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Epitaxy - Wikipedia, the f ree ency clopedia

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Epitaxy refers to the deposition of a crystalline overlayer on a crystalline substrate, where the overlayer is in registry with the substrate. In other words, there must be one or more preferred orientations of the overlayer with respect to the substrate for this to be termed epitaxial growth. The overlayer is called an epitaxial film or epitaxial layer. The term epitaxy comes from the Greek roots epi, meaning "above", and taxis, meaning "in ordered manner". It can be translated "to arrange upon". For most technological applications, it is desired that the deposited material form a crystalline overlayer that has one well-defined orientation with respect to the substrate crystal structure (single-domain epitaxy). Epitaxial films may be grown from gaseous or liquid precursors. Because the substrate acts as a seed crystal, the deposited film may lock into one or more crystallographic orientations with respect to the substrate crystal. If the overlayer either forms a random orientation with respect to the substrate or does not form an ordered overlayer, this is termed non-epitaxial growth. If an epitaxial film is deposited on a substrate of the same composition, the process is called homoepitaxy; otherwise it is called heteroepitaxy. Homoepitaxy is a kind of epitaxy performed with only one material. In homoepitaxy, a crystalline film is grown on a substrate or film of the same material. This technology is used to grow a film which is more pure than the substrate and to fabricate layers having different doping levels. In academic literature, homoepitaxy is often abbreviated to "homoepi". Heteroepitaxy is a kind of epitaxy performed with materials that are different from each other. In heteroepitaxy, a crystalline film grows on a crystalline substrate or film of a different material. This technology is often used to grow crystalline films of materials for which crystals cannot otherwise be obtained and to fabricate integrated crystalline layers of different materials. Examples include gallium nitride (GaN) on sapphire, aluminium gallium indium phosphide (AlGaInP) on gallium arsenide (GaAs) or diamond or iridium.[1] Heterotopotaxy is a process similar to heteroepitaxy except for the fact that thin film growth is not limited to two dimensional growth. Here the substrate is similar only in structure to the thin film material. Epitaxy is used in silicon-based manufacturing processes for BJTs and modern CMOS, but it is particularly important for compound semiconductors such as gallium arsenide. Manufacturing issues include control of the amount and uniformity of the deposition's resistivity and thickness, the cleanliness and purity of the surface and the chamber atmosphere, the prevention of the typically much more highly doped substrate wafer's diffusion of dopant to the new layers, imperfections of the growth process, and protecting the surfaces during the manufacture and handling.

1 Applications 2 Methods 2.1 Vapor-phase 2.2 Liquid-phase 2.3 Solid-phase 1/6


Epitaxy - Wikipedia, the f ree ency clopedia

3 Molecular-beam 4 Doping 5 Epitaxy in minerals 5.1 Epitaxy in isomorphic minerals 5.2 Epitaxy in polymorphic minerals 5.3 Rutile on hematite 5.4 Hematite on magnetite 6 See also 7 References 8 External links

Epitaxy is used in nanotechnology and in semiconductor fabrication. Indeed, epitaxy is the only affordable method of high quality crystal growth for many semiconductor materials.

Epitaxial silicon is usually grown using vapor-phase epitaxy (VPE), a modification of chemical vapor deposition. Molecular-beam and liquid-phase epitaxy (MBE and LPE) are also used, mainly for compound semiconductors. Solid-phase epitaxy is used primarily for crystal-damage healing.

Silicon is most commonly deposited by dosing with silicon tetrachloride and hydrogen at approximately 1200 C: SiCl4(g) + 2H2(g) Si(s) + 4HCl(g) This reaction is reversible, and the growth rate depends strongly upon the proportion of the two source gases. Growth rates above 2 micrometres per minute produce polycrystalline silicon, and negative growth rates (etching) may occur if too much hydrogen chloride byproduct is present. (In fact, hydrogen chloride may be added intentionally to etch the wafer.) An additional etching reaction competes with the deposition reaction: SiCl4(g) + Si(s) 2SiCl2(g) Silicon VPE may also use silane, dichlorosilane, and trichlorosilane source gases. For instance, the silane reaction occurs at 650 C in this way: SiH4 Si + 2H2 This reaction does not inadvertently etch the wafer, and takes place at lower temperatures than deposition from silicon tetrachloride. However, it will form a polycrystalline film unless tightly controlled, and it allows oxidizing species that leak into the reactor to contaminate the epitaxial layer with unwanted compounds such as silicon dioxide.



Epitaxy - Wikipedia, the f ree ency clopedia

VPE is sometimes classified by the chemistry of the source gases, such as hydride VPE and metalorganic VPE.

Liquid phase epitaxy (LPE) is a method to grow semiconductor crystal layers from the melt on solid substrates. Bitdefender Internet Security 2012 This happens at temperatures well below the melting point of the deposited semiconductor. The semiconductor is dissolved in the melt of another material. At conditions that are close to the equilibrium between dissolution and deposition, the deposition of the semiconductor crystal on the substrate is relatively fast and uniform. Mostly used substrate is indium phosphide (InP). Other substrates like glass or ceramic can be applied for special applications. To facilitate nucleation, and to avoid tension in the grown layer the thermal expansion coefficient of substrate and grown layer should be similar.

Solid Phase Epitaxy (SPE) is a transition between the amorphous and crystalline phases of a material. It is usually done by first depositing a film of amorphous material on a crystalline substrate. The substrate is then heated to crystallize the film. The single crystal substrate serves as a template for crystal growth. The annealing step used to recrystallize or heal silicon layers amorphized during ion implantation is also considered one type of Solid Phase Epitaxy. The Impurity segregation and redistribution at the growing crystal-amorphus layer interface during this process is used to incorporate low-solubility dopants in metals and Silicon.[2]

Main article: Molecular-beam epitaxy In MBE, a source material is heated to produce an evaporated beam of particles. These particles travel through a very high vacuum (108 Pa; practically free space) to the substrate, where they condense. MBE has lower throughput than other forms of epitaxy. This technique is widely used for growing III-V semiconductor crystals.[3][4]

An epitaxial layer can be doped during deposition by adding impurities to the source gas, such as arsine, phosphine or diborane. The concentration of impurity in the gas phase determines its concentration in the deposited film. As in CVD, impurities change the deposition rate. Additionally, the high temperatures at which CVD is performed may allow dopants to diffuse into the growing layer from other layers in the wafer ("out-diffusion"). Also, dopants in the source gas, liberated by evaporation or wet etching of the surface, may diffuse into the epitaxial layer ("autodoping"). The dopant profiles of underlying layers change as well, however not as significantly.

Epitaxy in minerals
In mineralogy epitaxy is the overgrowth of one mineral on another in an orderly way, such that certain crystal directions of the two minerals are aligned. This occurs when some planes in the lattices of the overgrowth and the substrate have similar spacings between atoms.[5] If the crystals of both minerals are well formed so that the directions of the crystallographic axes are clear then the epitaxic relationship can be deduced just by a visual inspection.[5] 3/6


Epitaxy - Wikipedia, the f ree ency clopedia

Sometimes many separate crystals form the overgrowth on a single substrate, and then if there is epitaxy all the overgrowth crystals will have a similar orientation. The reverse, however, is not necessarily true. If the overgrowth crystals have a similar orientation there is probably an epitaxic relationship, but it is not certain.[5] Some authors[6] consider that overgrowths of a second generation of the same mineral species should also be considered as epitaxy, and this is common terminology for semiconductor scientists who induce epitaxic growth of a film with a different doping level on a semiconductor substrate of the same material. For naturally produced minerals, however, the International Mineralogical Association (IMA) definition requires that the two minerals be of different species.[7] Another man-made application of epitaxy is the making of artificial snow using silver iodide, which is possible because hexagonal silver iodide and ice have similar cell dimensions.[6]

Epitaxy in isomorphic minerals

It is easy to understand that minerals that have the same structure (isomorphic minerals) may have epitaxic relations. An example is albite NaAlSi3O8 on microcline KAlSi3O8. Both these minerals are triclinic, with space group 1, and with similar unit cell parameters, a = 8.16 , b = 12.87 , c = 7.11 , = 93.45, = 116.4, = 90.28 for albite and a = 8.5784 , b = 12.96 , c = 7.2112 , = 90.3, = 116.05, = 89 for microcline.

Epitaxy in polymorphic minerals

Minerals that have the same composition but different structures (polymorphic minerals) may also have epitaxic relations. Examples are pyrite and marcasite, both FeS2, and sphalerite and wurtzite, both ZnS.[5]

Rutile epitaxic on hematite nearly 6 cm long. Bahia, Brazil

Rutile on hematite
Some pairs of minerals that are not related structurally or compositionally may also exhibit epitaxy. A common example is rutile TiO2 on hematite Fe2O3.[5][8] Rutile is tetragonal and hematite is trigonal, but there are directions of similar spacing between the atoms in the (100) plane of rutile (perpendicular to the an axis) and the (001) plane of hematite (perpendicular to the c axis). In epitaxy these directions tend to line up with each other, resulting in the a axis of the rutile overgrowth being parallel to the c axis of hematite, and the c axis of rutile being parallel to one of the an axes of hematite.[5]

Hematite pseudomorph after magnetite, with terraced epitaxic faces. La Rioja, Argentina

Hematite on magnetite 4/6


Epitaxy - Wikipedia, the f ree ency clopedia

Another example is hematite Fe3+2O3 on magnetite Fe2+Fe3+2O4. The magnetite structure is based on cubic close packed oxygen anions. In this packing the close-packed layers are parallel to (111) (a plane that symmetrically "cuts off" a corner of a cube). The hematite structure is based on hexagonal close-packed oxygen anions and in this packing the close-packed layers are parallel to (001) (a plane parallel to a face of a cube).[9] If the cations were small enough to fit into a truly close-packed structure of oxygen anions then the spacing between the nearest neighbour oxygen sites would be the same for both species. The radius of the oxygen ion, however, is only 1.36 [10] and the Fe cations are big enough to cause some variations. The Fe radii vary from 0.49 to 0.92 ,[11] depending on the charge (2+ or 3+) and the coordination number (4 or 8). Nevertheless the O spacings are similar for the two minerals hence hematite can readily grow on the (111) faces of magnetite, with hematite (001) parallel to magnetite (111).[9]

See also
Island growth Atomic layer epitaxy Topotaxy Epiwafer Exchange bias Heterojunction Nano-RAM Quantum cascade laser Selective area epitaxy Silicon on sapphire Single event upset VCSEL Wake Shield Facility Zhores Ivanovich Alferov

1. ^ M. Schreck et al., Appl. Phys. Lett. 78, 192 (2001); doi:10.1063/1.1337648 ( 2. ^ A. Polman et al., J. Appl. Phys., Vol. 75, No. 6, 15 March 1994 3. ^ A. Y. Cho, "Growth of III\V semiconductors by molecular beam epitaxy and their properties," Thin Solid Films, vol. 100, pp. 291-317, 1983. 4. ^ Cheng, K.-Y., "Molecular beam epitaxy technology of III-V compound semiconductors for optoelectronic applications," Proceedings of the IEEE , vol.85, no.11, pp.1694-1714, Nov 1997 URL: 5. ^ a b c d e f Rakovan, John (2006) Rocks & Minerals 81:317 to 320 6. ^ a b White and Richards (2010) Rocks & Minerals 85:173 to 176 7. ^ Acta Crystallographica Section A Crystal Physics, Diffraction, Theoretical and General Crystallography Volume 33, Part 4 (July 1977) 8. ^ 9. ^ a b Nesse, William (2000). Introduction to Mineralogy. Oxford University Press. Page 79 10. ^ Klein and Hurlbut (1993) Manual of Mineralogy 21st Edition. Wiley 5/6


Epitaxy - Wikipedia, the f ree ency clopedia

11. ^ Imperial College Database

Jaeger, Richard C. (2002). "Film Deposition". Introduction to Microelectronic Fabrication (2nd ed.). Upper Saddle River: Prentice Hall. ISBN 0-201-44494-1.

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