Code No: RR210802 Set No.

1
II B.Tech I Semester Supplimentary Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
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1. (a) Define and explain Inductive effect.

(b) Explain why aniline is less basic in comparison with methyl amine. [10+6]

2. What is alkylation and acylation? Give at least three different examples of each.
[16]

3. (a) Describe the chlorination of methane in the presence of peroxides.

(b) Discuss the chlorination of ethane in the presence of heat. [8+8]

4. (a) Discus the methods of resolution of recemic mixtures.

(b) What is the criterion of enantiomerism? [10+6]

5. Write a note on conformational analysis of cyclothexane. [16]

6. (a) What are Polymers? How are they Classified?

(b) Discuss the importance of Synthetic high polymers.
(c) Describe the preparation of nylon(6) from cyclohexanone. [6+5+5]

7. (a) How will you prepare Quinoline? How does it react with the following reagents?
i. HN O3 / H2 SO4
ii. H2 SO4
iii. KMnO4 .
(b) Give two methods of synthesis of pyridine. [11+5]

8. (a) What are dyes?

(b) Explain the classification of dye based on their chemical structure. [6+10]

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Code No: RR210802 Set No. 2
II B.Tech I Semester Supplimentary Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆

1. (a) Explain the following applications of Inductive effect

i. Effect of bond lengths
ii. Dipole moment
iii. reactivity of alkyl halide
(b) Discuss the strength of carboxylic acid based upon Inductive effect. [9+7]
2. Write a detailed note on Perkin reaction with mechanism. [16]
3. Formulate and give mechanism for the following reactions :-
(a) NBS and isobutylene
(b) Ditorane and isobutylene followed by treatment with H2 O2 . [8+8]
4. (a) Which of the following compounds exhibit optical isomerism?
i. Nitromethane
ii. Methyl chloride
iii. Glyceraldehyde
iv. Ethylene glycol
(b) Describe a method to determine the optical activity of an organic compound.
[8+8]
5. (a) How maleic acid and fumaric acid react with acetyl chloride? What inference
you get from this reaction?
(b) Write a note on E and Z configurations of geometrical isomens. [8+8]
6. (a) What is natural wool? How is it obtained?
(b) Explain the difference between natural and artificial silk. How are they dis-
tinguished? [8+8]
7. (a) Compare the basic nature of the following pairs of compounds and justify your
comparison.
i. Pyridine and pyrrole
ii. Pyridine and trimethylamine.
(b) How will you prepare Quinoline from aniline? [8+8]
8. Give a brief account of the chemistry of Diphenylamine and Triphenylamine dyes?
[16]

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Code No: RR210802 Set No. 3
II B.Tech I Semester Supplimentary Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆

1. Discuss about polar effects briefly such as inductive, hyperconjugation and reso-
nance effects. [16]

2. Show the reaction mechanism of aldol condensation and describe its uses. [16]

3. (a) Describe the chlorination of methane in the presence of peroxides.

(b) Discuss the chlorination of ethane in the presence of heat. [8+8]

4. Explain the following

(a) Chiral center

(b) Plane polarised light
(c) Meso compound
(d) Conformational isomers [4×4]

5. How will you assign E-Z notations to geometrical isomers? Explain with suitable
examples. [16]

6. (a) Describe the preparation of natural rubber from latex.

(b) What are bakelite resins and how are they made. [8+8]

7. (a) How will you obtain the following heterocyclic compounds.(Mention any two
methods)
i. Pyrrole and
ii. Quinoline.
(b) In pyridine, electrophilic substitution reaction occurs chiefly at C-3. Why?
[8+8]

8. Explain what are

(a) Direct dyes

(b) Mordant dyes
(c) Vat dyes
(d) Ingrain dyes with examples. [16]

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Code No: RR210802 Set No. 4
II B.Tech I Semester Supplimentary Examinations, November 2007
ORGANIC CHEMISTRY
(Chemical Engineering)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆

1. Discuss about polar effects briefly such as inductive, hyperconjugation and reso-
nance effects. [16]

2. (a) Discuss about hydroboration with reaction mechanism.

(b) Describe the Perkin condensation. [8+8]

3. (a) What are free-radicals ? How are they formed?

(b) Describe the free-radical type halogenation of alkanes. [10+6]

4. (a) Discus the methods of resolution of recemic mixtures.

(b) What is the criterion of enantiomerism? [10+6]

5. Write a note on conformational analysis of cyclothexane. [16]

6. (a) Describe the manufacture, properties and uses of Teflon. How is tetrafluo-
roethylene prepared?
(b) Discuss the preparation, properties and uses of bakelite. [8+8]

7. (a) How pyridine can act as a stronger base than pyrrole?

(b) How will you get isoquinoline? [8+8]

8. (a) Explain the terms : leuco base, colour base and a dye, giving suitable example
(b) Give the preparation and uses of either Fluoroscien or Malachite green. [8+8]

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