Quimica 1°polimodal

UNIDAD 1
Qumica. Concepto. Ramas de la Qumica. Materia. Cuerpo y sustancia. Diferencia entre masa y
peso. Propiedades de la materia. Estados de la materia. Cambios de estado.
Sistemas materiales: Homogneos y heterogneos. Mtodos de separacin y fraccionamiento
de fases.
Soluciones. Formas de expresar concentraciones.
El estado gaseoso: Leyes de los gases.
Estado lquido: tensin superficial, viscosidad, capilaridad, difusin.
Estado slido: slidos amorfos y cristalinos. Sistemas de cristalizacin. Tipos de slidos
cristalinos.
QUMICA:
Ciencia que estudia la naturaleza de la materia, sus propiedades, las modificaciones que se
producen en su composicin y los cambios de energa que acompaan a las mismas.
Sus principales divisiones son: QUIMICA ORGANICA, QUIMICA INORGANICA, FISICOQUIMICA,
BIOQUIMICA.
MATERIA:
Es todo aquellos que nos rodea, ocupa un lugar en el espacio y es perceptible por nuestros
sentidos.
Podemos decir que todo objeto est constituido por materia. Todo lo que nos rodea en la
naturaleza es de naturaleza material. En general todo lo que podemos ver o tocar esta
CUERPO:
Es toda porcin limitada de materia; es un objeto material caracterizado por su forma.
SUSTANCIA:
Materia que tiene propiedades definidas y una composicin que no vara de una
SUST. COMPUESTAS: (o compuestos) estn formadas por dos o ms elementos, o sea 2 o

ms clases de tomos. Ej. H2O, NaCl, HNO3
SUST. SIMPLES: estn formadas por un solo tipo de elemento. Ej. O3, O2, H2, Cl2
ELEMENTO: no pueden descomponerse en sust. ms simples.
PROPIEDADES DE LA MATERIA
PROPIEDADES EXTENSIVAS: son aquellas que varan con la cantidad de materia

considerada
Ej. PESO, VOLMEN, LONGITUD, etc.
PROPIEDADES INTENSIVAS: son aquellas que NO varan con la cantidad de materia

considerada.
Ej. PUNTO DE FUSIN, PUNTO DE EBULLICION, DENSIDAD, SOLUBILIDA,
COLOR, OLOR, SABOR.
ESTADOS DE LA MATERIA: (estados de agregacin) la materia se presenta en 3 estados:
SOLIDO, LIQUIDO, GASEOSO.
SLIDO:
-For
-Prc
ma y volumen propio
ticamente incompresibles (espacio
intermolecular pequeo)
-Nivel sub microscpico: partculas ordenadas que forman un conjunto compacto
que no les permite trasladarse.
LQUIDO
-Volumen propio, adoptan la forma del recipiente que lo contiene
-Poco compresibles, la distancia entre partculas le permite moverse lo que le da la
posibilidad
de fluir
-A nivel sub microscpico sus partculas son ms ordenadas que el gas pero menos
que el slido
GASEOSO:
- No tienen forma ni volumen propio, ocupan todo el lugar disponible: se expanden
- Son compresibles debido al gran espacio entre molculas
- Es el estado mximo de desorden y sus partculas se mueven al azar.
CAMBIOS DE ESTADO: pasajes que experimenta la materia de un estado de agregacin a

otros, como consecuencia de absorcin o liberacin de calor. Puede lograrse mediante la
variacin de la temperatura, la presin o ambas a la vez. Estos cambios no producen
alteraciones en la composicin de la materia, son solo transformaciones fsicas.
LICUACION (O CONDENSACION)
G
S
SOLIDIFICACION
L
VAPORIZACION
FUSION
SUBLIMACION
SUBLIMACION INVERSA
(O CRISTALIZACION)
SISTEMAS MATERIALES
Es todo cuerpo o conjunto de cuerpos tomados como objeto de estudio. Porcin limitada del
universo tomada con el objetivo de observarla, estudiarla.
Se clasifican segn: Su interaccin con el medio que los rodea y segn las propiedades de la
materia que los forman.
--Segn su INTERACCION:
SIST. ABIERTOS: intercambia tanto MATERIA como ENERGIA con el medio. Ej: taza de t, vaso
de agua
SIST. CERRADOS: intercambian solo ENERGIA con el medio. Ej: olla cerrada, botella de
gaseosa cerrada
SIST. AISLADOS: NO intercambian NI MATERIA NI ENERGIA. Ej: Termo.
--Segn las PROPIEDADES de su materia:
SIST. HOMOGENEOS: son aquellos en los cuales sus propiedades intensivas no cambian a lo
largo de todo el sistema; es decir, cualquier porcin del sistema tiene los mismos valores de sus
propiedades intensivas que el resto. Ej: trozo de Au (oro), agua salada, gas de una garrafa, etc.
SIST. HETEROGENEOS: son aquellos cuyos valores de las propiedades intensivas varan segn
la porcin del sistema considerado. Ej: agua con hielo, agua con arena, etc.
Los sist. Heterogneos presentan superficies de discontinuidad bien definidas entre sus
componentes, cada una de estas partes que tienen iguales valores de las propiedades
intensivas constituye una FASE del mismo.
--FASE: cada porcin de un sist. Material con iguales valores de sus propiedades
intensivas.
De esto podemos afirmar que todo sist. HOMEGENEO es MONOFASICO mientras que
un sist. HETEROGENEOS (con 2 o mas fases) es POLIFASICO.
Los criterios anteriormente presentados surgen a partir de una observacin a simple
vista, mas si a algunas soluciones las observamos al microscopio veremos que en
realidad presentan fases, como por ejemplo la leche, la sangre, la tinta china. Por
esto se ha tomado como convencin para determinar si un sist. Es homogneo o
heterogneo segn la observacin, al lmite del tamao de las partculas.
Asi:
---si la mayor partcula del sistema es MENOR a 1 nm (1 nanometro) el sistema es
considerado HOMOGENEO
---si la mayor partcula del sistema es MAYOR O IGUAL a 1nm el sistema es
considerado HETEROGENEO
SISTEMA
ELEMENTOS
COMPUESTAS
SIMPLES
SOLUCIONES HOMOGENEO
SUSTANCIAS
HETEROGENEO
FASES
METOS DE SEPARACION DE FASES

Al realizar actividades industriales, domsticas, agrarias, de investigacin, y otras,
frecuentemente nos vemos en la necesidad de separar las fases de sistemas heterogneos.
Existen diferentes mtodos para separar las fases de un sistema heterogneo. Estos
mtodos se basan en las propiedades fsicas de las fases del sistema, como por ejemplo la
densidad, el diferente tamao de los grnulos en sistemas slidos, propiedades magnticas,
volatilidad, etc.
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1
Tamizacin
Aplicacin
Se aplica a sistemas formados por dos fases slidas granuladas, donde los grnulos de una fase
tienen diferente tamao que los grnulos de la otra fase.
Ejemplo
Sistema formado por arena y pedregullo.
Materiales necesarios
Tamiz, criba o cernidor.
dhgt251677696fLayoutInCell1fBehindDocument1fIsButton1fHidden0fLayoutInCell1
Fundamento
Los orificios del tamiz son suficientemente grandes para dejar pasar a travs de ellos los
grnulos de la fase slida pulverizada, pero son lo suficientemente pequeos para retener los
grnulos de mayor tamao de la otra fase.
Decantacin
Aplicacin
Se aplica a sistemas formados por dos fases lquidas (no miscibles).
Ejemplo
Sistema formado por agua y aceite.
Ampolla de decantacin, vaso de precipitado, soporte.
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Fundamento
La ampolla de decantacin est diseada para que el sistema colocado en ella permanezca en
reposo, permitiendo as la separacin de las fases lquidas. La fase de mayor densidad, queda
en el fondo y al abrir la llave de paso saldr primero. La llave deber cerrarse cuando se llegue
al lmite inter fsico.
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Sedimentacin
Aplicacin
Se aplica a sistemas formados por una fase slida pulverizada que se encuentra en suspensin
en una fase lquida.
Ejemplo
Sistema formado por talco y agua
Cualquier recipiente, por ejemplo un vaso de precipitado.
Fundamento
La fase slida finamente dividida al ser ms densa que la
fase lquida, se ir depositando en el fondo del recipiente
debido a la fuerza de atraccin gravitatoria.

El mtodo es lento y poco preciso: para lograr la separacin de las fases, hay que inclinar el
recipiente y trasvasar la fase lquida superior, intentando que la fase slida no caiga.
pWrapPolygonVertices8;5;(-133,0);(-133,21513);(21600,21513);(21600,0);(133,0)dhgt251672576fLayoutInCell1fAllowOverlap1fBehindDocument1fIsButton1fHidden0fLayo
utInCell1
Filtracin
Aplicacin
Se aplica a sistemas similares a los descritos en el mtodo anterior; es decir, con una fase
slida pulverizada en suspensin en una fase lquida.
Ejemplo
Sistema formado por azufre y agua.
Papel de filtro (u otro material poroso: algodn, tela, cermica, vidrio sinterizado), soporte,
embudo, vaso de precipitado y varilla de
vidrio.
pWrapPolygonVertices8;5;(98,0);(-98,21468);
(21600,21468);(21600,0);(98,0)dhgt251671552fLayoutIn
Cell1fAllowOverlap1fBehindDo
cument0fIsButton1fHidden0fL
ayoutInCell1
Fundamento
El material poroso permite que la fase lquida pase a travs de los poros pero retiene a la fase
slida aunque est finamente pulverizada.
dhgt251681792fLayoutInCell1fBehindDocument1fIsButton1fHidden0fLayoutInCell1
Centrifugacin
Aplicacin
Se aplica sistemas formados por una fase lquida y una fase slida en suspensin.
Ejemplo
Sistema formado por talco y agua.
Centrfuga, tubos de centrfuga.
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Fundamento
Este mtodo utiliza una centrfuga que acelera el proceso sedimentacin. Mediante el
movimiento de rotacin, la fase slida, de mayor densidad, se deposita en el fondo del tubo de
centrfuga, quedando compactada y eficazmente separada de la fase lquida.

Luego se inclina el tubo y se transvasa el lquido a otro recipiente. Este mtodo se basa en el
concepto de fuerza centrfuga.
Imantacin
Aplicacin
Se aplica a sistemas formados por dos fases slidas, donde una de ellas tiene propiedades
magnticas.
Ejemplo
Sistema formado por arena y limaduras de hierro.
Imn y un recipiente.
Fundamento
Se logra separar fcilmente ambas fases utilizando un imn, porque una de las fases tiene la
propiedad de ser atrada por l y la otra no.
pWrapPolygonVertices8;5;(-54,0);(-54,21456);(21600,21456);(21600,0);(54,0)dhgt251673600fLayoutInCell1fAllowOverlap1fBehindDocument0fIsButton1fHidden0fLayout
InCell1
Otros mtodos de separacin de fases

Con el sistema formado por yodo slido y arena es posible analizar dos mtodos ms para
separar sus fases.
pWrapPolygonVertices8;5;(-104,0);(-104,21462);(21600,21462);(21600,0);(104,0)dhgt251683840fLayoutInCell1fBehindDocument0fIsButton1fHidden0fLayoutInCell
1
Sublimacin
Este mtodo se fundamenta en la propiedad del yodo de
sublimar (pasar del
estado slido al estado gaseoso). El yodo en forma de vapor, al
encontrar una
superficie a menor temperatura, se deposita en la forma de
pequeos cristales.
La arena queda en el fondo del recipiente
dhgt251685888fLayoutInCell1fIsButton1fHidden0fLayoutInCell1
Disolucin selectiva
Este mtodo se aplica para separar sistemas formados por dos
slidos con diferente solubilidad en un lquido determinado.

Por ejemplo el sistema yodo-arena.
En este caso, podemos aprovechar que el yodo tiene la propiedad de ser soluble en alcohol
(etanol) y la arena no. Entonces al agregar alcohol al sistema, el yodo queda disuelto en l y la
arena se deposita en el fondo del recipiente.
Luego, mediante filtracin, se separa la arena de la fase lquida (yodo disuelto en alcohol) y por
ltimo se evapora el alcohol y se recupera el yodo.
Aclaracin: No se confundirse, el lquido que se agrega para hacer la disolucin no forma
parte del sistema original, es un "medio" que utilizamos para separar las fases del sistema
disolvindolas selectivamente. El lquido agregado se evapora al final para recuperar la fase
slida que se disolvi en l.
MTODOS DE FRACCIONAMIENTO
Estos mtodos tienen como objetivo recuperar las diferentes fracciones o componentes de
una solucin: el solvente y los solutos.
Muchas veces no es posible realizar la recuperacin total de los componentes usando solo un
mtodo y en ese caso, se combinan varios de ellos.
Analizaremos algunos mtodos de fraccionamiento: cristalizacin, destilacin
y cromatografa.
sta es una introduccin terica, los detalles del procedimiento experimental a seguir para
aplicar cada uno de los mtodos se encuentran en la
Cristalizacin
Cristalizador, tubo de ensayo, pinza de madera, mechero, gradilla.
Sistema: lquido celeste (solucin acuosa de sulfato cprico).
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5a73634a7b6b5a6b63526
Secuencia del proceso de cristalizacin.
Fundamento
El mtodo consiste en extraer el solvente quedando en forma slida el componente que estaba
disuelto.
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10101010
Aplicaciones
En muchos casos la naturaleza se encarga de realizar este proceso mediante la energa solar,
como en las salinas, donde se obtienen cristales de cloruro de sodio al evaporarse el agua.
Cromatografa (sobre papel)
Tiras de papel absorbente, marcadores de fibra, recipiente de vidrio, agua o alcohol.
Sistema: tinta de marcador de fibra.

Fundamento
La cromatografa se basa en las diferentes afinidades de los componentes de una solucin por
el papel (soporte fijo) o por un lquido absorbido por ste (agua, alcohol u otro).
A medida que el lquido asciende por el papel, "arrastra" aquellos componentes ms solubles en
l, dejndolos a mayor distancia de la muestra inicial. Aquellos componentes menos solubles en
el lquido quedan ms cerca de la muestra.
Destilacin
Matraz, tapn perforado con tubo de desprendimiento, tubo refrigerante, soporte universal con
pinza y aro, mechero, termmetro, 2 vasos de bohemia.
Sistema: vino tinto.
Fundamento
El mtodo se basa en los diferentes puntos de ebullicin de los componentes de la solucin. De
esta manera se pueden extraer los componentes condensando sus vapores y recogindolos por
separado.

Quimica 1°polimodal

Diunggah oleh

Informasi Dokumen

Judul Asli

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Quimica 1°polimodal

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UNIDAD 1

SUST. COMPUESTAS: (o compuestos) estn formadas por dos o ms elementos, o sea 2 o

PROPIEDADES EXTENSIVAS: son aquellas que varan con la cantidad de materia

PROPIEDADES INTENSIVAS: son aquellas que NO varan con la cantidad de materia

CAMBIOS DE ESTADO: pasajes que experimenta la materia de un estado de agregacin a

METOS DE SEPARACION DE FASES

debido a la fuerza de atraccin gravitatoria.

centrfuga, quedando compactada y eficazmente separada de la fase lquida.

Otros mtodos de separacin de fases

slidos con diferente solubilidad en un lquido determinado.

Cromatografa (sobre papel)

Sistema: tinta de marcador de fibra.

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