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  • Oxi Rancid

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    zhaw_13
    289 tayangan22 halaman
    Rancidity is the decomposition of fats, oils and other lipids are three types. Free radicals break down double bonds in unsaturated fats through the free radical process. Many synthetic anti-oxidants can be distinguished from their natural counterparts by their molecular structure.

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    Rancidity is the decomposition of fats, oils and other lipids are three types. Free radicals break down double bonds in unsaturated fats through the free radical process. Many synthetic anti-oxidants can be distinguished from their natural counterparts by their molecular structure.

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    289 tayangan22 halaman

    Oxi Rancid

    Diunggah oleh

    zhaw_13
    Rancidity is the decomposition of fats, oils and other lipids are three types. Free radicals break down double bonds in unsaturated fats through the free radical process. Many synthetic anti-oxidants can be distinguished from their natural counterparts by their molecular structure.

    Hak Cipta:

    Attribution Non-Commercial (BY-NC)
    Unduh sebagai PDF, TXT atau baca online dari Scribd
    Tandai sebagai konten tidak pantas
    dari 22

    OXIDATIVE RANCIDITY

    Bryan Giger Howard Chua Alison Alcaraz

    Wednesday, December 12, 12

    DEFINITION
    What

    is Rancidity?

    Causes Undesirable odors and taste in food Is the decomposition of fats, oils and other lipids are three types - water splits fatty acids

    There

    Hydrolytic Microbial Oxidative

    - Microorganisms break down food - Oxygen breaks down unsaturated fatty acids

    Wednesday, December 12, 12

    OXIDATIVE RANCIDITY
    Oxygen

    breaks down double bonds in unsaturated fats through the free radical process
    Three

    stages:

    Initiation Propagation Termination

    Wednesday, December 12, 12

    INITIATION
    Formation RH

    of free radicals

    -> R + H

    Conditions: Light

    (sunlight) (Metal)

    Catalyst

    Wednesday, December 12, 12

    PROPAGATION
    Free-Radical R

    chain reactions

    + O2 + -> ROO + RH -> R + ROOH

    ROO As

    these reactions happen, peroxide radicals are formed and these in turn react with more unsaturated fatty acids, keeping the reaction continuous

    Wednesday, December 12, 12

    TERMINATION

    Free R R

    Radicals combine into non-radical products

    + R -> RR + ROO -> ROOR + ROO -> ROOR + O2

    ROO

    Wednesday, December 12, 12

    Wednesday, December 12, 12

    SYNTHETIC ANTIOXIDANTS
    Many

    synthetic anti-oxidants can be distinguished from their natural counterparts by their molecular structure
    They

    are usually phenols with a hydroxyl group attached to a benzene ring group is the tertiary butyl group which has three methyl groups bound to one carbon

    Another

    Wednesday, December 12, 12

    ANTI-OXIDANTS

    3 Types: 1. Free

    Radical Inhibitors (Scavengers) (Chelating Agents)

    2. Complexing Agents 3. Reducing Agents

    Wednesday, December 12, 12

    FREE RADICAL INHIBITORS


    Contain Either: interrupt

    a Phenolic or Tert-Butyl group

    the formation of free radicals in the initiation step of auto-oxidation the propagation of the chain

    interrupt

    They mop-up radicals

    by forming less stable and less reactive radicals or form non-radical products

    Wednesday, December 12, 12

    FREE RADICAL INHIBITORS


    R

    + AH -> R-H + A + AH - R-O-H + A + AH -> R-O-O-H + A

    RO

    ROO R

    + A -> R-A + A -> R-O-A

    RO

    Wednesday, December 12, 12

    FREE RADICAL INHIBITORS

    Simplied Examples: Vitamin

    by the formula AH

    E (Tocopherols) TBHQ

    BHA, BHT,

    Wednesday, December 12, 12

    BHA (BUTYLATED HYDROXYANISOLE)

    Molecular Oxygen

    Formula: C11H16O2

    Reacts more favorably with BHA or BHT so it acts as a getter and thus preserving food

    Wednesday, December 12, 12

    BHT (BUTYLATED HYDROXYTOULENE)

    Molecular Behaves Is

    Formula: C15H24O

    as a synthetic version of Vitamin E

    a Terminating agent

    Wednesday, December 12, 12

    Wednesday, December 12, 12

    Wednesday, December 12, 12

    COMPLEXING AGENTS
    Removes Transition Acts

    metals (Catalysts)

    like a getter for Transition metals an irreversible complex with metal ions like iron(II) ion Fe2+

    Forms

    This

    complexing is known as chelating (forming Ligands on metals)

    Wednesday, December 12, 12

    (ethylenediaminetetraacetic acid)

    4EDTA

    Wednesday, December 12, 12

    REDUCING AGENTS

    Act Can

    just like a reducing agent in a ReDox Reaction

    react with both oxygen and hydroperoxides produced in the auto-oxidation reaction
    Are

    electron donors that are ably to remove or reduce the concentrations of oxygen

    Wednesday, December 12, 12

    REDUCING AGENTS

    Examples: Vitamin

    Carotenoids -Carotene

    Wednesday, December 12, 12

    VITAMIN C (ASCORBIC ACID)

    Half

    Equation of Vitamin C

    Wednesday, December 12, 12

    RESOURCES/FURTHER READING

    http://www.foodcanmakeyouill.co.uk/library/content/

    Antioxidants.pdf

    Wednesday, December 12, 12

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