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PROGRAM PENINGKATAN PRESTASI AKADEMIK SPM

CHEMISTRY
Paper 2
Two hours and thirty minutes
JANGAN BUI(A KERTAS SOATAN INI SEHINGGA DIBERITAHU
1.

Kertas soalan ini adalah dalam dwibahasa. Soalan dalam Eahasa lnggeris mendahului soalan yang sepadan dalam Bahasa

2.

Untuk Kegunaan Pemeriksa Markah Markah Bahagian Soalan Penuh Dioeroleh

1

Melayu.
Calon dibenarkan menjawab keseluruhan atau sebahagian soalan sama ada dalam Bahasa lnggeris atau Bahasa Melayu.

10 10 10

2 3 A

4
5 6 7
B

10
10 10

4.

Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini.

20 20 20 20

8 9

c
10 Jumlah Kertas soalan inimengandungi

27 halaman bercetak

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INFORJ}'ATION FOR CA}I DI DATES MAKLUMAT UNTUKCALON

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l. 2.

This question paper consists of three sections: Sections A, B and C. Kertas soalan tni mengandmgi tiga bahagian: Bohaglan A,B dan C. Answer all guestions in Section ,A,. Write your answers for Section A in the spaces provided in the question paper. Jaw ab semua soalan dalam Bahagian A. Tul iskan j aw apan 6agz Sahegi an A da lam rucng yang disediakan dalam kertas soalan Answer one question from Section B and one question *om Section C. Write your answers for Section B and Section C on the 'writing paper' providd by the

3.

invigilaton.
Answer questions in Section B and Section C in detail. You may use equations, diagrams, tables, graphs and other suitable methods to explain your answer. Jswab sttu soalan daripada Bahagian B dan satu soslan dcripda Bahagian C. Tuliskan juwapan bagi Bahagian B dan Br.hagitn C pada haloman bergaris di bahagian akhir kertas soalan ini. Jawob Bahagian BdanBlthrgianC dengon terperinci. Anda boleh menggunakan perserrnean, gambar rqiah, jadual, grof dan cara lain yang sesuni untuk menjelasktn jawapan anda

4-

Show your working. It may help you to get marks. Tunjull<an kerja mengira.Ini membantu anda mendapatkan markah.

5. 6. 7. B.

If you wish to change your answer, neatly cross out the answer that you have done.
write down the newanswer.
Sekiranya anda hendak membatalkon sesuatu jswapan, buat garisan

T?ren

di

atas jawapan itu.

The diagrams in the questions ar not drawn to scale unless stated. Rajah yang mengiringi soalcn tidak diluhisksn mengikut skala kecaali dinyatakan

Marks allocated for each question or part question are shown in hackets. Markah yang dipenmakkan bagi setiap soalan atau cetaian saalan ditunjui*an dalam kurungan
The time suggested to answer Section A is 90 minutesn Section B is 30 minutes and Section C is 30 minutes. Masa yang dicadangkan untuk menjawcb Bahagian L ialah 90 minit, Bahagien B ialah 3O minit &tn Bahagian C ialah 30 minir

9.

You may use a non-programmable scientific calculalor Anda dibenarkan mengunakan kalkulator saintifkyang tidak baleh diprogramkan.

10. Hand in your answer sheets a the end of the examination. Serahkan semuo kertas jawapan anda di akhir peperikaan

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Section

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16A marksl Answer all'questions in tlris section

Jowob sernufr soalan dalam hahagian ini.

Figure I show the electron arrangetnent of three atoms of elernents P, Q and R Rajah I menunjuk*an susunan eleloron bagi tiga atom unsw P,Qdan R

Figure I

(a)

Write the electron &rangement for the atoms of element R.

Tuliskan susunctn elektron bagi atom unsur R.

{l
(b) Identify the position of element Q Kenol pasti kedudukan unsur Q.

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(c)

(i)

Which element is chemically inert? Unsur yang manakah lengai dari segi kimia?

ll

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(ii)

Give one reason for the answer in c (i) Beri satu sebab bagi jawapan di c (i)

ll

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(d)

Element Q dissolves in waterto form an acid and a strCIng bleaching agent. Write the chemical formulae of the bleaching agent. (Insur Q larut dalam air untuk membentuk satu asid dan satu agen pelwnr yang huu. Tuliskan formula kinia bagi ogen pelunhr ltu.

U markj

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(e)

Another element S has a proton number of 9. V/hich element shows similar chemical properties to element S? Uwur Inin, S mempunyai nombor proton9. Unsw yang manakah menunjuldran sifat kimia yang scna dengan unsur

S7

mark\

(g (i)

Which element. react vigorously with water?

Urcur yong manoftah benindak balas dengan cergcw dengan air?

$ nar*l

(ii)

Based on the answer in

Berdasarlcon jawapan

(i) ,write the chemical equation for the reaction" di fii) ,tulislnn perscrrflaan Hmia bagi tindak balas itu.
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(g)

Arrange the atomic size ofelements P, Q and R starting from the smallest. Sustmkon saiz atom unsur P,Q den R bermula daripada yang paling kecil-

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t Diagram 2 shows an experiment !o dctermine the empirical formula of copper (It) oxide. Rajah 2 menunjulr.kan satu ekperimen antuk menmtr*anfornula empirik kuprum(ll\ obida.

Combustion tube
Tabung pembakaran

Coppe(Il) oxide Kupnn(II) oksida

'Hydrogen flame
Nyalaan hidrogen

Dry hydrogen gas \ Gas hidrogen kering-

Heat
Ponaskon

Diagram 2

(a)

What is meant by empirical formula?

Apakah yang dimoksttdlcan dengot formula empiri k 2

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(b)

Before copper(Il) oxide powder is heate{ dry hydnrgen gas is flowed through the combustion tub for a while. Why? Sebelum serbuk hpram(ll) okida dipouskan, gas hidrogen kering dialirlcan melalut tiub pembakoran seloma beboapa ketiha. Mengapa?

ll

markl

(c)

State the observation that happens to copper(Il) oxide after heating.

Nyatukan pemerhaticn

lang berlahu kepada kuprun(Il) akida

selepas pemanosun.

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Table 2 shows the result obtained in tfte experiment: Jadaat 2 menunjrkkan keputusan yang diperolehi dalam eksperimen di atos

Mass of combustion tube + asbestos paper Jisim tiub pembakaran * kertas asbestos Mass of combustion tube + asbestcs paper + coppe(ll) oxide
Jisim tiab nembalcaren + kertas asbestos+ fuprw(ll\ olsida Mass of cornbustion tub + asbestos paper + copper Jisim tiub oembakaran + kertas asbestos* kuprwn

58.36 g 91.95 g 85.2a g

(i)

Table 2 Based on Table 2, Berdosarkan Jadual 2, Calculate the mass of coppr and the mass of oxygen that have reacted. Hitungkan jisim kuprum dan jisim oksigen yang telah bertindak balas. Mass of copper
Jisim kuprum: Mass of oxygen Jisim oksigen:
:
:

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(ii)

Calculate the ratio of moles of coppr atoms to oxygsn atoms.

Hitungktn nisbah mol bagi atom kuprum kepada atom oksigen. I Relative atomic mass /Jisim atam relatd:0 = 16 ; Cu:64 ]

(iii)

12 marks]

Determine the empirical formula of copper (II) oxide.

Tentuksnformula empirift kuprum (Il) oksida-

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(iv)

Write the chemical equation for the reaction in the experiment. Tulis persamaan bimia bagi tindakbalas dalau eksperimen tersebut'

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(v)

This method is not suitable to determine the empirical formula of magnesium oxide.

whv?
Kaedoh ini tidak sesusi untwk menentukanformula empirik bagi magnesium olcsida.
Kenapa?

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p and respectively' are industrial processes to manufrcture sulphuric acid and ammonia in Sufptrgic acid and ammonia are usd to manufacture ammonium sulphate as shown

Diagram 3.1 p ian Q adalah proses-proses indttspi untuk menghasilkan asid salfwik don anmonia maslng' ammcnium sulfat seperti dala*t masiing.)"sid sutfurik ioi *rirni" digwahan rmtik mengftasilkan Rajah3.l

Reaction R

Tinda*balasR

Ammonium sulPhate
Ammonium

sulf*

(NH4hSO4

Diasram 3.1 Name

(a)
Namakan

(i)

Process P:
Proses P

{ii}

Process Q
Proses Q

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{b)
State one raw material needed for procsss Q? Nyvtakon satu bahan mennh yang dtperlukan mtuk proses Q?

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(c)

(i)

Write a balanced chemical equation for reaction R

Tulis persamaan Hmia yang seimbang bagi tindak balas R

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i)

State one use of ammonium sulphate Nyatakan satu kegunaan ammonium sulfat

(iii)

Calculate the percentage of nitrogen by mass in ammonium sulphate

Hi tung pe ratus nitrogen mengikut j is im bagi amnonium sulfat.

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I Relative atomic mass / Jisim stom relatif: N

14 ; O

16; S = 32; H

=I

f 2 nartcl
(d) Diagram 3.2 shows the structuralformula of the polymer polyvinyl chloride Rajah 32 menunjuk*anformula struktur bagi polimer polivinil Horida

HCI
C
I I

Diagram 3.2 Draw the structural formula for its monorner LuVsformula struhur bagi monomer polimer tersebut

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{e) The use of synthetic polyrners extensively in our daily life has become an issue

of environmental pol lution. Penggunaan poliwer sintetik secara berlebihan didalom kehidupan seharian telah menjadi isu kepada pencemaran alam sekitar.
Give one method to overcome this problem. Berikan salu kaedah untuk mengatasi masalah ini

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Diagram 4.I and 4.2 shows a set up apparatus to investigate the role of water for acid to show its acidic properties. Rojah 4.1 ond 4.2 menunjukkan radas wuk menglaji peranan air untuk asid menuniukJan sdat
keasidannya.

Dry hydrogen chloride gas Gas hidrogen Horida kcrW

Methylbenzene

Metilbewena

Diagram

4.1

Dry hydrogen chloride gas Gas hidrogen Horida kcring

Water

Air
Diagram 4.2

(a)

Write the chemical formula of hydrogen chloride Tulisformula kimia hagi hidrogen Horida

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(b) (i)

Dry hydrogen chloride gas is bubbled in methylbernene for 5 minutes as shown in Diagram 4.1, then tssted with a piece of blue litrnus papr. State the observation. Gas hidrogen Horida kertng dialirkan masuk dalam metilbewena selama 5 minit seperti yang ditunjuW@n dalam Rnjah 4.1, kemudian diuji dengan sekeping kertas
Iitmus
b

iru.

Nyatakan pemerhatian.

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(ii)

Jelaskan jawapan anda

Explain your answer in b(i) dalamVi)

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(c)

Diagram 4.2 shows dry hydrrrgen chloride gas bubbled into water for 5 minutes. The solution is then divided into two parts, Part I and Parf II. Table 4 shows the observations of the two tests conducted on the two parts. Rajah 4.2 menunjukkan gas hidrogen Horida kering dialirtan masuk dalam air selama 5 minit . Larutan itu dibahagikan lepada dua bahagian, Bahogianl dan Bahoglaull.
Jadual 4 mentnjulckan pemerhatian bagi dua ujian yang dijalankan ke atas duo bahagian ita.

Part
Bahagian

Test
Ujian

Obseivation
Pemcrhorian

Add magnesium carbonate. Testgas given off with lime water

Tambahkon
m agn e s

Effervescence
Pembuakan

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karbonat.

Uji gas yang terbebas dengon air kapw

Lime water turns chalky Air kapur menjadi luruh

II

Add magnesium ribbon. Test gas given offby pufting in lighted wooden spl inter
Tambahkan pit a ma gn es i wn. Uji gas terhasil dengan memasukkan Irayuuji menyala

(i)

Table 4 State the role of water that caused the produced gas turns lime water chalky. Nyatakan peranan air yang menyebabkan penghasilan gas yang menukarkan air kapur menjadi keruh.

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(ii)

Write an ionic equation to the reprsnt the production of gas in Part

Tulis persamaan ion unuk mewakili penghasilan gas dalam Bahagian

I
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12

(iii) (iv)

Complete the observations in Table 4. Lengkapkan pemerhatian dalom Jadual 4

[2 marksl
What is the conclusion drawn from the observation in both part? Apakah kesimpulan yong boleh dibuat daripada pemerhatian dalom keduoduo bahagian.2

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Diagram 5 shows the flow chart for dte reaction of propan-l-ol. Rajah 5 menunjukkan carta alir bagi tindak balas propan-l- ol . Reaction

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Tindak balorl Compound X

Sebatian

tll H-C-C-C-OH

HHH

Reaction
Tindalc

II
Compound Y SebatianY

balasll

alumina
Heated
Panaskan

trl HHII

-------------*
KMnOt
berasid

Acidified KMnOe

Propan-l-ol

Reaction III l+ CH3COOH findakbala-sfit + HzSOa f

Compound Z
Sebatian

Diagrarn 5

(a) State the molecular

formula of propan-l-ol. Nyatakanforrmrla molehi bagi propan-l- ol.

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(b) The following

equation shows complete combustion of propan-l-ol. Persamaan berilat memrnjuklmn pembakarorc lengkap propan-l -ol.

C3H7OH + 9O2 -*+ 3COz + 4H2O

2
Calculate the volurne ofcarbon dioxide gas produced

if

0.1 mol of propan-l-ol is bumt

completely in air.
Ilinmgkan isipadu gas karbon dioksida yang terhasil jika A.l mol propan-l-al dibakar dengan
Iengkap dalam udara.

[Molar volume :24

dm3

mol-l at room condition]

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(c)

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Compound X is an unsaturatcd hydrocarbon. SebatianX adalah hidrokarbon tery.

(i)

What is the meaning of hydrocarbon?

Apakah yang dimaksudkm dengan hidrokarbon?

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(ii)

Complete the following diagram to collect compound X in reaction I.

Lengkapkan rajah berihtt unluk mengutip sebatian X dalam ttudak balas

l.

hopan-l-ol

soaked

with glass wool

Alumina

warrn

(d) hopan-lol

12 marksJ

is addsd with acidified potassium marganate

(VIt) solution and heated in

reaction II. Propn-l- oI

ditambahhan dengan larutan kaliun mangout (Yl7) berasid dan dipanaskan dalan

tindak balas lL

(i)

What is the name of reaction II? Apakah nans tindak bolas ll?

(ii)

Name compound Y.
Namakan sebatian Y.

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(e) Compound Zhas the following properties:

SebatUn Z mempnyai stfat-stfat beri*at :

o r (i)

Float on water Terapwg otas oir

Fruity smell
Yangi bwh-buahan

Draw the sfuctural formula of oompound Z. L*is formula smrkur bagi sebatian Z.

(ii)

Concer*rated sulphuric acid is added in reaction lll. Explain why? Asid sulfurik pelcat ditambah dalmt tindak balas lll .
Teranglan mengapa?

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6 (a)

rection between Jdual

Table 6 shows the result ofan experimcnt to study the cffet oftemperafure on the rate 50 cm3 1.0 mol dm-3hydrochloric acid solution, HCI and 50 cm3 0.2 mol dm-3 sodium thiozulphate soluticiq NazSzOr.

of

6 memmjuk*an kepr.hrsan bagi satu elrspeimen unn* menglraji kesan guhu kcatas kadar 50 cm3 1.0 mol dmo t*uton asid sulfarih HzSOr dan 5A enf 0.2 mol &n'3 tindakbalas

*i*o

lorutan natlium tiosulfat, NazSzQ.

TemperaturefC SuhufC Timc taken for'X' mark to disappear fronr sight Masa tanda X' hilansdari pandoutt
Table 6

30
94.8

35 49.9

40
36.1

45

50
19.8

25.2

(a)

Balanced the ctremical equmion below for the reaction that occurs in this erperimenL &imbangk*t percomaail kimia dibov,ah bagi tindakbalas yang berlaht dqlan ekprimen ini.

mHCl+Na2S2O3t nNaCl+HzO + Soz+

m=
TI:

{2

narksl

(b)

Draw the set-up of apparatus used to measure the time taken for 'X' mark to disappear from sight. Lakis*an susunan radas yng digwakan untuk mengalatr maso tanda'X' hilang dti

Q marksl

(c)

Name the substance that is responsible for'X' mark to disappear from sight. Nama*mt bahan yvng menyebablcan tanda X' hilang dari pandangan-

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(d)

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'Flot a graph of temperature against time taken for'X' mark to disappear from sight. I^akarkan graf suhu melasan masa tando'X' hilotg doi padmgan
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(e) Based on the graph in (d), sbte the relationship between temperature and time.
Berdasarkon

graf pada (d), nyatakm hubwgan qntara $rtu dan masa.

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Section B Answer any one question. Javtab m(rnt -rnsna sala soolan.

[20 rzr:ksl

Table 7 shows the proton numberofatom P, Q, Rand S. The letters used do not represent the actual symbols of the atoms. Jadual T mmwJulikan nombor proton untuk atom P, Q, R dcr S. Hun{yng diganakan tidak mewakili simbol sebens atom berkenaan.

Atom
P

Atom
Proton Number Nombor proton

a
12

t7

Table 7

{a) ,

Write the electron arrangement for the atom of element Q Determine the group for element Q Talis susunan elekron bagi atom rrrrrQ. Tentufun funpulan untuk msw Q.

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O) (i) (ii)

7, sel*t two differpnt elemen8 that can form ionic compound. Berdasarkan Jaduol T, pilih dua unsur Malnan yang akan membentuk sebation ion.

Basd on Table

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Draw a diagram to show the compound tlrat will be formed in 7(b) (i) Lulris rajah untuk menunjul*an sebatiot yang terbentulc di 7(b) (i)

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(c)

Diagrarn 7 shows the molecule of carbon dioxide. The bond formed between carbon atom and oxygen atom are double covalent bond. Rajah 7 menunjuk*an molekul karbon dlokida. Ikatanyang terbentuk antara atom Iurbon dan atom olsigen ialah ilcatan kovalen ganda dua.

Dagram 7
Explain the formation of this compouod in terms of o Electron arrangement r Electrons involved o Particles involvod [Proton number :C:6, O: 8 J
Terangkan tentang pembmwkan sebatian ini dari segi: Susunan elehron
:

t o

Elektron yang terlibat

Zaroh-zorahyangterlibat.
15

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(d)

Compare the physical propcrties benpeen ionic compound and covalent compound. Your answer should consist of the following : Physical properties in roorn conditions

o o o r o

Melting point and boiling point Electricalconductivity Solubility in water and organic solvent Example ofcompound

Bandingkan sifat*ifutfizikal di utoa sebatian ion don sebatian kovalen. Dalamjawopan ando, perlu mengan&ngi perkara bertlatt : o Keadaon jirim pada kzadaan bilik" t Taknt lebw dan takst didih t Kekonduksiot elekrik

o o

Keterlanttan dalan air dan sebatian organic

Contoh sebatian

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Diagram 8.1 shows the apparatus set-up for the electrolysis of concentrated copper (II) chloride solution, 0.1 mol dm-' using carbon electrodes. Rajah 8.1 menunjulkan susur'rcm radcn untuk me4jalankan elekrolisis larutan larprum(ll) Hirida t pe kat, 0. l mol dm' me ngunokan ele ldrod-e lektrod knrbon.

concentrated coppe(I I)

chloride solution I arut an hprum{ll).

Wlcat

kl or i da

Carbon electrode X Elel*rod karbonX

Carbon elrctrode Etefuod korbonY

Diagram 8.1
(a)
Based on Diagram 8.1, sbte the factors that determine the products formed at electrode X and elwtode Y. Berdasarkan Rajah 8.1, nyatakanfakor-fahor yang menentufran hasil yang terbennk pada

elebrodXdan elekrodY.
.12,

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(b)

Explain the reactions at electrodes, X and Y. Include the following in your explanation: Terangkan tindak batas pada elektod,X dan Y. Penerangan anda perla m

r r r . o

List the ions atttracted to each of elecfode, X and Y Senaraikan ion-ion yang tertarik ke setiap elekrad, X dan Y Name

of

the ions selectively discharged at each elechode

Nams ian'ian yang dipilih

Sebab ion-ion ini

wuk

dinyahcas di setiap

elekrd

The reason why the ions are selectively discharged

dipilih unuk dinyahcas

Half equations for each reaction

Setengah persomaan bagi setiap tindak balas

The observable changes ofthe solution Perubahan yang diperhatikon pada lanttan

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(c) '

Table I shows the incomplete results of a series ofexperiments carried out to c,onsmrct the electrochemical series of metals. W, X and Y are not the actual symbols of the metals.

Jadwl
W,

mmunjal4ran keputusan yang tidak lenglrap bagi satu siri eksperlmen yang telah
bulcan simbol sebenar logam-Iogam itu.

dijalanlwn antukmembina sin elebrokimia bagi logun.

XdanY

Pairs of metals
Pasangan lagan

Positive terminal
Terminal

Potential difference/ V
Beza keupayaan 3.1

positif

W' Copper

Copper

X,Y

Y X

0.3

wx
X, Copper

t.8

Table 8

(i)

Based on the values ofthe potential differences, arrange the metals in descending order in the elecbochemical series.

Berdasarkan niloi beza keupcyaan, susun logam-logan tersebut dalam tertib menuntn dalam siri elekrokimia.

lt ndf,

(iD

Predict the positive terminal and the value of potential difflerence for the pair metals X and Cu. Explain your answer.
Ramulkan terminal positif dan nilai
Jeloskan jawapan anda.

of

heza

bagf pasangan logom X dan

C*
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(d)

Diagram 8.2 shows a voltaic cell. Metal Q is situated below copper in the e leitroch em i stry series. dalam siri Rajah 8.7 menunjakkan saaru sel voltan. Lagam Q terletak di hawah kuprum
elelctrokimia.

Metal Q
Logam Q

Cu

Solution R LarutqnR

Copper${) nitrate Kaprum(ll) nitrut

Diagram 8.2

State the positive terminal and the negative lerminal ofthis cellm"tal Q and a solution that is suitable as solution Suggest a metal that is suitable

R.
Nyatalan terminal posilif dan tenninal negatif bagi sel ini' iaaanske, togam yani sesaai sebagai ligam Q dan larutan yang sesuai sebagai larutan
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Section C

[2A marks] Answer any one qrsstion.

Jawab masra-mana satu soalan,

Table 9 shows the heat of displacement of hvo diffe,rent metals P and Q with copper (II) sulphate solution. Jadual 9 menrmju?Jran luba penysarm bagi dua logam yong berlainan, P danQ dengan larut ot kuprunt{ll) s u lfat.

Experiment

Reactants Bahan Tlndalcbalas

50 cm" 0.2 rnoldm-'

Heat of Displecement I{*ba Penyesaran (kJ mol-I )

-336

coplxr gl)sulphate solution

+

metal P

50 crr3 0.2 moldm't larutan kupram {11'1sulfut

logamP

II

50 cm'0.2 moldm-' copper{U)sulphate solution metal Q 50 cm3 0.2 rnoldrn-t larutst kuprun (ll) sulfut + logam Q

-217

Table 9

(a)

Based on the information in Table 9,

(i) State one exanple which could be metal P and one ex{rmple which could be metai Q. Berdasarksn maftlunat dalam Ja&*al 9, Nyatalam ssta c{}ntoh ymg mwgkin bagi logrnnP dffi sdu contoh yang mungkin bagi
logamQ.

[2 marksl

(ii) Explain why there is a difference in the values of

the heat of displacement. Jelaskon mengapa terdaryt perbezool nilai lwba penyesran itu.

[4 marksl

O) Calculate the change in temperature

I:litang perubahsn sahu hagi campurcm dalam ehryterimen

of the rnixture in experiment I. og't {Specific heat capacity of solution: 4.2 Jg't ,

l-

[4 markl

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{c)

By using one of the metal in 9 (a) (D, describe one experiment to dstermine the heat of displaceinent. Your answer should consist of the following : o Procedure of the experiment

The method to calculate the heat of displacement

Dengan menggunakan satu daripda logam dalam menentukan hcba perqrcsaran.

(aXi), huraikan saw eksperimen tmtuk

Jawapan anda perlu mengandungi perkara berikut : Prosedur elsperim*t

c o

Kaedah untuk menghittmg haba penyesaron.

[10 markrl

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24 (a)

SI]LTT

10

Diagram l0 shows an apparatus set-up, its observation and chemical equation to investigate the displacement of halogen from its halide solution by halogen P. Rajah ft menunjukkan susunan radas , pemerhatian dan prsamaan kimia'untuk mengkaii penyesaran hologen daripada larutsn halidanya oleh halogenP .

larutan

potassium A , P iodide
solution
\ \
kaliumiodida

\H_w

,{, I I

,/

shake
gonccrrg

lr{

t_J

\#-

purple
ungu

l, l, I -trichloroethane l,l,l-triHoroetana

Persamaan

Chemical equation: kimio :

zlf.l + Pz -'+ 2KP + Ie

Diagnm
10

(i) (i0

C adangkan

Suggest the identity of halogen P idmtiti halogen P

U markl
Write half equation for the oxidation or rduction prccess that has occuned. Tuliskon setengah persamaan unuk proses pengofuidaan atet penuntnan yng telah
berlalru. [2,

narlal

{iii)

Describe a chemical test to verifu the displaced halogen in the reaction. Huraikon sata ujian kimia unt* mengesahkan halogen y(mg tersesar dalom tindak balas ini. 13 marksT

45iln

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(b)

Table l0.l shows the result of two experiments to study the effect of metals M and N on the rusting of iron when coiled on iron nail. Jodual l0 .l fienunjukkan keputusan dua eksperimen untuk mengkaji kesan logam M dan N
ke atas pengaratan besi apabila dililitkan pada paku besi.

Experiment
Eksnerimen

0bservation
Pemerhatian

Experiment I Eloperimenl Blue spots formed in the Hot agar solution + potassium hexacyanoferrate (l l$ solution + phenolphthalein
agar
Tompok biru terbentuk dolam agar-sgar

larutan agar-cgar panas * kalium heksasianoferat {lllt. +

metal

fenolftalein

logamM Experiment
Eksperimen

ll

II

metal N lopamN

Hot agar solution + potassium hexacyanofurrate (l II) solution + phenolphthalein larutan agar-agar panas + kaliam helasasianoferat (lfl) + fenalftalein

Pink spots formed in the agar Tompak merch jambu

terbentuk dalam agar-

agar

Table

l0.l for Experiment I and II.

Il.
15 rnarksl

(i)

Explain why there is a difference in observations

Terangkan mengopa terdapal perbezaan dalam pemerhalian bagi Eksperimenl dan

(ii)

Arrange in ascending order of metals M, N and iron based on the electropositivity of the metals. Susunkan secara menaik bagi togam M,N dan besi berdosarkan sifat
ke e I e laropo si tifan I o gam
.

I (c)

markl

A student carried out an experiment to construct a Reactivity Series based on the reactivity of metal with oxygen. Table 10.2 shows the observation obtained by the student. Seorang pelajar telah menjalankan satu eh;perimen unluk membina sant Siri Kereaktifan berdasarlcan kzreakdan logam dengan gas oksigen. Jadual 10.? menunjr*kan pemerhatian yang diperolehi oleh pelajar in. [Lihat sebel.rh SULIT

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Metal Logam
lron
Besi

Obscrvaiion
Pemerhatian

Iron glows brightly and prducing a brown residue

Besi membara dengon lerang dan rnenghasilkan baki berwarna perang

T
U

glows dimly and producing a black residue Lopam T membars densan ,nalan and menshasilkon boki berwarna hitam Metal U burns brightly and producing a white residue Log.am U terbakor densan terang dan menshasilkan bad berwarna putih

MetalT

Table 10.2

(i)

Write a balanced chemical equation when iron reacts with oxygen to form iron (III) oxide.
Tuliskan persamaan kimia yang seimbang apabila besi bertfndsk balas dengan olrsigen untuk membentuk ferum(lll) aksido .
12

marks)

(ii)

Table l0.J shows the appararus and materials to investigate the reactiviry of metals with oxygen. Jadual 10.3 menunjukkan radas dan bahon untuk mengkaji kereaktifan logam dengan
oksigen.

Solid potassium manganate (VIl), glass wool oasbestos WW1 bunsen burner, retort stand and clamp,

boiling iube
Pepejal lcolium manganat (Yll),wul koca ,kerlas asbestos , penuna bunsen koki retot dan pengapit, tabwg didih

Table 10.3
Based on Table 10.3, draw a labelled diagram to investigate the rcactiviqv of any given metal with oxygen in the school laboratory. Berdassrkan Ja&al 10.3, tukiskan sebuah rajah berlabel untuk menkaji kereaktifan
mana-tnana logam yang cliberi dengan oksigen di dslam malonal selcolah

[2 marks]

(iii)

Arrange in ascending order of metals ircn, T and U based on their reactivity towards oxygen. Explain how you construct this Reactivity Series. Susunkan secora menoik logam besi ,T danU herdasarkcn kereaktifan logam
terse but terhadap oksigen.

Terangkan bagaimana anda membina Siri Kereahtifan tersebut.

{4

narksl

END OS'Q{TESTTON PAPER

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PERIODIC TABLE OF THE I,LEMENTS

t

Li
Lithftm
1

Be
Scrytliunt
9

rn{ I f,i*+*SYmbol
I X**-Name

,-//Proton

number
5

He
Helium

of element atomic mass

B
Borfi
t1 t3

c
Carban

N
Nitroger

o
0lryS.rt

r
Flucine

l0

Ne
Nsr
?0

l2
l4

l4

t6

l9
17

ll Na
Sodium 23

It

\Relative

It

Mg
t{agneriu
m 24 20

AI
Alurni*ir
m
71

l6

si
Silicrlrt

P
Pllorphtr

l8

s
Sulphur
32 14

CI
Chlorit*
19 35

Ar
Argss
40 36

2t

Itt 3t
33

l9

2l

+t

23

K
Forascium 39 37

Ca
CalcfuE
40 38

Se
Scadium
45
39

Ti
Tironium
48
,lO

v
Vaaadiu

24

25

Cr
Chronium
52 42

Mn
Mrnpnx
c

26

27

?8

29

30

3l

Fe
Iron
56 44

Co
Cobolt
59 45

Ni
Nicktl
59 rl6

Cn
Copn6
64 47

Zn
Zirr
65
4E

Gn
Callium
?0 !t9

Ge
Carmaniu
m
71

'J

As
Ar$nic
75

Se
Schnium
79

Br
Bromine 80

Kr
Krygon
84

$
JI

5t
43

dl

l\ (t.l

Rb
Rutridiun
E6

Sr
$rontium

Y
Ytlriufi
89
51

Zr
Zircolium 9t
al

Nb
NiSium

Mo
Molybdcn

't*hoeliu
m
18
15

Tc

Ru
Rutheniu m

50

5t

5l

5{

R}
Rhodium
103

Pd
Palladiurn
106
?E

Ag
Sihtr
103

cd
Cadr,rium

In
lndirm

Sn
il9
82

Sb
Aatiuony t22
83

Te
Tellutlunr

I
lnlim
121 g5

Xe
Xmon

tt

9] 1t

uo
96 11

t0l
76

il2
EO

il5
8l

llt

l2t
8rl

t3t
86

JJ

56

Cs
Caesiun
r33 87

Ba
Berium
137

La
Laathanu m r39

TIf
llaftrium t79
104

Ta
Tanlalun

w
Tung5len
184
IUO

77

Re
Rheniun
186

0s
Omium
r90
108

Ir
lridiun
192 109

79

Pt
Plailusr
195

Att
Qold
197

Hg
Mdisury
?01

TI
Ttalliut
3(X

Pb

l8t
t0J

Ld
207

Bi
Bismulh 249

Po
fulonium

At
Aststinc
210

Rn
Rador

2t0

JJ''

t8

t9

107

Fr
Fnncium 723

Ra
Radium
2:16

Ac
&tinitrm
221

unq
Unnilquadium
251

unp
Unnil-

Unh
Unnil-hcr

Uns
Umilsc.pi

Uno
Unnilo$i
um
265

Uue
Unnil6nni
um 7n6

pct{inlr
260

um
161

un
262

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1 SULIT: Chemistry 2 4541/2 (PP) Sub Mark 1 1 1 1 1 1 1 2ROH 2LiOH + H2 + H2 1 1 1 Total Total Mark 1 1 1 1 1 1 1

Question No 1 (a) (b) (c) (i) (ii) (d) (e) (f) (i) (ii) // 2Li + 2H2O 2.1 // 2,1 Group 17, Period 2 P // Ne // Neon

Mark Scheme

Octet electron arrangement // 8 valence electrons HOQ // HOF Q // F // Fluorine R // Li // Lithium 2R + 2H2O

1. Correct reactants and products 2. Balanced equation (g) P,Q , R

2 1 10

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Question No 2 (a) (b) (c) (d) (i) (ii)

Mark Scheme Chemical formula that shows the simplest whole number ratio of atoms of each element in a compound To remove all oxygen / air Black solid turns brown Mass of copper = 26.88 g Mass of oxygen = 6.72 g ( unit compulsory )

Sub Mark 1 1 1 1 1 1 1

Total Mark 1 1 1 1

1. Number of mole of Cu = 26.88 /64 // 0.42 Number of mole of O = 6.72 /16 // 0.42 2. Ratio Cu : O = 1 : 1

2 1

(iii) (iv)

CuO CuO + H2 Cu + H2O 1. Correct reactants and products 2. Balanced equation

1 1

(e)

Magnesium is more reactive than hydrogen // Hydrogen is less reactive than magnesium // Hydrogen is below magnesiumin the reactivity series

1 Total

1 10

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3 Sub Mark 1 1 1 Total Mark 1 1 1

Question No 3 (a) (i) (ii) (b) (c) (i) 2NH3 + H2SO4 Contact process Haber process Nitrogen // Hydrogen

Mark Scheme

(NH4)2SO4 1 1 1 1 1 2 2 1

1. Correct reactants and product 2. Balanced equation (ii) (iii) Fertilizer 1. 28 X 100 % 132

2. 21.21% (d) H Cl | | C=C | | H H (e) Use biodegradable polymer. [ Accept: Any other correct answer ]

1 Total

1 10

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4 Sub Mark 1 1 1 1 1 2 Total Mark 1 1 1

Question No 4 (a) (b) (i) (ii) (c) (i) HCl

Mark Scheme

No changes // blue litmus paper remain unchanged Consist of molecule // no hydrogen ion / H+ 1. Helps acid to ionizes / dissociate 2. Produce hydrogen ion / H+ // HCl H+ + Cl[ award pt 2 if write correct equation]

(ii)

2H+ + CO32- CO2 + H2O 1. Correct reactants and products 2. Balanced equation 1 1 1 1 1 2 2 1

(iii) (iv)

1. Effervescence // bubbles of gas 2. `Pop` sound Acid only shows its acidic properties when dissolve in water // H+/ hydrogen ions are responsible for acid to show their properties.

Total

10

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5 Sub Mark 1 1 1 1 2 1 Total Mark 1

Question No 5 (a) (b) C3H8O [ r : C3H7OH ]

Mark Scheme

1. No. of mole of carbon dioxide = 0.1 X 3 // 0.3 2. Volume of carbon dioxide = 0.3 x 24 dm3 // 7.2 dm3 // 7200 cm3

(c)

(i) (ii)

Compound that contain carbon and hydrogen only

water 1. Functional diagram 2. Label : water (d) (i) (ii) Oxidation Propanoic acid [ r : formula ] (e) (i) H O H H H | || | | | HC COCCCH | | | | H H H H 1 [ a: CH3COOC3H7 ] (ii) To increase rate of reaction // As a catalyst 1 Total 1 10 1 1 1 1 1 2 1 1

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Question No (a) 6 (b)

Mark Scheme m=2 n=2 Eye

Sub Mark 1 1

Total Mark 2

mixture

1. Functional diagram 2. Label : Eye , X mark, hydrochloric acid and sodium thiosulphate solution // solution // mixture (c) (d) Sulphur 1. Labelled axis with units : ( temperature /oC, time /s) 2. Suitable scale : (cover 50% of graph paper) 3. All point are plotted correctly 4. Correct shape and smooth curve The higher the temperature, the less the time taken for X mark to disappear from sight // the temperature is inversely proportional to time

1 1 1 1 1 1 1

2 1

(e)

1 Total

1 10

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7 Sub Mark 1 1 1 Total Mark 2 1

Question No 7 (a) 1. 2.8.2 // 2,8,2 2. Group 2 // 2 (b) (i) (ii)

Mark Scheme

P and Q // Q and R // Cl and Mg // Mg and O [ a: names of elements ] +2

P 1 1 1 1 1 1 1 1 2

1. label nucleus with dot or symbol and correct shells 2. octet electron arrangement and correct charges [ a: actual elements] (c) 1. Electron arrangement of C : 2.4 2. O : 2.6 3. Carbon atom contributes 4 electrons for sharing with two oxygen atom. 4. One oxygen atom contributes 2 electrons for sharing. 5. both achieve the octet electron arrangement
Ionic compound Solid High Conducts electricity in molten / aqueous Soluble in water// Insouble in organic solvent Sodium chloride // other ionic compound Physical properties Physical state at room conditions Melting/ boiling pt Electrical conductivity Solubility in water and organic solvent Example of compound Covalent compound solid, liquid, gaseous Low Does not conduct electricity in all state. Insoluble in water// Soluble in organic solvent Tetrachloromethane // other organic compound

Max. 5

(d)

1+1 1+1 1+ 1 1+1

1+1 Total

10 20

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8 Sub Mark 1 1 Total Mark 2

Question No 8 (a) (b) Electrode Ions that are attracted Ions that are selectively discharged Reason (i)

Mark Scheme Electrode Y : the position of ions in electrochemical series Electrode X : concentration of ions / solution/electrolyte

Y Cu2+ , H+ Copper(II) ion Cu is lower than H+ in the electrochemical series Cu2+ + 2e Cu

2+

X Cl- , OHChloride ion Concentration of Cl- higher 2ClCl2 + 2e 1+1 1+1 1+1 2+2

Half equations Observable changes of the solution

Blue solution becomes paler

10 (c) (i) (ii) W, X, Y, Cu 1. Cu 2. 1.3 V 3. Metal X is more electropositive than metal Cu 1. Positif terminal :Q 2. Negative terminal : Cu 3. Suitable metal for Q : silver 4. Suitable solution for R : silver nitrate solution [ a: name of substance ] Total 10 1 1 1 1 3 (ii) 1 1 1 1 4 1

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9 Sub Mark 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1+ 1 Max 10 Total 20 4 Total Mark 2

Question No 9 (a) (i) (ii)

Mark Scheme 1. P : Mg // Magnesium 2. Q: Zn // Zinc 1. The value of heat of displacement for Expt I is more than Expt II. 2. The distance between P / Cu is bigger/ further 3. than Q/Cu 4. in the electrochemical series. 1. mol of CuSO4 = 0.2 x 50 // 0.01 1000 2. Heat = 0.01 x 336000 J // 3.36 kJ // 3360 J 3. Change in temperature = 3360 50 X 4.2 = 16 oC

(b)

(c)

1. Appratus: Polystyrene cup , thermometer, [spatula] measuring cylinder ( suitable volume) 2. Procedure: 1. Measure 50cm3 of copper(II) sulphate solution 2. Pour into a polystyrene cup. 3. Measure the initial temperature, T1 4. Add a spatula of P // Q powder 5. Stir 6. Record the highest temperature, T2 3. Calculations: 1. T2 T1 = T oC 2. Mol of copper(II) sulphate solution = n mol // 0.2 x 50 // 0.01 1000 3. Heat = mc (T) // 50 x c x T J 4. Heat of displacement = - 50 x c x T J mol-1 0.01 [ negative symbol and correct unit compulsory]

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10

10 (a) (i) (ii)

P = chlorine // bromine Accept : formula Oxidation = 2I- I2 + 2e or Reduction = P2 + 2e 2PNote : P is Cl / Br 1.Correct formula of reactant and product 2.Balanced equation

1 1 1 1 1 6

(iii) 1. Add slowly // Add drop by drop // Add by using dropper 2. starch solution to the product in a test tube 3. dark blue colouration/solution is formed r: precipitate (b) (i) Exp 1 1.Presence of iron(II) ion 2.Metal M is less electropositive than iron // metal M located lower than iron in Electrochemical Series 3.When metal M in contact with iron nail, Iron rust Exp 2 4. No iron (II) ion // presence of hydroxide ion 5. Metal N is more electropositive than iron //metal N located above iron in Electrochemical Series 6.When metal N in contact with iron nail, iron do not rust

1 1 1 1 1 1 Max 5

(ii) (c) (i)

M,iron,N 4Fe + 3O2 2 Fe2O3 1. formula of reactant and product correct 2. Balanced equation

1 1 1

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11 (ii)

Glass wool Solid potassium manganate(VII)

Metal
powder

Asbestos paper heat heat 1 1 1 1 1 1 4 20 2

1. functional diagram,shading,and both heat 2. label (iii) 1.T,iron,U 2.U is more reactive than T and iron so U is located above iron and T in the Reactivity Series 3.iron is more reactive than T but less reactive than U so iron is located above T and below U in the Reactivity Series 4.T is less reactive than U and iron so T is located below U and iron in the Reactivity Series.

END OF MARKING SCHEME