SEKOLAH MENENGAH KEBANGSAAN ISKANDAR SHAH JASIN 77000, MELAKA

CHEMISTRY FORM 5
UJIAN PENGESANAN MAC 2012

MASA 21/2 JAM

ARAHAN

1. JAWAB SEMUA SOALAN. 2. SOALAN INI MENGANDUNGI i. Kertas 1 - Soalan objektif ii. Kertas 2 - Soalan berstruktur Kertas 3 - Soalan berstruktur 3. SOALAN OBJEKTIF HENDAKLAH DI JAWAB DALAM BORANG OMR. 4. ASINGKAN JAWAPAN OBJEKTIF ANDA, SEMENTARA JAWAPAN-JAWAPAN YANG LAIN HENDAKLAH DIIKAT BERSAMA-SAMA

KERTAS UJIAN INI MENGANDUNGI 14 MUKA BERCETAK Disediakan oleh ABDUL JALIL MAYASSIN Disahkan oleh PN JAMILAH IBRAHIM

GURU KIMIA

GKMP SAINS & MATAMATIK

BAHAGIAN A : JAWAB DALAM BORANG OMR. 1. The general formula for the alkene series is A CnHn; B C CnH2n+2; D

CnH2n; CnH2n-2.

2.

All carbon-carbon bonds in a saturated hydrocarbon molecule are A single covalent; B double covalent; C triple covalent; D coordinate covalent. Which formula represents a saturated hydrocarbon? A C2H2; B C2H4; C C3H6; D C3H8 C2H4 + H2 C2H6 The above reaction is an example of A addition; C fermentation.

3.

4.

B D

substitution; esterification.

5.

Which compound is a member of the alkane series? A C2H6; B C3H6; C C4H6; D C6H6. Given the following reaction: C4H10 + Br2 C4H9Br + HBr. The above reaction is an example of A substitution; B addition; C polymerization; D fermentation. Compounds which have the same molecular formula but different molecular structures are called A isomers; B isotopes; C allotropes; D homologs. CnH2n+2 is the general formula of a homologous series. Which is a member with this characteristic? A methyl alcohol; B benzene; C propane; D hexane Which molecular formula represents pentene? A C4H8; B C C5H10; D

6.

7.

8.

9.

C4H10; C5H12.

10.

As the molecular mass of the compounds of the alkane series increases their boiling points A C decreases; remains the same. B increases;

11.

Name the industrial process that produce ammonia? A C Haber process Ostwald process B Contact process

12.

Which of the following is not true about the uses of sulphuric acid? A C Leather tanning Production of margerine B D Manufacture of paint Manufacture of detergents

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. Which of the following is not the aim of making alloy? A C To prevent rusting To improve physical appearance B D To minimize corrosion To lower the melting of the metal

14.

The diagram shows the structure of polymer P

H C H

Cl C H

H C H

Cl C H

H C H

Cl C H

H C H

Cl C H
St ai nl e ss st e H el n ail

Which of the following is the monomer of polymer P? A

H C H

Cl C H H Cl C H H

C l C H

H C

H C H

H C H

Cl C

H C H H

C H

15.

A student wants to study the relationship between the concentration of hydrochloric acid and time of reaction by reacting the acid with magnesium ribbon.

What should be the responding variable ? A C Concentration of acid Amount of magnesium ribbon B D Time taken for reaction Length of magnesium ribbon

16.
A B C D

Aluminium powder reacts faster with hydrochloric acid than an aluminium strip because the particles in the aluminium strip are packed closely the particles of aluminium powder have more kinetic energy the aluminium powder has a larger total surface area there is a layer of aluminium oxide on the aluminium

17.

The table shows the total volume of gas collected at regular intervals in a reaction Time (s) Volume of gas (cm3 ) 0 0 30 2.0 60 3.7 90 5.2 120 6.4 150 7.3 180 8.6 210 8.6

What is the average rate of reaction in this experiment ? A C 0.041 cm3 /s 0.049 cm3 /s B D 0.048 cm3 /s 0.053 cm3 /s

18.
A C 19 A C

Which of the following substance is acidic ?

Sodium hydroxide Potassium oxide B D Sulphur dioxide Ammonia

Which of the following is not grouped in the same homologous series ? Propane, butane, hexane Heptene, ethene, pentene B D Ethanol, methyl propanol, 1-butanol Acetic acid, propanoic acid,sulphuric acid

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Which of the following is NOT a characteristic of ammonia? A C Very soluble in water A white fume gas B C Has a pungent smell. Alkaline gas.

BAHAGIAN B : Jawab semua soalan didalam ruang yang di sediakan. 1. Two experiments are carried out to investigate the factors affecting the rate of a reaction. Table 1 shows information about the reactants and the temperature used in each experiment. Experiment I

Reactants Temperature/oC 3 Excess calcium carbonate chips and 30 cm of 40 -3 0.5 mol dm hydrochloric acid II Excess calcium carbonate powder and 30 cm3 of 40 0.5 mol dm-3 hydrochloric acid Table 1 (a) What is the factor that influences the rate of reaction in both experiments? [1 mark] (b) The reaction in the experiment is represented by the following equation: CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) + H2O(l) (i) Among the products stated in the equation, which is the most suitable to be chosen to determie the rate o reaction? [1 mark] (ii) State one reason for choosing the product in (b)(i). [1 mark] (c) State two controlled variables in both experiments. i. ii [2 marks] (d) The results for both experiments are represented by graph 1

Based on graph 1: (i) Experiment II has a higher rate of reaction. How does the graph show this? [1 mark] (ii) What has happened to the reactants at time x? [1 mark]

(iii) Why are both curves at the same level after time x? [1 mark] (e) What is the conclusion for both experiments?

(f) Draw a diagram to show how the gas could be collected and its volume measured. [2 mark]

(g) Another experiment is carried out using excess calcium carbonate powder and dilute hydrochloric acid with different concentrations. Sketch the curve of concentration of dilute hydrochloric acid against the time taken to collect a fixed quantity of the product.

2. Three experiments have been carried out to study the effect of factors affecting the rate of reaction at room temperature. Table 2 shows the results of the experiments. Experiment I II III

Set-up of apparatus

10 cm of -3 1 mol dm sulphuric acid

10 cm of -3 2 mol dm sulphuric acid

10 cm of -3 2 mol dm sulphuric acid

Excess of magnesium strip

Excess of magnesium strip

Excess of magnesium powder

Time taken for magnesium strip to react completely(s)

60 Table 2

30

10

(a) Sketch the graph for the volume of gas released against time for Experiment I, II and III on the same axes. [3 marks]

(b) Compare the rate of reaction between Experiment I and Experiment II; Explain why there is a difference in the rate of reaction based on the collision theory. [4 marks]

3. Name the homologus series each of the following compounds.

Compound Name of Homologus series

4. Complete the following table.

IUPAC Name 3-methylpent-1-ene Structure Formulae

pentan-3-ol

butanol

HCOOH

5. The diagram 1 shows the chemical reaction of propanol.

Diagram 1 (a) (i) Name process reaction I [ 1 mark ] (ii) Write the general formula of compound E. ................ [ 1 mark ] (i) Name process II. .................... [ 1 mark ] (ii) What is the catalyst used in process II? ................... [ 1 mark ] (c) Describe a chemical test to distinguish compound D and E. (By using Bromine water or acidified Potassium mangganate (VII)) [ 3 marks ]

(b)

(d) (i)

Name a chemical used in process III to convert the propanol to propanoic acid. [ 1 mark ] What is the observation in process III? [ 1 mark ]

(ii)

(iii)

Propanoic acid can reacts with magnesium. Write the chemical equation for the reaction.

(e) (i)

................... [ 1 mark ] A Compound Y is formed in process IV. Name the compound Y ...................... [ 1 mark ] What is the function of concentrated sulphuric acid in process IV? ...........

(ii)

6.

(a) (i) What is meant by alloy?

[2 marks]

(ii) List two aims of alloying.

[2 marks]

Diagram 2 shows the apparatus set-up to investigate the hardness of copper and bronze.

Diagram 2 A steel ball bearing is taped onto the copper block using cellophane tape. A weight of 1 kilogram is dropped at a height of 50 cm to hit the ball bearing. The diameter of the dent made on the copper block is measured. The experiment is repeated by replacing copper block with bronze block.

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Table 3 shows the results of the experiment. Type of block Copper Bronze Diameter of dent (cm) 0.5 0.2 Table 3

(i) Based on the results of the experiment, compare the hardness between copper and bronze. . [ 1 mark] (ii) Draw a labelled diagram to show the arrangement of atoms in copper and bronze. [3 marks]

(c) Sulphuric acid, H2SO4 is manufactured in industry through Contact Process. This process consists of the following stages: Stage 1 Stage 2 Molten sulphur is burnt in dry air to produce sulphur dioxide. S + O2 SO2 Sulphur dioxide and excess oxygen gas are passed over vanadium (V) oxide catalyst at 450oC to produce sulphur trioxide. 2SO2 + O2 2SO3 Sulphur trioxide

Stage 3

Step I Oleum Step Dilute sulphuric acid II

(i) Describe Step I and Step II in Stage 3. [2 marks]

(ii) Write the chemical equation for Step I and Step II in (c)(i). [2 marks]

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Bahagian C An experiment was conducted to find out the effect of temperature on the rate of reaction. 50 cm3 of sodium thiosulphate solution 0.2 mol dm-3 at 30 oC was put into a 150 cm3 conical flask. Then the conical flask was placed on an X sign on a piece of white paper. 5 cm3 of sulphuric acid 1.0 mol dm-3 was added to the sodium thiosulphate solution and shaken. At the same time, the stop watch was started. The stop watch was stopped as soon as the X sign was no longer visible. The same steps of the experiment were repeated for sodium thiosulphate solution which was heated to 35oC, 40oC, 45oC and 50oC. Diagram 1 shows the reading of the stop watch for each of the reaction at different temperatures.

Time ,t1 at 30 o C

Time ,t2 at 35 o C

Time ,t3 at 40 o C

Time ,t4 at 45 o C

Time ,t5 at 50 o C

Diagram 1
(a) Record the time for each reaction in the spaces provided in Diagram 1. [3 marks] (b) State one observation in this experiment. [3 marks]

12

(c)

Construct a table and record temperature, time, and 1/ time for this experiment.

[3 marks]

(d) (i)

Plot a graph of temperature of sodium thiosulphate solutions against 1/ time. [3 marks]

Graph of temperature against 1/ time

13

(ii) Based on the graph in (d) (i), state the relationship between the rate of reaction and temperature. . [3 marks] (e) Complete the Table below based on the above experiment.

Type of variable (i) Manipulated variable: . . .

Action that needs to be taken The way to manipulate the variable: ... ... ...

(ii) Responding variable: . . .

What to observe in the responding variable: ... ... ...

(iii) Fixed variable: . . .

The way to maintain the fixed variable: ... ... ...

[6 marks]

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Skema

(a)

(i)

A mixture of two or more elements with a certain fixed composition in which the major component is a metal.

1 1 2

(ii)

1. Improve the appearance 2. Improve the strength and hardness 3. Increase the resistance to corrosion
[Any two corrections] Bronze is harder than copper.

1+1 2 1

(b)

(i) (ii)

1. 2. 3. 4.

Pure copper is made up of same type of atoms and are of the same size. The atoms are arranged in an orderly manner. The layer of atoms can slide over each other. Bronze is made up of atoms of different size// In bronze, tin atoms and copper atoms are of different size. 5. The atoms are not orderly arranged// The presence of tin atoms disturb the orderly arrangement of copper atoms. 6. This reduces/prevents the layer of copper atoms from sliding.

1 1 1 1 1 1 Max5

(iii)

Pure copper:

Copper atom
[minimum 3 3 layers ] Bronze: 1

Tin atom

Copper atom

1+1 3

(c)

(i)

Sulphur trioxide is dissolved in concentrated sulphuric acid to form oleum. Oleum is diluted with water to produce sulphuric acid. SO3 + H2SO4 H2S2O7

1 1 1

(ii)

15

H2S2O7 + H2O 2H2SO4 (iii) Moles of S = moles of sulphur = 48 / 32 =1.5 Volume of SO2 = 1.5 24 dm3 = 36 dm3

1 1

1 Total 7 20

Paper 3 a) KK0503 Measuring and using numbers EXPLANATION [Able to write all the times with units accurately] Suggested answer: t1 55.0 s, t2 48.0 s , t3 42.0 s , t4 37.0 s , t5 33.0 s [Able to record all the times accurately but without units / no decimal place] t1 55.0 , t2 48.0 , t3 42.0 , t4 37.0 , t5 33.0 // // t1 55 s , t2 48.0 s , t3 42 s, t4 37s, t5 33s [Able to write at least 3 readings of the times accurately] No response given / wrong response 1 (b) KK0501- Observation EXPLANATION [Able to state the colour of sulphur and the rate of it is formed] Suggested answer: Pale / light yellow precipitate is slowly formed [Able to state the colour of sulphur] Pale / light yellow precipitate is formed. [Able to state the formation of precipitate] A precipitate is formed. No response given / wrong response 1 (c) KK0506 Communicating EXPLANATION [Able to construct a table correctly containing three labeled columns with correct units and record all the time and 1/time accurately ] Suggested answer: SCORE SCORE 3 2

SCORE 3

1 0

2 1 0

16

Temperature, 30 35 40 45 50 o C Time , s 55.0 48.0 42.0 37.0 33.0 1 / time , s-1 0.018 0.021 0.024 0.027 0.030 [Able to construct a table correctly containing three labeled columns with correct units and record all the time and 1/time but not accurately] [Able to write at least 3 readings of the times accurately] No response given / wrong response

1 0

1 (d) (i) KK0506 Communicating EXPLANATION [Able to draw a graph accurately that consists of the following aspects] Suggested answer: 1. Both axes labeled and units ( Y axis - temperature , X axis 1/ time ) 2. All points transferred correctly 3. Uniform scale, graph size covers at least half of the graph paper. 4. Straight line/ best fits drawn [Able to draw a graph that consists of the following aspects] 1. Both axes labeled / units ( Y axis - temperature , X axis 1/ time ) 2. At least three points transferred correctly 3. Uniform scale, graph size covers at least half of the graph paper. 4. Straight line/ best fits drawn [Able to draw a graph that consists of the following aspects] 1. Both axes labeled and units ( Y axis - temperature , X axis 1/ time ) 2. Draw a line No response given / wrong response 1(d)(ii) KK0509 To define Operationally EXPLANATION [Able to interpret the relationship between the rate of reaction and the temperature of sodium thiosulphate solution from graph accurately] Suggested answer: The rate of reaction is directly proportional to the temperature of sodium thiosulphate solution // As the temperature of sodium thiosulphate increases the rate of reaction increases. [Able to interpret the relationship between the rate of reaction and the temperature of sodium thiosulphate solution from graph ] 2 SCORE 3

SCORE 3

17

The rate of reaction is proportional to the temperature // the temperature is proportional to the rate of reaction // the rate of reaction increases when the temperature increases. [Able to state an idea of hypothesis The temperature affects the rate of reaction. No response given / wrong response

18

1(e) KK0510 - State variables EXPLANATION [Able to state three variables and three action to be taken] Suggested answer: Variable Manipulated: Temperature Action to be taken Heat the sodium thiosulphate solution at different temperature // Use different temperature. Record the time taken for X mark to disappear from view. SCORE

Responding: Rate of reaction / time taken for X marks to disappear from view. Controlled : Use the same concentration and volume Concentration and volume of H2SO4, of H2SO4 /sodium thiosulphate solution concentration and volume of sodium // Use same size conical flask. thiosulphate solution, size of conical flask. [Able to state any two variables and any two action to be taken] [Able to state any one variables and any one action to be taken] No response given / wrong response

2 1 0

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