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Answers of Organic Chemistry Quiz I

10/26/2004 1) The answer is (C). Compound A has the (S) configuration. Both B and D have (R) configurations but compound C has (S). 2) The answer is (D). Resonance structures have the characteristic property of being interconvertible by electron-pair movement only, and the nuclear positions in the molecule remain unchandes. 3) The answer is (D). Only (D) has two carbonyl group. 4) The answer is (B). (m1+m2) m1m2

Vibration frequency v = K

Consider the bond strengths and masses of the attached atoms and find that the bond strengths triple bond > double bond > single bond. Than the masses of the attached atoms, N+H << C+O < C+N 5) The answer is
O FH2CH2C OH < H3CFHC O OH < H3CF2C O OH

To predict relative strength of an acid HA, in this case we just consider the position of the electronegative atom(s) F. When it more approaches the geoup, COOH, the more polar the bond and the more acidic the proton will be.

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