¸ 24 ¸ ¸ 2 3 ]

2012 ¹ 3 |

PBUCBESS I^ CHEHIS1BY
\ol. 24 ^o. 2 3
Har. 2012
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÷[±§± U613. 71¸ 1B383 5µ||y A 5Ëÿ± 1005-281X(2012}02 3-0275-09
Application of Halloysite Nanotubes
1o Z/i

!ong ]inye Coo Xiong Ding Tong Çin Yongning

(Ioparimoni ol Caialysis Scionco and 1ochnolo,y¸ Collo,o ol Chomical En,inoorin, and
1ochnolo,y¸ 1ianjin Inivorsiiy¸ 1ianjin 300072¸ China}
Abstract Halloysiio nano-pariiclos havo roconily hocomo iho suhjoci ol rosoarch aiioniion as a now iypo ol
maiorial. Halloysiio nanoiuhos (H^1s} aro roadily ohiainahlo and aro much choapor ihan oihor nano-pariiclos such
as carhon nanoiuhos(C^1s}. Horo imporianily¸ iho uniquo crysial siruciuro ol H^1s noi only rosomhlos ihai ol
C^1s in iorms ol aspoci raiio¸hui also has a hi,hly ordorod siruciuro wiih aluminol ,roups hound in iho innor
surlaco and silanol ,roups on iho oxiornal surlaco. Consoquonily H^1s noi only havo poioniial as addiiivo lor
onhancin, iho mochanical porlormanco ol polymors hui also mako ihom aiiraciivo candidaios lor a varioiy ol poioniial
applicaiions¸ includin, molocular adsorpiion¸ molocular oncapsulaiion¸ siora,o and iranspori¸ caialysi or caialysi
suppori in chomical roaciions. 1his roviow summarizos iho oxionsivo hui scaiiorod liioraiuro on halloysiio nanoiuhos`
applicaiion¸ lrom iis crysial siruciuro¸ chomical and characiorisiic ol morpholo,ical¸ io iis adsorpiion¸ iranspori and
caialysis roaciiviiy¸ involvin, iho various valuahlo prospocis. Iinally¸ iho luiuro ironds and prospocis in iho
dovolopmoni ol applicaiion rosoarch ol H^1s aro hi,hli,hiod.
Key words halloysiio nanoiuhos¸ adsorpiion¸ conirollod-roloaso¸ caialysi¸ caialysi suppori
Contents
1 Iniroduciion
2 Chomical composiiion and crysiallino siruciuro ol
halloysiio nanoiuhos
3 Adsorpiion¸ siora,o and iranspori proporiios ol
H^1s
3. 1 1ranspori proporiios ol hydro,on-hondin, liquids
such as waior¸ moihanol and oihanol
3. 2 Adsorpiion siora,o proporiios ol luol ,as CH
4
¸
·276· ¸24 ¸
H
2
on H^1s
3. 3 H^1s as iho suppori lor dru,s or hioaciivo
moloculos
3. 4 H^1s as sorhonis lor coniaminanis and polluianis
4 H^1s usod as caialysi or caialysi suppori
4. 1 Acid caialysi
4. 2 Enzymaiic carrior
4. 3 1ho suppori ol iho caialysi moial comploxos
5 Somo oihor proporiios ol H^1s
6 Uuilook
1 ¸±
2008 ¹¸[[ ^aiural^ano ¸)¸|¸¡)
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Fig. 1 Crysiallino siruciuro ol halloysiio nanoiuhos
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Fig. 2 Siruciuro ol halloysiio monolayor and cross sociion
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Table 1 1ho proporiios ol iho puriliod samplos
[83¸
samplo puriliod K1 puriliod K2 puriliod K3
minoral composiiion halloysiio kaoliniio(70%}
halloysiio(30%}
dickiio
SiU
2
(wi%} 46. 76 46. 54 46. 80
Al
2
U
3
(wi%} 39. 12 39. 54 39. 67
spocilic surlaco aroa
(m
2
,}
89. 4 41. 1 9. 0
spocilic surlaco aroa
(calcinod ai 800'}
(m
2
,}
61. 9 24. 3 7. 0
roioniion ol spocilic
surlaco aroa (%}
69. 18 59. 12 77. 78
micro-roaciion aciiviiy
(%}
24 13. 4 0
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)I|¸¡"¸¸[¸¡ H^1s ¸¸¦[±|(±}
"¸T|[±|(±}"¸{)I¿¸100%[[¸
¯¸J¸¹]|(±}"¸]_´¸[¸¸j[ H^1s
[(J¸]¸¸¡"¸¸[]]¸}¸|[|¸|
)¸¿¸[¸¡|)[q]¸]|[j¡¡)¸T
¯¹¸T¡¡¸)]¡[¿|(¡, j)±@|/
(PhIU}|¸(]]¸)(2 )I[¸µµj]¸¸
¿|]¸±]¸¸|¦¿|¡j]||µ¬|j;
¸H^1s _¿¡|¸¸¡"¸¸[]]¸¿|]_
ÿ, ¡/ Liu ¸
[92¸
¸) A,^U
3
[j¸[|_¡
10nm ¸|[µ¬±¡±|]¸ H^1s ¸¸)¬j¡
^aBH
4
¸[¸[¸/|(4-^P}¸j¸±¸/|(4-
AP}¸¿|¡¡¯|{^aBH
4
}|[])]]),
Barrionios-Bamíroz ¸
[94¸
{¸¸H^1s |¸_¡
j¡¡CuBr-N-±¸¸-¸-±}¸¹¸¡¡(CuBr
AEAP1S}[]]¦¡¹¸}¹µ¹p(HHA}¸{¸
( [ CuBr-AEAP1S | | j ¡ ¸ H^1s-CuBr
AEAP1S ¸|j¡|j CuBr-AEAP1S |]¸ H^1s
¸j¸}jHHA [¦¡)}¸¸|¡±_(1
n
} |
·280· ¸24 ¸
{¡¡¯[])];]])¸¸]j 1
n
;¸|¸¡
±_¡|¡¸PII |]¸¡¡¯|¸¸[¸||j
]¸¡±_¡|¸|¸|ÿ[j] 1
w
1
n
= 1. 3,
|j¸/¸j¡|¡µ¶¡ CuBr AEAP1S ¸I|
]||j¸[]¡¸ H^1s |;¡¡¿
[94¸
¸|
]Hj¸(J]¸[|¡¸j¡]][)¸],
±2 ¡´|[)j¹|[±|(±} "¸j¡±@|/
(PhIU}(¡T¡¡
[91¸
Table 2 Cyclohoxano oxidaiion hy PhIU caialyzod hy an
anionic iron(±} porphyrin indilloroni modia
[91¸
caialysi alcohol
yiold(%}
koiono
yiold(%}
alcohol
koiono
run
Io-Hallo 39 3 13 1
[Io(1IISPP}¸
3 ÷
19 7 3 2
Io-Kao-Hallo 28 ¬ 28 3
raw halloysiio iraco iraco ¬ 4
Io-Hallo¸ [Io(1IISPP}¸ immohilizod on raw halloysiio hy moans ol iho
prossurizod moihod. [ Io ( 1IISPP}¸
3 ÷
¸ homo,onoous caialysis. Io-
Kao-Hallo¸ [ Io ( 1IISPP}¸ immohilizod on synihoiic halloysiio-liko
nanoiuhos
[93¸
5 HNTs j¬§)¶|þ(;
µ¬|)}j¡¿·]¹|¸¸¡¸¸]]j
A¸_¸[]¡¿¡|]¸¸[I¡}), ¸¸]
µ¬||;|¸H^1s j)|µ¬)}j]¡µ¬
¡±¿µ¬;, ( Luca T 1homson
[105¸
|/[¡
H^1s [||¦¡|¸¸¦/[, ¦/¸H^1s |¸
µ¬)}j¿µ¬j|)I]¡µ¬}¡¸µ¬;¸
µ¬¡[¸
[107¬115¸
¸(¡ H^1s ¹I¸j¸¡3]
¸¦¡[¡]¡;]¡¸j(J||¸[)]|
[¬¬¬¸][¸¡¿¡j¸¿]¿[¡]¡¿¡|
÷¸jA][¸
[106¸
, ¡j¡±[]|_[];|
T|¸[(J|¸¸;¸[¡±[|j[]|¸[
||¸¸, ]{¸{)|jJ¸||¸j]|¸¸´
;¿¸|T¬]¸¡j¡±[¸J¸¿¸{¸¸¸
]I¢¡¸¡¸¦||¸¡j¿|]¸)|¿|]
¸¸|]¸¡±[[})¸l¡](¸|]j¡j]
||¡_[¡±[_¸"¸
[117¬122¸
, Zhao ¸
[116¸
¡]¸)H^1s ¸[[±)¡j]|]|[¸]¸
¡±[¸)¸[±¹^H
+
4
[||¸{||ÿ[(÷¸
¸]j||¡|j¸¡j¡±[||¿||¸||
¸¸¸, ¸[µ¬||¸]¸H^1s ¡]|¸¸]
J¸]¸[})¸¸,)|¸,¸¡j|[[¸
¸]3 ||j¸[¸¸¡(¡|T¸¸¦¡|¸]¹
¦|[|¸|¸¸]¡±]|ÿ[)j¸]T¸
¸]¸J¦|[÷]¶]¸¸¯¿]¸/¸l¡_¡
¸¸]¡±|[¸¿¸¸j[¸¡, Yan, ¸
[123¸
¸
|¸_¡¸,¸¡j|[[]¡¸¸|}[)j¸
H^1s [(J¸¸j¸¦|[¸¿¸|]µ[|)
;¡¡¿¸¸j[|¶|| H^1s ¦|[¸,¸
¡j¡¸¿[]|¸[¸¸¯¸)¸¡¸¸[
||{H^1s )/_[])¸¸¸¯¸¿|[]|
]¿¡[j, l¡H^1s ¡¸¡¸]J]|ÿ[}
)¡¸,
6 §§
|¡¸H^1s |¸||]||¸;|¡|[
¡¸µ¬|[¸[]¸)j|[j¸¸J¸;¸)[
{¸j¿¸|,||¸¸])¸[¸,¸¶¡¸(1}
;¸¸|[|¡|w|A¸¡|¸j(¸]j]
¸]¸])¸¸j¸¿|)´]¸,¸¿¸¿¡¸
l¡|]¸]¡]||¸)[})¸(÷¸|¸
|¡j]¡¸]|÷¡j¸|¡)j[]|¸;¡
|µ¬|¸|¸](,¸[¸)]]T})¡|,
(2})|[[]|¸¸@¡|¬[¸||;|[|
¡|¸¸¡|¡¡]¸|j÷¸¹¡)j¸]¡¸
]]_|¸[[¸j;]|¸¸¸)]||¸[[
[¸¸¸,]||j];|[]|¸¸(÷¸¿´
|[¸¸¸[|j;]|¸j|j¸¯¡¸j||
;|[]¸¸}´]_¸¡[j;]|¸|])¸
j¸¸)jj|¸[¡[[[, (3}j¸[]|ÿ
[¸¸¸)¸]¸/¸H^1s (J[](,¸[){
¡¸|¸]¸¡¡¸¸|¸]|¸ ;|]¡|[
]J|¸I¡})¸};)¸]¡¸±¸[|¸¿¸¸
¡|[]¡¸@¸)|)]¸[{¸, (4}|¡[
{¸jj¦¸)|¸¿;÷[)|;¿¬¶¡
H^1s []¸¸};)H^1s T¸]¸||¸|)[
)|¬¸¡[¸¸;¡;,|j|_|][j|{¸
{¸H^1s T¸][|)|])[[|¡|]¸|
}]})¸[,
¶ ¶ 5 µ
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