Test 11 Name _________________________ Section ____________ TA ___________________________ Chemistry 115-M EXAM I Monday, 8:00 PM September 20, 2010 THIS

EXAM IS FOR STUDENTS WITH MONDAY-FRIDAY 2:30 or 3:30 PM LECTURE. YOU SHOULD HAVE A GREEN COMPUTER ANSWER SHEET! Directions: 1. 2. Each student is responsible for following directions. Read this page carefully. Write your name and other requested information on this page and on the separate answer sheet. CODE your name on the answer sheet using an ordinary (#2) pencil. CODE your correct 10-digit identification number (PUID) on the answer sheet. THIS IS VERY IMPORTANT! CODE your section number on the answer sheet. Please use all four digits, 0101, 0102, 0201, etc. This is also very important! CODE the test number shown in the upper right-hand corner on the answer sheet in the block labeled Test/Quiz Number. This is Test 11. Put all calculations on the examination pages. DO NOT PUT ANY EXTRA MARKS ON THE COMPUTER ANSWER SHEET! This exam consists of 20 multiple-choice questions worth 7.5 points each. Choose the one best or correct answer for each question and write it both on your exam paper and on the computer answer sheet. The computer answer sheet is the only one that will be graded! This exam consists of 6 pages plus a Table of Useful Information, a Periodic Table and a sheet of scratch paper. Please check to be sure that you have them all! Total Points = 150

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KEEP YOUR ANSWERS AND WORK COVERED TO PROTECT THE INTEGRITY OF YOUR WORK!!

115-M Exam 1 (Test 11) 09/20/10

_____ 1.

The balanced chemical equation for the degradation of glucose (C6H12O6, MW = 180.2 g/mol) to carbon dioxide and water is C6H12O6 + 6 O2 6 CO2 + 6 H2O What is the mass of water produced by the degradation of 856 g C6H12O6? (a) (b) (c) (d) (e) 4.75 g 28.5 g 209 g 514 g 1250 g

_____ 2.

Methanol (CH3OH) burns in oxygen to produce carbon dioxide and water. The chemical equation below is not balanced. What is the stoichiometric coefficient of the oxygen (O2) in the balanced chemical equation? ____CH3OH + ____O2 (a) (b) (c) (d) (e) 1 2 3 4 5 ____CO2 + ____H2O

_____ 3.

A student finds a balloon that has 0.1000 moles of laughing gas (N2O) and 0.1000 moles of methyl chloride (CH3Cl). Assuming that the balloon has a volume of 200.0 mL and the room is 25.00 C, what is the total pressure inside the balloon? (a) (b) (c) (d) (e) 1.026 atm 2.053 atm 12.20 atm 12.23 atm 24.47 atm

_____ 4.

Which of the following energy sources is renewable and carbon-free (does not contribute to the buildup of carbon dioxide in the atmosphere)? (a) (b) (c) (d) (e) Solar radiation Enriched uranium dioxide Oil Coal None of the above

115-M Exam 1 (Test 11) 09/20/10

_____ 5.

The effect of humans must be considered to satisfactorily model the temperature anomalies (changes) of the past 100 years. Which of the following is a result of the temperature anomaly (change)? I. melting glaciers II. increase in carbon dioxide concentration III. increase in volcanic eruptions (a) (b) (c) (d) (e) I II III I and III I, II, and III

______ 6.

As part of the Reactions in Aqueous Solution laboratory you reacted small portions of copper (Cu), zinc (Zn), and magnesium (Mg) metals with hydrochloric acid (HCl). For this type of reaction what was the indication a reaction had occurred? (a) (b) (c) (d) (e) A dark or black deposit formed on the metal. A blue deposit formed on the metal. The solution turned cloudy and slightly yellow. Bubbles appeared. A yellow orange solid formed.

_____ 7.

What is the correct formula of an ionic compound that contains calcium and bromide ions? (a) (b) (c) (d) (e) CaBr CaBr2 Ca2Br2 Ca2Br CaBr3

_____ 8.

Two isotopes of oxygen are 18O and 16O. These two isotopes have different: (a) (b) (c) (d) (e) numbers of protons. atomic numbers. numbers of electrons. charges. mass numbers.

_____ 9.

Identify the process by which beryllium-7 (Be-7) is formed from lithium-7 (Li-7). (a) (b) (c) (d) (e) Beta decay Alpha decay Positron emission Electron capture Oxidation

115-M Exam 1 (Test 11) 09/20/10

_____ 10.

Radioactive iridium-192 is used to treat cancer. A patient is given 1.0 mg. After 148 days only 25% of the original iridium is left. What is the half-life of iridium-192? (a) (b) (c) (d) (e) 37 days 74 days 101 days 148 days cannot be determined from given information.

_____ 11.

The half-life of a 20.0 g sample of a radioactive substance is 15 hours. What is the half-life of a 5.0 g sample of the same substance? (a) (b) (c) (d) (e) Cannot be determined from the given information. 3.75 hours. 7.5 hours 15 hours 60 hours

_____ 12.

Identify X in the following reaction:

235 92

U + 1n 0

134 54

Xe + 2 1 n + X 0

(a) (b) (c) (d) (e)

98 38 99 36

Sr Kr Rb

100 37

100 38
101 38

Sr

Sr

_____ 13.

A very small percent of naturally occurring carbon, which is predominantly the stable isotope carbon-12, is radioactive carbon-14. The most likely mechanism by which carbon-14 would decay is: (a) (b) (c) (d) (e) alpha decay positron emission spontaneous fission electron capture beta decay

115-M Exam 1 (Test 11) 09/20/10

5
238 92

_____ 14.

Determine the binding energy for the

U nucleus.

[masses of nucleons: 238 U = 238.05078 amu; 1 p = 1.007825 amu; 1 n = 1.008665 amu; 92 1 0 1 amu = 1.661 x 10-27 kg] 1.42 x 108 J 3.53 x 108 J 2.89 x 1010 J 9.64 x 1019 J 1.74 x 1017J

(a) (b) (c) (d) (e) _____ 15.

The half-life of 226Ra is 1620 years. Starting with a pure 1.00 g sample of 226Ra, what weight of Radium will be present at the end of 10.0 years? (a) (b) (c) (d) (e) 0.004 g 0.030 g 0.999 g 0.970 g 0.996 g

_____ 16.

The following decay is an example of which type of decay?

39 20

Ca

39 19

K + ?

(a) (b) (c) (d) (e) _____ 17.

positron emission alpha decay beta decay gamma emission neutron capture

What is the purpose of the control rods in the nuclear reactor in a nuclear power plant? (a) (b) (c) (d) (e) to absorb protons to keep the reaction going to absorb neutrons to slow/stop the reaction to absorb electrons to slow/stop the reaction to cool the superheated water to rotate the turbine to generate electricity

_____ 18.

Which of these has the highest binding energy per nucleon? (a) (b) (c) (d)
1 1

H
He Fe

4 2

56 26

238 92

115-M Exam 1 (Test 11) 09/20/10

(e) _____ 19.

55 25

Mn

Which is a fusion reaction? (a) (b) (c) (d) (e) Ca(s) + 2 HBr(aq) H2(g) + CaBr2(aq)
2 1

H +

3 1

4 2

He + 1 n 0

Na2CO3(s) + 2 HCl(aq) 2 NaCl(aq) + H2O(l) + CO2(g)

235 92

U + 1n 0

144 56

Ba + 89 Kr + 3 1 n 36 0

Na2CO3(aq) + Ni(NO3)2(aq) NiCO3(s) + 2 NaNO3(aq)

_____ 20.

The radioactive isotope 238Pu used in pacemakers decays by emitting an alpha particle. The isotope has a half-life of 86 years. After 10 years the activity of the isotope decreases by 8.0 percent. What is the rate constant (k) for the decay? (a) (b) (c) (d) (e) 8.1 x 10-3 y-1 2.3 x 10-2 y-1 6.9 y-1 60 y-1 86 y-1

END OF EXAM 1) Please make sure that you have entered 20 answers on your scan sheet. 2) Make sure that you have entered your name, ID number, and lab section number (4 digits). 3) You MUST turn the scan sheet in to your TA before leaving the exam!

115-M Exam 1 (Test 11) 09/20/10

7 USEFUL INFORMATION

K = 273.15 + C

R = 8.206 x 102 Latm/(molK) c = 3.00 x 108 m/s

PV = nRT E = h =
hc

1 amu = 1.661 x 1027 kg h = 6.63 x 1034 Js

1 n2
2

E = mc2
1 1 n12

RH

RH (Rydberg constant) = 1.096776 x 107 m1

dN = -k[N] dt

1 atm = 760 mm Hg (exactly) = 760 torr

ln

N N0

kt

1 J = 1 kg m /s

k t1/2 = ln 2

115-M Exam 1 (Test 11) 09/20/10

115-M Exam 1 (Test 11) 09/20/10

9 ANSWERS

1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) 15) 16) 17) 18) 19) 20)

D C E A A D B E A B D D E C E A B C B A