Ph

4.8
4.8
4.9
5
5.1
5.2
5.3
5.5
5.7
6.3
8.6
10.8
11.8
11.9
12
12.1
12.2
12.3
12.3
12.4
12.4

Paso 1

Volumen
HCL
agegado
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10

Volumen
NaOH
agregado
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10

Vprom

DpH/DV

(Vprom)prom

0.25
0.75
1.25
1.75
2.25
2.75
3.25
3.75
4.25
4.75
5.25
5.75
6.25
6.75
7.25
7.75
8.25
8.75
9.25
9.75
5

0
0.2
0.2
0.2
0.2
0.2
0.4
0.4
1.2
4.6
4.4
2
0.2
0.2
0.2
0.2
0.2
0
0.2
0
-24.8

0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
7.375
2.5

Ph

Vprom

DpH/DV

(Vprom)prom

4.6
4.5
4.3
4.2
4.1
3.9
3.8
3.5
3.3
2.8
2.4
2.1
2
1.9
1.8
1.7
1.6
1.6
1.5
1.5
1.5

0.25
0.75
1.25
1.75
2.25
2.75
3.25
3.75
4.25
4.75
5.25
5.75
6.25
6.75
7.25
7.75
8.25
8.75
9.25
9.75
10.25

-0.2
-0.4
-0.2
-0.2
-0.4
-0.2
-0.6
-0.4
-1
-0.8
-0.6
-0.2
-0.2
-0.2
-0.2
-0.2
0
-0.2
0
0
-0.2

0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5

10.5
11
11.5
12
12.5
13
13.5
14
14.5
15

Volumen
NaOH
agregado
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
11.5
12
12.5
13
13.5
14
14.5
15
15.5

1.4
1.4
1.4
1.3
1.3
1.3
1.3
1.3
1.3
1.2

10.75
11.25
11.75
12.25
12.75
13.25
13.75
14.25
14.75
7.5

0
0
-0.2
0
0
0
0
0
-0.2
-2.4

11
11.5
12
12.5
13
13.5
14
14.5
11.125
3.75

pH

Vprom

DpH/DV

(Vprom)prom

0
0.2
0
0
0
0
0.2
0
0
0
0.2
0
0
0.2
0
0.2
0
0.2
0
0.2
0.2
0.2
0.2
0.4
0.6
0.6
0.6
0.6
0.2
0.4
0.2
0.2

0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
11.5
12
12.5
13
13.5
14
14.5
15
15.5
16

1.2
1.2
1.3
1.3
1.3
1.3
1.3
1.4
1.4
1.4
1.4
1.5
1.5
1.5
1.6
1.6
1.7
1.7
1.8
1.8
1.9
2
2.1
2.2
2.4
2.7
3
3.3
3.6
3.7
3.9
4

0.25
0.75
1.25
1.75
2.25
2.75
3.25
3.75
4.25
4.75
5.25
5.75
6.25
6.75
7.25
7.75
8.25
8.75
9.25
9.75
10.25
10.75
11.25
11.75
12.25
12.75
13.25
13.75
14.25
14.75
15.25
15.75

16
16.5
17
17.5
18
18.5
19
19.5
20
20.5
21
21.5
22
22.5
23
23.5
24
24.5
25
25.5
26
26.5
27
27.5
28
28.5
29
29.5
30
30.5
31
31.5
32
32.5
33
33.5
34
34.5
35

4.1
4.2
4.3
4.4
4.5
4.6
4.7
4.9
5
5.2
5.4
5.6
5.7
6.1
7
8.4
9.2
10
10.7
11.2
11.5
11.6
11.8
11.8
11.9
12
12
12.1
12.1
12.2
12.2
12.2
12.2
12.3
12.3
12.3
12.3
12.3
12.4

16.25
16.75
17.25
17.75
18.25
18.75
19.25
19.75
20.25
20.75
21.25
21.75
22.25
22.75
23.25
23.75
24.25
24.75
25.25
25.75
26.25
26.75
27.25
27.75
28.25
28.75
29.25
29.75
30.25
30.75
31.25
31.75
32.25
32.75
33.25
33.75
34.25
34.75
17.5

0.2
0.2
0.2
0.2
0.2
0.2
0.4
0.2
0.4
0.4
0.4
0.2
0.8
1.8
2.8
1.6
1.6
1.4
1
0.6
0.2
0.4
0
0.2
0.2
0
0.2
0
0.2
0
0
0
0.2
0
0
0
0
0.2
-24.8

16.5
17
17.5
18
18.5
19
19.5
20
20.5
21
21.5
22
22.5
23
23.5
24
24.5
25
25.5
26
26.5
27
27.5
28
28.5
29
29.5
30
30.5
31
31.5
32
32.5
33
33.5
34
34.5
26.125
8.75

0.4
0
0
0
0
0.4
0
1.6
6.8
-0.4
-4.8
-3.6
0
0
0
0
-0.4
0.4
-0.4
-49.6
49.6

0
7.924E-06
1.259E-05
0.000015
1.589E-05
1.577E-05
1.504E-05
1.107E-05
7.981E-06
2.255E-06
1.256E-08
8.717E-11
9.509E-12
8.183E-12
7E-12
5.957E-12
5.048E-12
4.26E-12
4.511E-12
3.782E-12
3.981E-12

J/K

10pH * V

-0.4
0.4
0
-0.4
0.4
-0.8
0.4
-1.2
0.4
0.4
0.8
0
0
0
0
0.4
-0.4
0.4
0
-0.4
0.4

0
15811.388
19952.623
23773.398
25178.508
19858.206
18928.72
11067.972
7981.0493
2839.3081
1255.9432
692.40898
600
516.31335
441.67014
375.89043
318.48574
338.39109
284.60499
300.41638
316.22777

Experimento 1
14

12
10
8

Ph

10-pH * V

6
4
2
0

Volumen NaOH (F= 0.1 mol/L) agregado

Experimento 2 (Paso 1)
5
4.5
4
3.5
3
Ph

J/K

2.5
2
1.5

1
0.5
0

0.5

1.5

2.5

3.5

4.5

5.5

6.5
Volumen HCl agregado

0
-0.4
0.4
0
0
0
0
-0.4
-4.4
4.8

263.74808
276.30751
288.86694
239.43148
249.40779
259.3841
269.36041
279.33672
289.31304
237.73398

J/K

10- * V

0.4
-0.4
0
0
0
0.4
-0.4
0
0
0.4
-0.4
0
0.4
-0.4
0.4
-0.4
0.4
-0.4
0.4
0
0
0
0.4
0.4
0
0
0
-0.8
0.4
-0.4
0
0

0
0.0315479
0.0501187
0.0751781
0.1002374
0.1252968
0.1503562
0.1393375
0.1592429
0.1791482
0.1990536
0.1739253
0.1897367
0.205548
0.1758321
0.1883915
0.159621
0.1695973
0.1426404
0.1505649
0.1258925
0.105
0.0873761
0.0725601
0.0477729
0.0249408
0.013
0.006766
0.0035166
0.0028931
0.0018884
0.00155

pH

Ph

Experimento 2 ( P
13
12.5
12
11.5
11
10.5
10
9.5
9
8.5
8
7.5
7
6.5
6
5.5
5
4.5
4
3.5
3
2.5
2
1.5
1
0

10 11 12 13 14

3
2.5
2

0.0012709
0.0010411
0.000852
0.0006967
0.0005692
0.0004647
0.0003791
0.0002455
0.0002
0.0001293
8.36E-05
5.401E-05
4.39E-05
1.787E-05
0.0000023
9.356E-08
1.514E-08
2.45E-09
4.988E-10
1.609E-10
8.222E-11
6.656E-11
4.279E-11
4.358E-11
3.525E-11
2.85E-11
2.9E-11
2.343E-11
2.383E-11
1.924E-11
1.956E-11
1.988E-11
2.019E-11
1.629E-11
1.654E-11
1.679E-11
1.704E-11
1.729E-11
1.393E-11

2
DpH/DV

0
0
0
0
0
0.4
-0.4
0.4
0
0
-0.4
1.2
2
2
-2.4
0
-0.4
-0.8
-0.8
-0.8
0.4
-0.8
0.4
0
-0.4
0.4
-0.4
0.4
-0.4
0
0
0.4
-0.4
0
0
0
0.4
-50
49.6

1.5

1
0.5
0
-0.5

1a Derivada

Experimento 1
6

DpH/DV

5
4

3
2
1

10

12

0
0

Volumen NaOH (F= 0.1 mol/L) agregado

Vprom

Experimento 2 (Paso 1)
6

DpH/DV

4
3
2

1
0
-1 0
-2

6.5

7.5

8.5

Volumen HCl agregado

9.5 10 10.5 11 11.5 12 12.5 13 13.5 14 14.5 15 15.5 16

Experimento 2 ( Paso 2)

Series1

14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37
Volumen NaOH agregado

1a Derivada

10

15

20
Vprom

25

30

35

40

1a Derivada

Series1

10

12

1a Derivada

Series2
Series1
0

10

Vprom

15

20

Series1

Volumen
agregado de
NaOH
0
0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10

pH

Vprom

DpH/DV

(Vprom)prom

J/K

10-pH * V

1.5
1.5
1.5
1.5
1.6
1.6
1.7
1.7
1.9
1.9
2.1
2.4
3
5.5
8.3
10.5
11.6
11.9
12
12.1
12.2

0.25
0.75
1.25
1.75
2.25
2.75
3.25
3.75
4.25
4.75
5.25
5.75
6.25
6.75
7.25
7.75
8.25
8.75
9.25
9.75
5

0
0
0
0.2
0
0.2
0
0.4
0
0.4
0.6
1.2
5
5.6
4.4
2.2
0.6
0.2
0.2
0.2
-24.4

0.5
1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
7.375
2.5

0
0
0.4
-0.4
0.4
-0.4
0.8
-0.8
0.8
0.4
1.2
7.6
1.2
-2.4
-4.4
-3.2
-0.8
0
0
-49.2
48.8

0
0.01581139
0.03162278
0.04743416
0.05023773
0.06279716
0.05985787
0.06983418
0.05035702
0.05665164
0.03971641
0.02189589
0.006
2.0555E-05
3.5083E-08
2.3717E-10
2.0095E-11
1.0701E-11
9E-12
7.5461E-12
6.3096E-12

Estandarizacin HCl
14
12

pH

10
8
6
4
2
0
0

Volumen de NaOH (F=O.1mol/L) agregado

10

1a Derivada
6
5

10

DpH/DV

4
3
Series1

2
1
0
-1

6
Vprom

10

12