Title : ZEOLIT Date: 21 April 2012 Subject: MINERALOGY AND CRYSTALLOGRAPHY Lecturer: Prof. Dr. Ir. Bondan T.

Sofyan, M.Si. We the undersigned declare that the following paper is purely our own work. No work of others that we use without mentioning the source. This paper has never been used or presented for other assignment. We understand that this paper may be reproduced and or communicated for the purpose of detecting plagiarism. GROUP K

Hudan Ali Yusar (1106018234)

Yermia Andri Prawira (1006772582)

Wahyu Hidayat (1106021733)

Darel Domu Abadi (1106069853)

Rizky Cakti Bramantyo (1006704732)

SOURCES and REFERENCES Handbook of zeolite science and technology, Scott M. Auerbach, Kathleen A. Carrado, Prabir K. Dutta, eds. CRC Press, 2003, p. 16. Handbook of Mineralogy. Mineralogical Society of America. 2004 U.S. Geological Survey, Mineral Commodity Summaries, January 2011

http://www.moutere.com/stories/storyReader$39 http://regionalinvestment.bkpm.go.id/newsipid/en/commodity.php?ic=918 Accessed on 22/04/2012

Zeolites (natural), USGS Mineral Commodity Summaries 2011

http://www.tekmira.esdm.go.id/currentissues/wp-content/uploads/2009/01/ekspor-zeolitlampung.JPG http://transindozeolite.com/Company-Profile.html

Indonesia is a country with rich resources in minerals. Find out information on the mineral deposit. The information should at least cover: The type of ore mineral found in Indonesia. One element can have more than one ore minerals. Describe for each type of ore. The crystal structure of the mineral (of each type of the mineral) The form of the crystal structure (You will learn about form of crystal in the Symmetry Chapter. For now, please just absorb and write the information) The location of the mineral deposit in Indonesia. How much is the deposit? And whether the deposit has been exploited or not. Compare the deposit with that of other countries in the world. What company does the extraction of the minerals in Indonesia? Please find out info on the company (headquarter, investment in Indonesia, etc). Does the company process the ores in Indonesia, or the ores are directly exported without processing. The annual volume and value (in USD) of the mineral export from Indonesia, in the last 5 years and predicted for the next 5 years. The annual volume and value (in USD) of the metal export and import, in the last 5 years and predicted for the next 5 years. Please remember, Biro Pusat Statistik is one of the best source of information. So, please visit BPS to find out the statistics. Upon finalizing the report, you are expected to get the idea on how rich Indonesia in mineral deposit, and how the deposit enriches and is used for the prosperity of the people.

The type of Zeolit found in Indonesia. Describe for each type of ore.
Clinoptilolite Mordenite Christobalite

Examples of mineral zeolite with structure and form crystals

Amicite Analcime Barrerite Brewsterite Chabazite Clinoptilolite Edingtonite K2Na2Al4Si4O165(H20) NaAlSi2O6H2O (Na,K,Ca)2Al2Si7O186(H2O) (Sr,Ba)2Al4Si12O3210H2O (Ca,Na2,K2,Mg)Al2Si4O126H2O (Na,K,Ca)2-3Al3(Al,Si)2Si13O3612(H2O) BaAl2Si3O104H2O pseudotetragonal cubic orthorhombic prismatic rhombohedral monoclinic, triclinic triclinic monoclinic

monoclinic (Found in Indonesia) tetragonal, orthorhombic, or triclinic hexagonal (cage-like hexoctahedral

Erionite (Na2,K2,Ca)2Al4Si14O3615H2O prismatic structure composed of a framework of linked tetrahedral) Faujasite Ferrierite Gismondine symmetry Gmelinite (Na2,Ca,Mg)3.5[Al7Si17O48]32(H2O) (Na,K)2Mg(Si,Al)18O36(OH)9H2O CaAl2Si2O84(H2O) Na4(Si8Al4)O2411H2O cubic orthorhombic

bipyramidal crystals of orthorhombic Hexagonal, Dihexagonal Dipyramidal Orthorhombic-bipyramida, tetragonal monoclinic monoclinic, simple rhombic prisms monoclinic prismatic

Gonnardite (Na,Ca)2(Si,Al)5O103H2O scalenohedral Harmotome Heulandite Laumontite (Ba0.5,Ca0.5,Na,K)5Al5,Si11O3212(H2O) (Ca,Na)2-3Al3(Al,Si)2Si13O3612H2O Ca(AlSi2O6)24H2O

Levynite(Levyne) trigonal Mesolite Mordenite Indonesia) Natrolite

Levyne-Na (Na2,Ca,K2)Al2Si4O126(H2O), Levyne-Ca (Ca,Na2,K2)Al2Si4O126(H2O) orthorhombic orthorhombic

Na2Ca2(Al2Si3O10)38H2O (Ca, Na2, K2)Al2Si10O247H2O Na2Al2Si3O102H2O

prismatic orthorhombic (Found in orthorhombic

Paulingite Phillipsite Pollucite Scolecite Stellerite Stilbite Thomsonite Wairakite

(K,Na,Ca)3-4(Si,Al)21O42 (Ca,Na2,K2)3Al6Si10O3212H2O Cs(Si2Al)O6.nH2O CaAl2Si3O10.3H2O Ca(Al2Si7O18).7H2O

cubic hexoctahedral monoclinic, complex cruciform twins isometric hexoctahedral monoclinic, pseudotetragonal orthorhombic, rhombic-dipyramidal

Stilbite-Ca: NaCa4(Si27Al9)O7228(H2O) Stilbite-Na: Na9(Si27Al9)O7228(H2O) Monoclinic, triclinic, and pseudo-orthorhombic NaCa2Al5Si5O206H2O Ca8(Al16Si32O96).16H2O orthorhombic cubic Dipyramidal

The form of the crystal structure

Legend: Circle = Oxygen, Square = Silicon, aluminium Typical zeolite crystal formation showing the open-cage structure and right, showing the position of oxygen and silicon atoms. When silicon is replaced by aluminium an overall negative charge results and this is responsible for the properties of the zeolite.

The location of the mineral deposit in Indonesia. How much is the deposit? And whether the deposit has been exploited or not. Comparation the deposit with that of other countries in the world.
POTENTIAL OF ZEOLITE AT NORTH SUMATERA Zeolite function: ornament, puzzolan cement, agregat, bearers and toothpaste filler, purifying methane gas, natural gas, and toxins metals absorption. Location : Sukamaju Village Pahaejae Subdistrict North Tapanuli Regency Status : Preliminary Exploration Deposit : 1,800,000 ton Location: Ambar Village Simangumban Subdistrict Coordinate: North 1o45'07,9" - East 99o08'35,8" Status : Preliminary Exploration Deposit: 6,000,000 ton Analysis Result: SiO2 = 55.15 %, Fe2O3 = 2.80 %, Al2O3 = 24.84 %, Na2O3 = 0.39 %, K2O = 1.26 %

POTENTIAL OF ZEOLITE AT BENGKULU

It is located at Limau Village and Sekayun Village, Pondok Kelapa Subdistrict Investigation phase : Survei Review 1,250,000 M3 Information : regional Mining Department 1992

POTENTIAL OF ZEOLITE AT LAMPUNG

Location: Bandar Dalam Village, Sidomulyo Subdistrict Resource : 3,198,505 ton (hypothetic) Location: Campang Tiga Village, Sidomulyo Subdistrict Resource : 825,000 ton (hypothetic) Location: Batubalak Village, Kalianda Subdistrict Resource : 17,600,000 ton (counted) Location: Pekon Batubalai, Kota Agung Subdistrict Resource : 4,950,000 ton (hypothetic) Location: Pekon Tengor, Cukuh Balak Subdistrict Resource : 4,600,000 ton (hypothetic)

POTENTIAL OF ZEOLITE AT WEST JAVA

Sukabumi Regency Location: Cikembar, Gegerbitung Subdistrict estimated reserve: 159,435,000 ton Ciamis Regency Location: Kalipucang and Padaherang Tasikmalaya Regency Location: Cipatujah, Karang Nunggal, Cikatomas, Cikalong. Deposit: 50million ton

POTENTIAL OF ZEOLITE AT WEST SULAWESI

Regency of Mamasa Location: Messawa Subdistrict Regency of Mamasa Deposit: 17,057,600 ton Regency of Majene Location: Sendana

POTENTIAL OF ZEOLITE AT SOUTH SULAWESI

Gowa Regency Deposit: 722,178,800 ton Tana Toraja Regency Location: Sangkaropi Deposit: 600,000,000 ton

POTENTIAL OF ZEOLITE AT EAST NUSATENGGARA

Regency of Manggarai Location: Sambi Rampas, Elar Spreading area: Sambi Rampas 1.500.000 m3. Elar 7.500.000 m3 Regency of Ngada Deposit: 1,008,400 m3 Regency of Sikka Deposit: 130,000 m3

World Zeolite Mine Production

Country United States China Japan Jordan Korea, Republic of Slovakia Turkey Other World Total (rounded) Mine Production (Ton) 2009 2010 59500 59000 2000000 2000000 155000 150000 425000 140000 165000 210000 90000 85000 100000 100000 5500 5000 3000000 2750000

What company does the extraction of the minerals in Indonesia? Please find out info on the company (headquarter, investment in Indonesia, etc).
Only a few of natural Zeolite delivered to the factory in Indonesia to be extracted and much more of zeolite exported or sold to others country like, China, USA, Italy, Turkey, UK dan India to be processed there. These some companies some does the mining, extraction and maufacture of zeolit in Indonesia :

1. PT. TRANSINDO CITRA UTAMA

PROFIL PERUSAHAAN Nama Perusahaan : TRANSINDO UTAMA Bidang Usaha : pertambangan, industri dan ekspor komoditi berbahan baku Zeolit Segmen pasar : Dalam negeri 20%, ekspor 80% Cadangan Zeolit : 80 juta metrik ton Umur tambang : 104 tahun Jenis Zeolit : Clinoptilolite & Mordenite Lokasi Tambang : Bayah, Provinsi Banten (Zeolit Indonesia terbaik) Metode Penambangan : Tambang terbuka gali pilih Pabrik pengolahan : Plered, Purwakarta Provinsi Jawa Barat Indonesia Kapasitas produksi : 4.500. ton / bulan Berdiri perusahaan : Tahun 1986 Eksplorasi cadangan : Tahun 1987 (Penelitia Geologi, Zeolit pemetaan detail, eksplorasi detail) Produksi percobaan : Tahun 1988 untuk bidang pemasaran Tambak Udang (Aquaculture) Produksi komersial : Tahun 1989 pasar lokal dan menembus pasar Korea Selatan (Ekspor perdana untuk aplikasi pengolahan air) SERTIFIKAT ANALISA Jenis komoditi : Zeolit alam aktif Kemasan : 25-1.000Kg KOMPOSISI MEINERAL Kuantitatif : mengandung mineral zeolit ; Clinoptilolite = 23,0% Mordenite = 59,7% Total = 82,7% Christobalite = nihil Mineral liat/clay = nihil KOMPOSISI KIMIA SiO2 = 65.04%

Al2O3 = 16.51% Fe2O3 = 0.81% TiO2 = 0.04% CaO = 2.23% MgO = 0.71% K2O = 2.57% Na2O = 0.66% MnO2 = 0.02% Zn = 0.12% Pb = nihil Lost Ignition = 11.24% Cation Exchange Capacity = 80-170 meq/100grs

2. Company Location Product 3. Company Location Product 4. Company Location Product

: PT Panja Multi Mineralindo (Manufacture) : Bekasi Utara, Jawa Barat, Indonesia : Zeolite : Samudra Mineralindo (Manufacture) : Bandung, Jawa Barat, Indonesia : Powder Zeolite and Granular Zeolite : CV. Pulau Mas Mineralindo (Manufacture) : Indonesia : Powder Zeolite, Granular Zeolite, Granular Round Pellet Zeolite.

5. Company : CV. Transindo Citra Utama (Manufacture and Extraction) Business : Mining, Industry and export Zeolit Market : 20% Indonesia, 80% export Type of Zeolite : Clinoptilotite & Mordenite Mining Location: Bayah, Banten Zeolite reserves: 80 mt/ton Mining Method: Opened Mining Factory : at Plered, Purwakarta, Jawa Barat, Indonesia Production : 4.500 ton/month 6. Company Product Location Market 7. Company Product 8. Company : Zeolite Indah Warsa (Manufacture) : Zeolite : Ciruas, Serang, Jawa Barat : Eastern Asia : CV. Dwijaya Perkasa Abadi (Manufacture) : Zeolite : Nusagri (Manufacture)

Product 9. Company Production Market

: Zeolite : Sanmaru Resources (Mining and Manufacture) : 5.000 mt/ month : South East Asia

The annual volume and value (in USD) of the mineral export from Indonesia, in the last 5 years and predicted for the next 5 years. For Data Export in the entire Indonesian region , we couldnt find it either in bps.go.id or another sites But we found this

SOURCES and REFERENCES Handbook of zeolite science and technology, Scott M. Auerbach, Kathleen A. Carrado, Prabir K. Dutta, eds. CRC Press, 2003, p. 16. Handbook of Mineralogy. Mineralogical Society of America. 2004 U.S. Geological Survey, Mineral Commodity Summaries, January 2011

http://www.moutere.com/stories/storyReader$39 http://regionalinvestment.bkpm.go.id/newsipid/en/commodity.php?ic=918 Accessed on 22/04/2012

Zeolites (natural), USGS Mineral Commodity Summaries 2011

http://www.tekmira.esdm.go.id/currentissues/wp-content/uploads/2009/01/ekspor-zeolitlampung.JPG http://transindozeolite.com/Company-Profile.html