrsgSaA

RESONANCE

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CHEMISTRY

[k.M

- III : iw
.kkd mkj izd kj

bl [k.M esa5 iz'u gSaA gj 'u d k mkj ,d vad d k iw.kkd ]0 ls9 nksuksalfgr rd ]gSA

36.

,d d kcZfud ;kS
fxd d kizFke d ksfV lsfo;kst u (decomposition) gks
rkgS
A bld siz
kjfEHkd lknaz
.k(initial concentration)
[1t / 8 ]

d s1/8 vkSj 1/10 Hkkx rd fo;ksft r gksusesa e'k%11/8 vkSj t10 le; y xrkgSA [t ] 10 d keku fud kfy;s(log102 = 0.3
1 / 10
y sa)
Ans.

Sol.

CO
Kt1/8 = In C / 8 = In 8
O
CO
Kt1/10 = In C / 10 = In 10
O

t1/ 8

In 8

log 2

rc t 10 = In 10 10 = log 10 10 = 9
1/ 10
37.

t c fn;kgqv k,YMksgsDlksl Mh&foU;kl lajpuk(D- configuration) esagSrc mld sikbjSuksl (pyronose) : i d sfofHkUu
f=kfoe leko;oh(stereoisomers) : iksad hd qy la[;kgSA

Ans.

Sol.

d qy f=kfoe leko;oh = 23 = 8

RESONANCE

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CHEMISTRY
38.

uhpsfn xbZlkj.khes
aukSis
IVkbMksa(prepitdes) d sR1 vkS
j R2 izfrLFkk;h(substituents) fn;sgq
;sgSaA buesalsfd rusis
IVkbM
pH = 7.0 ij /kukRed vkos
f'kr (positively charged) gSa\

Peptide
I
II

R1
H
H

R2
H
CH3

III

CH2COOH

IV

CH2CONH2

(CH2)4NH2

CH2CONH2

CH2CONH2

VI

(CH2)4NH2

(CH2)4NH2

VII

CH2COOH

CH2CONH2

VIII

CH2OH

(CH2)4NH2

IX

(CH2)4NH2

CH3

Ans.

Sol.

fn;sx;sikWy hisIVkbM d klefoHko fcUnq7 lsvfkd gksxkA bld kery c gSfd ikWy hisIVkbM {kkjh; izd `fr d kgSvkSj blesa
nks;k nkslsvfkd ,ehukslewg gksuspkfg,A vr%(iv) , (vi), (viii) rFkk(ix) lghfod Yi gSaA

39.

vkorZlkj.khes
a18 xz
i (group) gS
q
A rka
cs(copper) d s,d leLFkkfud (isotope) d ksiz
ks
VkW
us
ka(protons) lsceckjh(bombardment) d jusij uhpsfn[kkbZx;hukfHkd h; vfHkf ;k(nuclear reaction) gks
rhgSft lea
srRo X t fur gks
rkgS
A rRo X vkorZ
lkj.kh d sfd l xqi esagS\
63
1
29 C 1 H

Ans.

Sol.

63
1
29 Cu 1 H

610 n 211H X

610 n 24 211H X

64 = 6 + 4 + 2 + A

A = 52

29 + 1 = 30 = 0 + 2 + 2 + z z = 26

rRo X, Fe gksuk pkfg, vkSj bld k xzqi 8 gSA

40.

29.2% (w/w) HCl d s,d

LVkWd foy ;u d k?kuRo 1.25 g mL1 gSA HCl d kvkf.od Hkkj 36.5 g mol1 gSA 0.4 M HCl
d s200 mL foy ;u d kscukusd sfy , bl LVkWd foy ;u d h fd ruh ek=kk (mL) pkfg;sa\

Ans.

8 mL.

Sol.

29.2% (w/w) HCl foy ;u

d k ?ku?Ro = 1.25 g/ml

0.4 M HCl foy ;u d sfy , HCl d seks
y
= 0.4 0.2 eks
y = 0.08 eksy
;fn v mol HCl foy ;u gS]rksfoy ;u d k nzO;eku
= 1.25 v

O;eku = (1.25 v 0.292)

HCl d k nz
HCl d seks
y =

blfy ,, v =

1.25v 0.292
= 0.08
36.5

36.5 0.08
mol = 8 mL
0.29 1.25

RESONANCE

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