General ................................................................................................... 3 Commitment............................................................................................4 More Information and Guidelines ................................................................4 Abbreviations and definitions in this document .............................................5 Part 1: Apparel/Accessories/Footwear/Interior Products ...................... 6 Textile (Natural & Synthetic), incl. pigment print ..........................................6 Leather ...................................................................................................8 Plastic, Rubber, Paint & Surface coating ......................................................9 Metal .................................................................................................... 11 Paper & Wood ........................................................................................ 11 Fusing, Padding, Feather & Down ............................................................. 12 Glass & Crystal....................................................................................... 12 Additional Requirements all Material....................................................... 13 Recycled Material ................................................................................... 13 Part 2: Food Contact Products ............................................................... 14 Requirements - all Food Contact Material................................................... 14 Ceramic & Glass ..................................................................................... 14 Metal .................................................................................................... 15 Paper & Board........................................................................................ 15 Plastic ................................................................................................... 16 Wood .................................................................................................... 18 Part 3: Cosmetic Products ..................................................................... 19 Cosmetic Products .................................................................................. 19 Additional Requirements.......................................................................... 23 Part 4: Toys........................................................................................... 24 Additional Requirements.......................................................................... 24 Part 5: Electrical and Electronic Products .............................................. 25 Additional Requirements.......................................................................... 25 Part 6: Packaging .................................................................................. 26 Glass .................................................................................................... 26 Metal .................................................................................................... 26 Paper & Wood ........................................................................................ 26 Plastic, Rubber, Paint & Surface coating .................................................... 27 Additional Requirements all Material....................................................... 28 Part 7: Restricted Substances in Production.......................................... 29 Appendix A - Restricted Substances and CAS no. .................................. 30 A.1. Apparel/Accessories/Footwear/Interior ............................................... 30 A.2. Food Contact Products...................................................................... 35 A.3. Cosmetic Products ........................................................................... 36 A.6. Packaging ....................................................................................... 38 A.7. Restricted Substances in Production ................................................... 40 Appendix B - Test Methods .................................................................... 41 B.1. Apparel/Accessories/Footwear/Interior ............................................... 41 B.2. Food Contact Products...................................................................... 44 Appendix C Permitted Colorants in Cosmetic Products ....................... 46 Substance/Requirement Index ............................................................. 49
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General
H&M has with concern for the health of customers as well as for the environment and working conditions, established Chemical Restrictions for all H&M products. H&M Part Part Part Part Part Part Part Chemical Restrictions consist of seven parts: 1: Apparel/Accessories/Footwear/Interior Products 2: Food Contact Products 3: Cosmetic Products 4: Toys 5: Electrical and Electronic Products 6: Packaging 7: Restricted Substances in Production
The Apparel/Accessories/Footwear/Interior Products and Food Contact Products are divided into materials. The restrictions in Part 1 also applies to Part 2, 4 and 5 products. If the product is sold in a packaging, it must also comply with part 6. All products must comply with Part 7. Each limit in H&M Chemical Restrictions is valid for homogeneous parts of the concerned product. Individual restricted substances with CAS no are specified in Appendix A. Test methods are found in Appendix B. All details on your product must comply with H&M Chemical Restrictions, see example below for a padded jacket, a water bottle and a lip gloss. The examples do not claim to be complete.
Apparel/Accessories/Footwear/Interior Products
Fabric & lining: Follow Textile restrictions in Part 1 Painted zipper & press buttons: Follow Metal restrictions in Part 1 for the metal. Follow the Plastic, Rubber, Paints & Surface coating restrictions in Part 1 for the paint. Drawstring, stoppers & possible placement print: Follow Plastic, Rubber, Paints & Surface coating restrictions in Part 1 Padding: Follow Fusing, Padding, Feather and Down restrictions in Part 1
Cosmetic Products
Lip gloss: Follow restrictions for cosmetic products in Part 3. Lid and bottle: Follow restrictions for packaging in Part 6.
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Commitment
When signing H&M Standard Purchase Conditions Compliance Commitment, the H&M supplier commits to comply with H&M Chemical Restrictions. It is the suppliers responsibility to inform all their downstream suppliers and subcontractors about the content of the restrictions and to assure compliance. By signing H&M Standard Purchase Conditions Compliance Commitment, each supplier acknowledges that H&M reserves the right to: Check any product, any part of production and/or packaging, by any listed/appropriate method, at any time or stage of production. Cancel the ordered product or, if already delivered, return the goods if the product, production and/or packaging do not correspond to the restrictions. Hold the manufacturer/exporter responsible for any damage caused by the ordered product if the product, production and/or packaging do not correspond to the restrictions. Receive the complete product information and Material Safety Data Sheets (MSDS) about all products (dyes, colorants, solvents, chemicals etc.) included in the production of a specific order and/or batch. In the case of contradictory test result, H&Ms test result will prevail.
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CI no cl cSt GMP Homogeneous IU Kinematic viscosity Organoleptic ppm REACH Reporting limit SML SML(T)
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Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) Cationic Surfactants* Chlorinated Aromatic Hydrocarbons* Chloroparaffins Short chained (SCCPs) C10-C13 Medium chained (MCCPs) C14-C17 Chromium VI (Cr6+) Dyes Azo Dyes & Pigments* Disperse Dyes* Other Dyes* Flame Retardants*1 Formaldehyde
Products for children aged 0-3 years, incl. bed linen (e.g. 50-98 cl) Products for children above 3 years (e.g. 104-170 cl) and products for adults with direct skin contact, incl. bed linen Products for adults without direct skin contact (e.g. outer wear, curtains)
100 ppm 100 ppm Not detected Not detected Not detected, sum of listed surfactants 2 ppm, per listed substance group
20 ppm, per listed amine 1 mg/l extract, per listed disperse dye Not detected, per listed other dye Not detected
Supplier must always get an approval from H&M before using any flame retardant, even if it is not listed in Appendix A.1. No flame retardants are allowed on babies and childrens products. Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test method.
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Restricted substance Metals, Extractable Amount Antimony (Sb) Arsenic (As) Chromium (Cr) Cobalt (Co) Copper (Cu) Lead (Pb) Mercury (Hg) Nickel (Ni) Metals, Total Amount Antimony (Sb) Arsenic (As) Cadmium (Cd) Chromium (Cr) Lead (Pb) Mercury (Hg) Octamethylcyclotetrasiloxane Organotin Compounds* Dibutyltin (DBT) Dioctyltin (DOT) Sum of other listed organotins Sum of other not listed tri-substituted organotins Perfluoro Compounds Perfluorooctane Sulfonate (PFOS) and PFOS related substances Perfluorooctanoic Acid (PFOA) Pesticides* Dieldrine Sum of listed pesticides pH Phenols Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) Phthalates*
Limit
30 ppm3 0.2 ppm 1 ppm4 1 ppm 25 ppm5 0.2 ppm 0.02 ppm 1 ppm
260 ppm3 1 ppm 1 ppm 100 ppm4 90 ppm 0.5 ppm 1000 ppm
1 g/m2 1 g/m2
Not detected Not detected 50 ppm 500 ppm, per phthalate. The sum of phthalates 1000 ppm
For 100% polyester the total Sb limit applies (for 50% polyester the limit is 130 ppm etc.). For all other textile materials the extractable Sb limit applies.
For polyamide, polyamide blends (min 5% PA) and worsted wool the extractable Cr limit applies. For all other materials, chromium based dyes are not accepted, and the total Cr limit applies. 5 Extractable Cu limit applies only to woven baby wear up to size 98
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Limit
The sum < 0.5 ppm Polychlorinated Triphenyls (PCT) Polyvinylchloride (PVC) and similar chlorinated polymers, e.g. Polyvinylidenchloride Triclosan Not detected
Not detected
Leather
Restricted substance Limit
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) Chlorinated Aromatic Hydrocarbons* Chloroparaffins Short chained (SCCPs) C10-C13 Medium chained (MCCPs) C14-C17 Chromium VI (Cr6+) Dyes Azo Dyes & Pigments* Other Dyes* Flame Retardants*6 Formaldehyde
Products for children aged 0-3 years (e.g. 50-98 cl) Products for children above 3 years (e.g. 104-170 cl) and products for adults with direct skin contact, incl. bed linen Products for adults without direct skin contact (e.g. outer wear, curtains)
100 ppm 100 ppm Not detected Not detected 2 ppm, per listed substance group
20 ppm, per listed amine Not detected, per listed other dye Not detected
Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix A.1. No flame retardants are allowed on babies and childrens products.
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Restricted substance Metals, Total Amount Arsenic (As) Cadmium (Cd) Lead (Pb) Mercury (Hg) Organotin Compounds* Dibutyltin (DBT) Dioctyltin (DOT) Sum of other listed organotins Sum of other not listed tri-substituted organotins Pesticides* Dieldrine Sum of listed pesticides Perfluoro Compounds Perfluorooctane Sulfonate (PFOS) and PFOS related substances Perfluorooctanoic Acid (PFOA) Phenols Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) Polychlorinated Biphenyls (PCB) Polychlorinated Triphenyls (PCT)
Limit
1 g/m2 1 g/m2
Not detected Not detected 50 ppm The sum < 0.5 ppm
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) Bisphenol-A (BPA) Chloroparaffins Short chained (SCCPs) C10-C13 Medium chained (MCCPs) C14-C17
7
100 ppm 100 ppm Not detected Not detected Not detected
Surface coating includes paint and print, excluding reactive print and electroplating.
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Isocyanates* Metals, Total amount Cadmium (Cd) Lead (Pb) Mercury (Hg) Organotin Compounds* Dibutyltin (DBT) Dioctyltin (DOT) Sum of other listed organotins Sum of other not listed tri-substituted organotins Phenols Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) Phthalates* Polyaromatic Hydrocarbons (PAH) * Benzo(a)pyrene Sum of other listed PAHs Polychlorinated Biphenyls (PCB)
Not detected Not detected 50 ppm 500 ppm, per phthalate The sum of phthalates 1000 ppm
The sum < 0.5 ppm Polychlorinated Triphenyls (PCT) Polyvinylchloride (PVC) And similar chlorinated polymers, e.g. Polyvinylidenchloride Triclosan Not detected
Not detected
Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix A.1. No flame retardants are allowed on babies and childrens products. Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test method.
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Metal
Restricted substance Metals, Total Amount Cadmium (Cd) Lead (Pb):
Decorative10 items Functional11 items
Limit
g/cm2/week g/cm2/week
1 g/m2
10 11
Decorative items are items that are not needed for a specific function, for example jewelleries.
Functional items are items needed for a specific function, for example belt buckles, buttons, zippers and rivets used to strengthen seems.
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Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) Cationic Surfactants* Feather and Down Products filled with down and/or feathers Oxygen index number12 Mesophil aerobic bacteria count Faecal streptococci count Sulphite reducing clostridium count Presence of salmonella Flame Retardants*13 Formaldehyde
Products for children aged 0-3 years, incl. bed linen (e.g. 50-98 cl) Products for children above 3 years (e.g. 104-170cl) and products for adults with direct skin contact, incl. bed linen Products for adults without direct skin contact (e.g. outer wear, curtains)
100 ppm 100 ppm Not detected Not detected Not detected, sum of listed surfactants
20 <1 000 000 CFU/g <100 CFU/g <100 CFU/g Absent in 20 g Not detected
Isocyanates* Organotin Compounds* Dibutyltin (DBT) Dioctyltin (DOT) Sum of other listed organotins Sum of other not listed tri-substituted organotins Phthalates*
1 ppm 1 ppm Not detected 1 ppm 500 ppm per phthalate The sum of phthalates 1000 ppm
12 13
If the oxygen index number is 20, no further analysis of the microbiological state is necessary Supplier must always get an approval from H&M before using any flame retardant at all, even if it is not listed in Appendix A. No flame retardants are allowed on babies and childrens products. Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test method.
14
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Recycled Material
For recycled materials16, the restrictions are the same as for other materials, with below mentioned exceptions. These exceptions are only valid for orders where H&M explicitly specify on the product that recycled material is used. Restricted substance Details of exception Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) * Cationic Surfactants* Provided that no additional APEO has been used after the collection of the waste, the APEOrestriction does not apply. Provided that no additional banned cationic surfactants have been used after the collection of the waste, the restriction about cationic surfactants does not apply.
Metals, Total Amount Chromium (Cr) Provided that no additional Chromium dyes have been used after the collection of the waste, the restriction about total chromium does not apply. The restriction for extractable Chromium applies, regardless of waste type.
15
http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
16 Recycled materials is both pre- and post-consumer waste defined as follows: Pre-consumer waste: The reintroduction of manufacturing scrap, such as waste from textile production, back into the yarn manufacturing process. Post-consumer waste: A waste produced by the end consumer of a material stream such as used PET bottles or worn out garments.
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Cat 1. 0.07 mg/dm2 Cat 2. 0.3 mg/l Cat 3. 0.1 mg/l Lead (Pb) Cat 1. 0.8 mg/dm2 Cat 2. 4.0 mg/l Cat 3. 1.5 mg/l Cat 1. Objects which can be filled and objects that can not be filled, whose internal depth measured between the lowest point and the horizontal plane passing through the upper edge is less than or equal to 25 mm Cat 2. Fillable objects other than 1) packaging or storage containers with a capacity up to 3 l 2) Cooking utensils Cat 3. Cooking utensils; packaging and storage containers with a capacity up to 3 l. Cobalt (Co) 0.1 mg/l Lead (Pb), Cadmium (Cd) (Drinking Rim Area) Pb: 2mg/l Cd: 0.2 mg/l
17
http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
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Metal
Restricted substance Aluminium (Al) (only for Al-container in contact with fruit juices) Cadmium (Cd) Chromium (Cr) Lead (Pb) Nickel (Ni) Limit 8 ppm
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Plastic
Restricted substance Limit
All Plastics Must comply with 2002/72/EC on plastic materials that come into contact with food, and its amendments. Global Migration 10 mg/dm2 PAH* content Specific Migration PAH* Specific Migration Phthalates* 0.2 ppm 0.2 to 10 ppm18: Test specific migration PAH.19 5 g/kg BBP: 30 ppm DEHP: 1.5 ppm DBP: 0.3 ppm DINP/DIDP: 9 ppm ODP/DnDP/DnOP: 5 ppm
0.008 % 1%
15 ppm 30 ppm
15 ppm
Polyamide (PA) Peroxide Specific Migration Caprolactam Specific Migration Primary Aromatic Amines Polyethylene (PE) Chromium (Cr) Peroxide Vanadium (V)
18 19
Fail test result if PAH content is >10 ppm Compliant test result if specific migration result is 5 g/kg
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40 ppm as PbO 1%
0.008 % 1%
Polypropylene (PP) Chromium (Cr) Hafnium (Hf) Peroxide Vanadium (V) Zirconium (Zr)
Rubber Organotin Compounds* Specific Migration Formaldehyde Specific Migration Primary Aromatic Amines Total Lead (Pb) Zinc (Zn)
0.5 %
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Temperature Resistant Coatings Specific Migration Chromium VI (Cr6+) Specific Migration Chromium III (Cr3+) Specific Migration Formaldehyde Specific Migration Lithium (Li) Specific Migration Perfluorooctanoic Acid (PFOA) Specific Migration Phenolic Substances* Specific Migration Primary Aromatic Amines Thermoplastic Elastomer (TPE) Specific Migration Formaldehyde Zinc (Zn)
Not detected Not detected 15 mg/dm2 0.5 mg/extract 0.005 mg/dm2 0.05 mg/dm2 0.01 mg/dm2
Wood
Restricted substance Pentachlorophenol (PCP) Polychlorinated biphenyls (PCB)* Specific Migration of Formaldehyde and Hexamethylenetetramine Limit Not detected 15 ppm SML(T) 15 ppm
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Cosmetic Products
Restricted substance Acetanilide in all types of products except when used to stabilize hydrogen peroxide to stabilize hydrogen peroxide Adenosine in all types of products except anti wrinkle products in anti wrinkle products Aloe Barbadensis (Aloe Vera Gel) Antimony (Sb) in all types of products except glitter products with polyester ingredient in glitter products with polyester ingredient Polyester ingredient (i.e. glitter flakes) Arachis Hypogaea Oil/Flour21 (Peanut oil/flour and all other substances containing traces of peanut) Arsenic (As) Beta-sitosterol in all types of products except skin creams in skin creams Cadmium (Cd) Camphor Chlorofluorocarbon propellants (halogenated alkanes) Chromium (Cr) Chromium VI (Cr6+) CI 77288
20 21
Limit
Total content: 10 ppm Total content, except the polyester ingredient: 10 ppm Total content: 260 ppm Shall not contain any Cyanogen bounds.
Usage ban 0.1 % Total content: 5 ppm 3% Usage ban Total content: 10 ppm Not detected Usage ban
The regulation was adopted on the 30 November 2009, but not yet published at the time of this publication. Supplier must inform H&M before use of any peanut containing substance.
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Restricted substance CI 77289 Cinnamyl Anthranilate Cobalt (Co) Cyclomethicone Cyclopentasiloxane Formaldehyde in all types of products originated from Formaldehyde releasers22
Limit Usage ban Usage ban Total content: 10 ppm Usage ban Usage ban Usage ban <0.05 % (500 ppm) free or possible release of formaldehyde (calculated content)23
Formaldehyde releasers22, i.e. some preservatives in leave-on products for face Usage ban in leave-on products for children under 3 Usage ban years of age Fragrance Allergens, as defined in EU Cosmetic Regulation The calculation of the concentration of the fragrance allergens shall take into account all possible sources of the fragrance allergens. I.e. not only the perfume and/or aroma can contribute to the concentration of them. Possible other sources include, but are not limited to, ingredients, herbal extracts and essential oils. in all deodorants and anti-perspirants aimed 0 fragrance allergens to be labelled on product. to be used under arms in all childrens products Max 4 fragrance allergens to be labelled on product. in all leave-on products except childrens Max 6 fragrance allergens to be labelled on products product. in all rinse-off products except childrens Max 8 fragrance allergens to be labelled on products product. Lead (Pb) Total content: 5 ppm Melaleuca Alternifolia Oil (Tea Tree Oil)24 in oral hygiene products in all types of products except oral hygiene products Mercury (Hg) Methylchloroisothiazolinone/ Methylisothiazolinone (MCI/MI), (Kathon CG) Methylisothiazolinone (MI) 0.5 % 2.0 % Total content: 1 ppm Usage ban
Usage ban
22
Formaldehyde releasers are for example: 2-Bromo-2-Nitropropane-1,3-Diol, Diazolidinyl Urea, DMDM Hydantoin, Imidazolidinyl Urea. The manufacturer must always control with their raw material supplier if the preservative used is a Formaldehyde releaser. If it is the raw material supplier will give them all necessary information. 0.05% (500 ppm) free or possible release of formaldehyde (calculated content) demands the warning: Contains formaldehyde. Shall not be used in products for children below 12 years.
23
24
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Restricted substance Methyl Salicylate in all types of products except mouth water and skin cream products in mouth water in skin creams Nickel (Ni) 2-Nitro-1,4-Benzenediamine or 2-Nitro-p-Phenylenediamine 4-Nitro-1,2-Benzenediamine or 4-Nitro-o-Phenylenediamine Nitrosamines Nonylphenol Ethoxylates (NPE) and its degradation products Octylphenol Ethoxylates (OPE) and its degradation products Phenylmercuric salts (including borate) Phenyl Salicylate in all types of products except oral hygiene products in oral hygiene products Phthalates except Diethyl Phthalate Prunus Armeniaca Kernel Oil (Apricot kernel oil) Residual Monomers e.g. Acrylamide, Acrylates Residual Solvents e.g. Benzene, Toluene Retinol (Vitamin A) Retinyl Palmitate (Vitamin A) Salicylic Acid25 when used as a preservative in all types of products except when used as a preservative Sucralfate in all types of products except skin products in skin products Symphytum Officinale (Comfrey) Talc Thimerosal
Limit
Usage ban 0.05 % 1.0 % Total content: 10 ppm Usage ban Usage ban See also EU Cosmetic regulation. Shall not be formed during the lifetime of the product. Usage ban Usage ban Usage ban
Usage ban 1.5 % Usage ban Shall not contain any Cyanogen bounds Shall not be in the product. Shall not be in the product. 10 000 IU/g equals 0.3 % 10 000 IU/g equals 0.7 %
Usage ban 2% Shall not contain any Pyrrolizidine Alkaloids Must at least be of cosmetic purity grade See also EU Cosmetic regulation Usage ban
25
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Restricted substance Thioctic Acid in all types of products except anti wrinkle products in anti wrinkle products Toluene 1,1,1-Trichloroethane Triclosan Urea Viscum Album in all types of products except shampoos in shampoo Vitamins (e.g. Vitamin E) except Vitamin A, C and D Xanthin derivatives e.g. Caffeine, Theophylline, Aminophylline, Theobromine and Methylsilanol
Limit
Usage ban 5% Usage ban Usage ban Usage ban 10 % Products intended to be diluted >10 %
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Additional Requirements
Requirement/Restricted substance Fragrance Oils Good Manufacturing Practice (GMP) Must follow ISO 22716:2007 Cosmetics GMP Good Manufacturing Practices. Microbiological Quality26 For products specifically intended to be used in the eye area27, on mucous membranes28, or for children under 3 years: Total viable count for Aerobic Mesophyllic microorganisms Pseudomonas aeruginosa Staphylococcus aureus Candida albicans For other products than those specified above: Total viable count for Aerobic Mesophyllic microorganisms Pseudomonas aeruginosa Staphylococcus aureus Candida albicans Product Information files (PI-files) All products must have a complete PI-file. Stability test To deliver, stability test must be OK after 12 w. Total stability test period is 52 w. Report to H&M if any deviation is found. <1 000 CFU/g or ml in 0.1 g or 0.1 ml of the product not detected in 0.1 g or 0.1 ml of the product <100 CFU/g or ml in 0.5 g or 0.5 ml of the product not detected in 0.5 g or 0.5 ml of the product Limit/Requirement All fragrance oils must fulfil IFRA standard.
26 27 28
Test method: ISO 21149:2009, ISO 22717:2009, ISO 22718:2009, ISO 18416:2009 Eye area includes eye lid, eye lashes, and the area below the eye down to the cheek bone. Mucous membranes include the intimate/genital area and the oral cavity of the mouth.
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Part 4: Toys
Toys must comply with the European Standard EN 71. Below is a summary of the chemical restrictions and requirements that have to be fulfilled for toys. This table does not claim to be complete. Toys must also fulfil Part 1.
Restricted substance Extractable Metals Flame Retardants Colorants Primary Aromatic Amines Monomers Solvents Migration Solvents Inhalation Wood Preservatives Preservatives Plasticizers - Migration
CAS no See EN 71-3 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9
Limit See EN 71-3 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9 See EN 71-9
Test method See EN 71-3 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11 EN 71-10 & 11
Additional Requirements
Requirement REACH SVHC Limit/Requirement Usage ban for all substances listed on the Candidate List of Substances of Very High Concern (SVHC). Check the ECHA website for the updated list29
29
http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
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Restricted substance Lead (Pb) Cadmium (Cd) Mercury (Hg) Chromium VI (Cr6+) Polybrominated Diphenyl Ethers (PBDE) and Polybrominated Biphenyls (PBB)
Limit 1000 ppm 100 ppm 1000 ppm 1000 ppm 1000 ppm
Additional Requirements
Requirement REACH SVHC Limit/Requirement Usage ban for all substances listed on the Candidate List of Substances of Very High Concern (SVHC). Check the ECHA website for the updated list32
30
EU directive 2002/95/EC Directive on the Restriction of the use of certain Hazardous Substances in electrical and electronic equipment (RoHS) 31 EU directive 2002/96/EC Directive on Waste Electrical and Electronic Equipment (WEEE) 32 http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
H&M Chemical Restrictions, 14 December 2009 Part 5 Electrical and Electronic Products
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Part 6: Packaging
Below restrictions and requirements are valid for all packaging that the customer brings home with the product. The container/packaging33 of cosmetic products is considered to be a part of the cosmetic product. Therefore it must comply with both EU Cosmetic Regulation and below restrictions and requirements. If a group of substances is marked with an asterisk* in the table below each included substance is specified in Appendix A.6.
Glass
Restricted substance Total Lead (Pb) Limit 100 ppm
Metal
Restricted substance Metal containers/packages for cosmetic products Metals, total amount Cadmium (Cd) Lead (Pb) Mercury (Hg) Limit Not corrode, i.e. must be of non-corroding material
1 g/m2 1 g/m2
Not detected
The container/packaging of cosmetic products includes both primary and secondary packaging, but excludes transportation packaging.
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Restricted substance Polyvinylchloride (PVC) And similar chlorinated polymers, e.g. Polyvinylidenchloride
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP) Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) Bisphenol-A (BPA) Dimethylformamide (DMF) Isocyanates* Metals, Total Amount Cadmium (Cd) Lead (Pb) Mercury (Hg) Organotin Compounds* Dibutyltin (DBT) Dioctyltin (DOT) Sum of other listed organotins Sum of other not listed tri-substituted organotins Phenols Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) Phthalates* Polychlorinated Biphenyls (PCB) The sum < 0.5 ppm Polychlorinated Triphenyls (PCT) Polyvinylchloride (PVC) And similar chlorinated polymers, e.g. Polyvinylidenchloride Triclosan Not detected 1 ppm 1 ppm Not detected 1 ppm 75 ppm 90 ppm 10 ppm 100 ppm 100 ppm Not detected Not detected Not detected 100 ppm Not detected, sum of listed isocyanates
Not detected Not detected 50 ppm 500 ppm, per phthalate The sum of phthalates 1000 ppm
Not detected
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Mainly used in silica gel. Mainly used in humidity reducing sachets. If supplier believes fumigation is necessary, contact H&M. More info and restrictions regarding fumigation can be found in H&M PIM Packing Instruction Manual. http://echa.europa.eu/chem_data/authorisation_process/candidate_list_table_en.asp
37
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Limit/Requirement Usage ban Usage ban Finishing treatments with chlorinated bleaching agents can be used in denim production only.
Glues Solvent based systems shall be exchanged to water based systems.38 Organic Solvents Usage ban
In glues, spot removers, paints, lacquers etc.
Benzene (Benzol) 1,4-Butanediol Dimethylacetamide (DMAC) Dimethylformamide (DMF) Ethylene glycol monoethyl ether n-Hexane 4,4methylenebis(2-chloraniline) (MOCA) Methylene chloride Phenol Tetrachloroethylene (PERC) Tetrachloromethane Trichloroethylene (TRIS) Toluene (Toluol) Sand Blasting
The abrasive material must contain less than 1% crystalline silica, i.e. quartz, trydimite and christobalite.
38
Supplier must always get an approval from H&M before using any non-water based systems.
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A.1. Apparel/Accessories/Footwear/Interior
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP)
Name Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) CAS no. Various Various 25154-52-3 27193-28-8
Bisphenol-A (BPA)
Name BPA CAS no. 80-05-7
Cationic Surfactants
Name Distearyldimethyl ammouniumchloride (DSDMAC) Ditallowdimethyl ammoniumchloride (DTDMAC) Dihydrogenated tallowdimethyl ammouniumchloride (DHTDMAC) CAS no. 107-64-2 68783-78-8 61789-80-8
Chloroparaffins
Name Short chained (SCCPs) C10-C13 Medium chained (MCCPs) C14-C17 CAS no. 85535-84-8 85535-85-9
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
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Chromium VI (Cr6+)
Name Cr6+ CAS no. 18540-29-9
Dimethylformamide (DMF)
Name Dimethylformamide (DMF) CAS no. 68-12-2
Dimethylfumarate (DMFu)
Name Dimethylfumarate (DMFu) CAS no. 624-49-7
Disperse Dyes
Name Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse Disperse CI NO Blue 1 64 500 Blue 3 61 505 Blue 7 62 500 Blue 26 63 305 Blue 35 Blue 102 Blue 106 Blue 124 Brown 1 Red 1 11 110 Red 11 62 015 Red 17 11 210 Orange 1 11 080 Orange 3 11 005 Orange 11 60 700 Orange 37 11 132 Orange 76 (previously designated Orange 37) Orange 149 Yellow 1 10 345 Yellow 3 11 855 Yellow 9 10 375 Yellow 23 26 070 Yellow 39 Yellow 49 CAS no. 2475-45-8 2475-46-9 3179-90-6 3860-63-7 12222-75-2 12222-97-8 12223-01-7 61951-51-7 23355-64-8 2872-52-8 2872-48-2 3179-89-3 2581-69-3 730-40-5 82-28-0 12223-33-5 51811-42-8 85136-74-9 119-15-3 2832-40-8 6373-73-5 6250-22-3 12236-29-2 54824-37-2
Flame Retardants
Name Tris(2,3-dibromopropyl)phosphate (TRIS) Bis(2,3-dibromopropyl)phosphate Tris-(aziridinyl)-phosphineoxide (TEPA) Polybrominated Diphenyl Ethers (PBDE) Tetrabromobisphenol A (TBBP A) Polybrominated Biphenyls (PBB) Tri-o-cresyl phosphate Tris(2-chloroethyl)phosphate (TCEP) Hexabromocyclododecane 2,2-Bis(bromomethyl)-1,3-propanediol Tris(1,3-dichloroisopropyl)phosphate (TDCP) Triphenyl phosphate (TPhP) CAS no. 126-72-7 5412-25-9 5455-55-1 Various 79-94-7 Various 78-30-8 115-96-8 3194-55-6 3296-90-0 13674-87-8 115-86-6
Formaldehyde
Name Formaldehyde CAS no. 50-00-0
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
31(52)
Isocyanates
Name Diphenylmethane diisocyanate (MDI) Hexamethylene diisocyanate (HMDI) Isophorone diisocyanate (IPDI) Tetramethylxylene diisocyanate (TMXDI) 2,4-Toluene diisocyanate (2,4 TDI) 2,6-Toluene diisocyanate (2,6 TDI) CAS no. 101-68-8 822-06-0 4098-71-9 2778-42-9 584-84-9 91-08-7
Metals
Name Antimony (Sb) Arsenic (As) Cadmium (Cd) Chromium (Cr) Cobalt (Co) Copper (Cu) Lead (Pb) Mercury (Hg) Nickel (Ni) CAS no. 7440-36-0 7440-38-2 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-02-0
Octamethylcyclotetrasiloxane
Name Octamethylcyclotetrasiloxane CAS no. 556-67-2
Organotin Compounds
Name Dibutyltin (DBT) Dioctyltin (DOT) Tributyltin (TBT) Tricyclohexyltin (TCyHT) Trioctyltin (TOT) Triphenyltin (TPhT) Tripropyltin (TPT) Other tri-substituted organotins CAS no. 1002-53-5 56573-85-4 6056-50-4 250252-89-2 668-34-8 Various
Other Dyes
Name Acid Red 26 Basic Red 9 Basic Violet 14 Direct Black 38 Direct Blue 6 Direct Brown 95 Direct Red 28 Solvent Yellow 1 Solvent Yellow 2 Solvent Yellow 3 p-Phenylenediamine CI 16 42 45 30 22 30 22 11 11 11 76 NO 150 500 510 235 610 145 120 000 020 160 060 CAS no. 3761-53-3 569-61-9 632-99-5 1937-37-7 2602-46-2 16071-86-6 573-58-0 60-09-3 60-11-7 97-56-3 106-50-3
Perfluoro Compounds
Name Perfluorooctane Sulfonate (PFOS) and PFOS related substances Perfluorooctanoic Acid (PFOA) CAS no. Various 335-67-1
Pesticides
Name Aldrine Captafol Chlordane Chlordecone (Kepon) Chlordimerform Chlorobenzilate DDD DDE CAS no. 309-00-2 2425-06-1 57-74-9 143-50-0 6164-98-3 510-15-6 72-54-8 72-55-9
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
32(52)
Pesticides
Name DDT Dibromochloropropane (DBCP) Dieldrine Dinoseb DTTB-(Timiperone) Endrine Endosulphane Ethylene dibromide Heptachlor Heptachloroepoxide Hexachlorobenzene -Hexachlorcyclohexane -Hexachlorcyclohexane -Hexachlorcyclohexane Lindane (-Hexachlorcyclohexane) Isodrin Kelevane Metamidophos Methoxychlor Mirex Monocrotophos Monomethyldibromodiphenylmethane Monomethyldichlorodiphenylmethane Monomethyltetrachlorodiphenylmethane Parathion Parathion-methyl Perthane (Ethylane) Phosphamidone Quintozene Strobane Telodrin (Isobenzan) Toxaphene (Camphechlorine) Halogenated biphenyls with the formula C12HnX10-n x=halogen, n=1,2,...9 Halogenated terphenyls with the formula C18HnX14-n x=halogen, n=1,2,...13 Halogenated naphthalenes with the formula C10HnX8-n x=halogen, n=1,2,...7 2-(2,4,5-Trichlorophenoxy) propionic acid and its salts and 2-(2,4,5-Trichlorophenoxy) propionyl compunds (2,4-D) 2,4,5-Trichlorophenoxyacetic acid and its salts and 2,4,5-Trichlorophenoxyacetyl compounds (2,4,5-T) CAS no. 50-29-3 96-12-08 60-57-1 88-85-7 57648-21-2 72-20-8 115-29-7, 33213-65-9 106-93-4 76-44-8 1024-57-3 118-74-1 319-84-6 319-85-7 319-86-8 58-89-9 465-73-6 4234-79-1 10265-92-6 72-43-5 2385-85-5 6923-22-4 99688-47-8 76253-60-6 56-38-2 298-00-0 72-56-0 13171-21-6 82-68-8 8001-50-1 297-78-9 8001-35-2 Various Various Various Various
Various
Phenols
Name Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) CAS no. 87-86-5 58-90-2, 25167-83-3 90-43-7
Phthalates
Name Di-isononyl phthalate (DINP) Di(ethylhexyl) phthalate (DEHP) Di-n-octyl phthalate (DNOP) Di-iso-decyl phthalate (DIDP) Butyl benzyl phthalate (BBP) Dibutyl phthalate (DBP) All other phthalates (all other esters of o-phthalic acid CAS no. 28553-12-0 117-81-7 117-84-0 26761-40-0 85-68-7 84-74-2 Various
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
33(52)
Polychlorinated Compounds
Name Polychlorinated Biphenyls (PCB) Polychlorinated Triphenyls (PCT) CAS no. 1336-36-3 61788-33-8
Polyvinylchloride (PVC)
Name Polyvinylchloride (PVC) Polyvinylidenchloride CAS no. 9002-86-2 9002-85-1
Triclosan
Name Triclosan CAS no. 3380-34-5
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
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H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
35(52)
28553-12-0 117-81-7 117-84-0 26761-40-0 85-68-7 84-74-2 Various 72869-69-3 Various e.g.: 79-06-1 96-33-3 140-88-5 141-32-2 Various e.g.: 71-43-2 108-88-3 68-26-8/11103-57-4 79-81-2 69-72-7 54182-58-0
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
36(52)
Restricted Substance
Name Symphytum Officinale (Comfrey) Talc Thioctic Acid Thimerosal Toluene 1,1,1-Trichloroethane Triclosan Urea Viscum Album Vitamins, except Vitamin A, C and D, e.g.: Vitamin B1, thiamine Vitamin B2, riboflavin Vitamin B6, adermine Vitamin B12 Vitamin E, tocopherol Vitamin K Biotin, Vitamin B7/H Folic acid, L-Glutamic acid Niacin, Vitamin B5 Pantothenic acid, Vitamin B3/B5 Xanthin derivates e.g.: Aminophylline Caffeine Theobromine Theophylline Methylsilanol CAS no. 84696-05-9 14807-96-6 1077-28-7 54-64-8 108-88-3 71-55-6 3380-34-5 57-13-6 84929-55-5 Various e.g.: 59-43-8 83-88-5 8059-24-3 68-19-9 59-02-9/ 119-13-1/ 1406-18-4/ 10191-41-0 58-27-5/ 84-80-0/ 11104-38-4/ 12001-79-5 58-85-5 59-30-3 59-67-6 79-83-4 Various e.g.: 317-34-0 58-08-2 83-67-0 58-55-9 Various
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
37(52)
A.6. Packaging
Alkylphenol Ethoxylates / Alkylphenols (APEO/AP)
Name Nonylphenol Ethoxylates (NPE) Octylphenol Ethoxylates (OPE) Nonylphenol (NP) Octylphenol (OP) CAS no. Various Various 25154-52-3 27193-28-8
Bisphenol-A (BPA)
Name BPA CAS no. 80-05-7
Dimethylformamide (DMF)
Name Dimethylformamide (DMF) CAS no. 68-12-2
Dimethylfumarate (DMFu)
Name Dimethylfumarate (DMFu) CAS no. 624-49-7
Formaldehyde
Name Formaldehyde CAS no. 50-00-0
Isocyanates
Name Diphenylmethane diisocyanate (MDI) Hexamethylene diisocyanate (HMDI) Isophorone diisocyanate (IPDI) Tetramethylxylene diisocyanate (TMXDI) 2,4-Toluene diisocyanate (2,4 TDI) 2,6-Toluene diisocyanate (2,6 TDI) CAS no. 101-68-8 822-06-0 4098-71-9 2778-42-9 584-84-9 91-08-7
Metals
Name Cadmium (Cd) Chromium (Cr) Lead (Pb) Mercury (Hg) CAS no. 7440-43-9 7440-47-3 7439-92-1 7439-97-6
Organotin Compounds
Name Dibutyltin (DBT) Dioctyltin (DOT) Tributyltin (TBT) Tricyclohexyltin (TCyHT) Trioctyltin (TOT) Triphenyltin (TPhT) Tripropyltin (TPT) Other tri-substituted organotins CAS no. 1002-53-5 56573-85-4 6056-50-4 250252-89-2 668-34-8 Various
Perfluoro Compounds
Name Perfluorooctane Sulfonate (PFOS) and PFOS related substances Perfluorooctanoic Acid (PFOA) CAS no. Various 335-67-1
Phenols
Name Pentachlorophenol (PCP) and its salts and esters Tetrachlorophenol (TeCP) and its salts and esters o-Phenylphenol (OPP) CAS no. 87-86-5 58-90-2, 25167-83-3 90-43-7
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
38(52)
Phthalates
Name Di-isononyl phthalate (DINP) Di(ethylhexyl) phthalate (DEHP) Di-n-octyl phthalate (DNOP) Di-iso-decyl phthalate (DIDP) Butyl benzyl phthalate (BBP) Dibutyl phthalate (DBP) All other phthalates (all other esters of o-phthalic acid CAS no. 28553-12-0 117-81-7 117-84-0 26761-40-0 85-68-7 84-74-2 Various
Polychlorinated Compounds
Name Polychlorinated Biphenyls (PCB) Polychlorinated Triphenyls (PCT) CAS no. 1336-36-3 61788-33-8
Polyvinylchloride (PVC)
Name Polyvinylchloride (PVC) Polyvinylidenchloride CAS no. 9002-86-2 9002-85-1
Triclosan
Name Triclosan CAS no. 3380-34-5
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
39(52)
H&M Chemical Restrictions, 14 December 2009 Appendix A Restricted Substances and CAS numbers
40(52)
Reporting Limit
50 mg/kg
50 mg/kg
5 mg/kg
Bisphenol-A Cationic Surfactants Chlorinated Aromatic Hydrocarbons Chloroparaffins (SCCP and MCCP)
100 mg/kg
3 mg/kg
3 mg/kg
10 mg/kg
Dimethylformamide
0.03 mg/kg
Dimethylfumarate Dyes
Textiles in general: EN 14362-1:2003 Polyester textiles: EN 14362-2:2003 Azo Dyes & Pigments Leather: ISO/DIS 17234-1 ISO/DIS 17234-2 Detection of p-Aminoazobenzene: LFBG B 82.02-9 Disperse Dyes DIN 54231: 2005-11 BVL B 82.02-10: 2007-03 DIN 54231 BVL B 82.02-10: 2007-03 Except for p-phenylenediamine: Methanol extraction and analysis by GC-MS
10 mg/kg
10 mg/kg
10 mg/kg
10 mg/kg 1 mg/l
1-5 mg/l
Other Dyes
41(52)
Restricted Substance
Test Method
TRIS, Bis(2,3-dibromopropyl) phosphate: Methanol extraction and analysis with GC-MS TEPA: Potassium Hydroxide digestion followed by GC-MS Headspace analysis of Ethyleneimine
Reporting Limit
10 mg/kg
10 mg/kg
Flame Retardants
PBDEs, TBBP A: Acetonitril extraction and analysis by LC-DAD-MS and confirmation with GC-MS PBBs, Tri-o-cresyl phosphate, TCEP, Hexabromocyclododecane, 2,2-Bis(bromomethyl)1,3-propanediol, TDCP, TPhP: Methanol extraction and analysis by GC-MS Textile, non-woven, prints: Products for children 0-3 years, incl. bed linen: JIS L 1041-1983, Method A Textile, non-woven, prints: Products for children above 3 years and products for adults with direct skin contact incl. bed linen: ISO 14184-1 Leather: ISO 17226-2 Paper: EN 645 and EN 1541
16 mg/kg
Formaldehyde
20 mg/kg
20 mg/kg 3 mg/kg Reporting limit: 0.1 mg/kg Except Hg/Cd: 0.02 mg/kg
Isocyanates
ISO 10283 Draft DIN 5433-3 Extractable with artificial sweat solution by ISO 105-E04 Metal content by ICP-MS analysis Nickel: Nickel release by EN 1811. Abrasion of coated items by EN 12472:2005 + A1:2009 Total metal content by microwave digestion with HNO3/H2O2 and ICP-MS analysis
0.05 g/cm2/week
Lead in paint and surface coating: CPSIA Section 101 16 CFR 1303: CPSIA Standard Operating Procedure for Determining Lead in Paint Not applicable , check physical data info on the MSDS 1. Smell test SNV 195651 2. Light microscope analysis for suspicious spots 3. Staining with lactophenol blue followed by microscope analysis 1. Suspicious smell/ no suspicious smell 2. Little spots 3. Spores and mycelia of mould detected/not detected 1. no odour 2. slight odour, not unpleasant 3. endurable odour, slightly unpleasant 4. pestering odour, unpleasant 5. insufferable odour, very unpleasant 50 mg/kg 0.05 mg/kg
Mineral Oils
Mould Test
39
Where A is the absorbance of the sample and A0 is the absorbance of the zero-sample, both measured according to test method.
42(52)
Restricted Substance
Organic Solvents
Test Method
Extraction with ethylacetate followed by GC-MS screening and/or headspace-GC/MS analysis Draft CEN/TS 15968 Methanol extraction and analysis by LC/MS or LC/MS/MS U.S. EPA Method 8081a, 8151a, 8141a & 8270 c or Analysis of organochloro pesticides by GC-MS or LC-MS ISO 3071-1980
Reporting Limit
1 mg/kg
1 g/m2
Perfluoro Compounds
0.2 mg/kg
Pesticides
pH
Specify in the test report which solution (water or KCl) that has been used. Textile, plastics, paper: BVL B 82.02-08 (modified) PCP, TeCP: Potassium Hydroxide extraction direct LC-MS analysis OPP: BVL B 82.02-08 (modified) Acetone extraction, derivatisation followed by GC-MS analysis Leather: BVL B 82.02-08 (modified) PCP, TeCP, OPP: Acetone extraction, derivatisation followed by GC-MS analysis Textile articles (surface coating): ISO 15777
5 mg/kg
Phenols
Phthalates
All other materials: Extraction with THF/CAN and analysis by HPLC-DAD-MS, confirmation test for DBP using GC-MS Solvent extraction and analysis by GC-MS ZEK 01_02-08 Extraction with toluene followed by GC-MS analysis Beilsteins test and infrared spectroscopy (IR) with or without chemical separation Solvent extraction, derivatisation followed by GC-MS analysis
50 mg/kg
qualitative
10 mg/kg
Triclosan
43(52)
Test Method
EN 10955 in combination with EN 1230.1 & 2 EN 1186-1 to 15 CEN/TS 13130
Bisphenol-A Caprolactam Chromium (Cr) Chromium VI (Cr6+) Formaldehyde Formaldehyde and Hexamethylenetetramine Lithium (Li) Melamine Organotin Compounds Perfluorooctanoic Acid (PFOA) Phenolic Substances Phthalates Polyaromatic Hydrocarbons (PAH) Primary Aromatic Amines Metals
EN 13130-13 EN 13130-16 EN 13130 + ICP/MS EN 13130 + photometric detection EN 13130-23 EN 13130-23 EN 13130 + ICP/MS EN 13130-27 EN 1186-1 + ICP/MS, if detected derivatisation + GC/MS EN 13130 + LC/MS EN 13130 + photometric detection EN 13130 + GC/MS resp. LC/MS EN 13130 + GC/MS EN 13130 xx (draft). Photometric determination and identification with GC/MS resp. LC/MS
Chromium VI (Cr6+) Chromium III (Cr3+) Cobalt (Co) Hafnium (Hf) Lead (Pb)
EN 1388-1, ICP/MS Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS Paper and Board: EN 12498 Ceramics and Glass: EN 1388-1 and-2, 84/500/EEC, Drinking rim area: DIN 51031 Metals: EN 1388-1, ICP/MS DIN 17075 EN 645 + ICP-MS According to EN 1388-1 and -2 Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS Paper and Board: EN 12498 and EN645 [cold water extract] & EN647 [hot water extract] Ceramics and Glass: EN 1388-1 and-2, 84/500/EEC, Drinking rim area: DIN 51031 Metals: EN 1388-1, ICP/MS Plastic: Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS EN 12497 EN 1388-1, ICP/MS Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS Total metal content by microwave digestion with HNO3/H2O2 and determination with ICP/MS
Mercury (Hg) Nickel (Ni) Vanadium (V) Zinc (Zn) Zirconium (Zr)
44(52)
Restricted Substance
Other Test Methods
Test Method
Antimicrobial Effect Azo Dyes & Pigments Di-isobutyl Phthalate (DIBP) Migration Diisopropylnaphthalene (DIPN) Extractable Matter Formaldehyde Glyoxal Isocyanates Organoleptic Test Organotin Compounds Pentachlorophenol (PCP) Peroxide Polyaromatic Hydrocarbons (PAH)
EN 1104 EN 14362 part 1 & 2, LFGB ASU 82.02-8 DIN PREN 14719 DIN PREN 14719 Gravimetric EN 645 + EN 1541 DIN 54603 EN 13130-8 modified EN 1230-1 and -2 in combination with EN 10955 DIN 38407-13 LFBG 82.02.8 Ph. Eur. Method 2.5.5 ZEK 01.2-08 (Harmonized method of the Central district for information exchange of accredited institutions in accordance with EN 1186 ff) ISO 15318 EN 1186-1 Gravimetric Method (90C, 24 hrs)
Polychlorinated Biphenyls (PCB) Primary Aromatic Amines Release Volatile Organic Matter (VOM)
45(52)
4)
Permitted Colorants40
Colour
X X X
CI 15880 CI 15985 43
Red Yellow X
CI 16035
Red
40
Permitted colorants are named by their CI no. or other commonly used denomination. The lakes and salts of the permitted colorants, using substances not prohibited in Annex II or not regulated in Annex V of EU Cosmetic Regulation, are also permitted except if otherwise specified under the headline Other requirements. If there is no cross in the columns below the headline Field of application appropriate restrictions and conditions of use will be found under the headline Other requirements. Colorants whose number is preceded by the letter E in accordance with the EU Directive of 1962 concerning foodstuffs and colouring matters must fulfil the purity requirements laid down in those Directives. They continue to be subject to the general criteria set out in Annex III to the 1962 Directive concerning colouring matters where the letter E has been deleted there from. See also EU Cosmetic Regulation Annex IV for more information about the limitations and purity requirements in Europe for each colorant specified above. The insoluble Barium, Strontium and Zirconium lakes, salts and pigments of these colorants shall also be permitted. They must pass test for insolubility, which will be determined by the procedure laid down in Article 8 in the EU Cosmetic Regulation. This colorant has two different names as a certified colorant in USA. Therefore this colorant has two different criteria regarding purity, other requirements, limitations and field of application.
41
42
43
44
H&M Chemical Restrictions, 14 December 2009 Appendix C - Permitted Colorants in Cosmetic Products
46(52)
Colour
Field of Application41 1 2 3 4 X
Other Requirements42
Red
CI 19140 43
Yellow
X X X X
Also permitted in lip products at a maximum level of 3.0% in the finished product. And permitted in mouthwashes (including breath fresheners) and dentifrices. See also 21 CFR 74.2333. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. E 102. The aluminium lake of this colour is permanently permitted in cosmetics intended for use in the area of the eye. See also 21 CFR 74.2705. All other lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051 and 21 CFR 82.51. See also 21 CFR 73.2095. See also 21 CFR 74.2203. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051 and 21 CFR 82.51. See also 21 CFR 74.2104. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. The aluminium lake of this colour is permanently permitted in cosmetics intended for use in the area of the eye. See also 21 CFR 74.2101. All other lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051 and 21 CFR 82.51. Maximum level in the finished cosmetic product should not exceed 6%. See also 21 CFR 74.2707. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Maximum level in the finished cosmetic product should not exceed 6%. See also 21 CFR 74.2708. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Also permitted in lip products at a maximum level of 5.0% in the finished product. And permitted in mouthwashes and dentifrices that are to be ingested. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2255. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2321. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2322. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2327. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 2% 2-(bromo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2328. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 3% 2-(iodo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2260. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Not more than 1% 2-(6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid and 3% 2-(iodo-6-hydroxy-3-oxo-3H-xanthen-9-yl)benzoic acid. See also 21 CFR 74.2261. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. See also 21 CFR 74.2711.
CI 45350 44
Yellow
Yellow
CI 45370 43
Orange
CI 45380 43, 44
Red
Red
CI 45410 43,
44
Red
Red
CI 45425 44
Red
Red
CI 47000
Yellow
H&M Chemical Restrictions, 14 December 2009 Appendix C - Permitted Colorants in Cosmetic Products
47(52)
Colour
Field of Application41 1 2 X 3 4
Other Requirements42
Yellow
CI 59040
Green
X X X
E 104. See also 21 CFR 74.2710. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. Maximum level in the finished cosmetic product should not exceed 0.01%. See also 21 CFR 74.2208. See also 21 CFR 74.2602. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. See also 21 CFR 74.2602a. See also 21 CFR 74.2206. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. See also 21 CFR 74.2205. All lakes are permitted in all cosmetics, except those intended for use in the area of the eye, see 21 CFR 82.1051. See also 21 CFR 74.2330. All lakes are permitted as the ordinary colour, see 21 CFR 82.1051. E 160 b.See also 21 CFR 73.2030. E 160 a. See also 21 CFR 73.2095. See also 21 CFR 73.2329. E 120. See also 21 CFR 73.2087. Only to be used in cosmetic dentifrices at a maximum level of 0.1% and only together with*: Water. Glycerine. Sodium carboxymethylcellulose. Tetrasodium pyrophosphate. Sorbitol. Magnesium phosphate, tribasic. Calcium carbonate. Calcium phosphate, dibasic. Sodium N-lauroyl sarcosinate. Artificial sweeteners*. Flavours*. Preservatives* (see chapter 3.1.). E 140 and E 141. *See also 21 CFR 73.2125. E 173. See also 21 CFR 73.2645. See also 21 CFR 73.2725. See also 21 CFR 73.2162. See also 21 CFR 74.2052. See also 21 CFR 73.2646. See also 21 CFR 73.2647. E 172. See also 21 CFR 73.2250. E 172. See also 21 CFR 73.2250. E 172. See also 21 CFR 73.2250. E 172. See also 21 CFR 73.2250.
X X
X X
Free from cyanide ions. See also 21 CFR 73.2299. See also 21 CFR 73.2775. Permitted in fingernail polishes at a maximum level of 1.0% in the finished product. E 174. See also 21 CFR 73.2500. E 171. See also 21 CFR 73.2575. See also 21 CFR 73.2991. E 150. See also 21 CFR 73.2085. See also 21 CFR 73.2496.
X X X X
H&M Chemical Restrictions, 14 December 2009 Appendix C - Permitted Colorants in Cosmetic Products
48(52)
Substance/Requirement Index
1
1,1,1-Trichloroethane, 22, 37 1,4-Butanediol, 29, 40
Arsenic (As), 7, 9, 19, 32, 36 Azo Dyes & Pigments, 6, 8, 15, 30, 41, 45
B
Basic Red 9, 32 Basic Violet 14, 32 BBP, 16, 33, 36, 39 Benzene, 21, 29, 36, 40 Benzidine, 30 Benzo(a)anthracene, 33 Benzo(a)pyrene, 10, 33 Benzo(b)fluoranthene, 33 Benzo(e)pyrene, 33 Benzo(g,h,i)perylene, 34 Benzo(j)fluoranthene, 33 Benzo(k)fluoranthene, 34 Beta-sitosterol, 19, 36 Biotin, Vitamin B7/H, 37 Bis(2,3-dibromopropyl)phosphate, 31 Bisphenol-A, 9, 27, 30, 35, 38, 41, 44 Boron (B), 16, 17, 35, 44 BPA, 9, 27, 30, 35, 38 Butyl acrylate, 36 Butyl benzyl phthalate, 33, 36, 39
2
2-(2,4,5-Trichlorophenoxy) propionic acid, 33 2-(2,4,5-Trichlorophenoxy) propionyl compunds (2,4-D), 33 2,2-Bis(bromomethyl)-1,3-propanediol, 31, 42 2,4,5-Trichlorophenoxyacetic acid, 33 2,4,5-Trichlorophenoxyacetyl compounds (2,4,5-T), 33 2,4,5-Trimethylaniline, 30 2,4-Diaminoanisole, 30 2,4-Toluene diisocyanate (2,4 TDI), 32, 38 2,4-Toluenediamine, 30 2,4-Xylidine, 30 2,6-Toluene diisocyanate (2,6 TDI), 32, 38 2,6-Xylidine, 30 2-Amino-4-nitrotoluene, 30 2-Bromo-2-Nitropropane-1,3-Diol, 20, 36 2-Naphthylamine, 30 2-Nitro-1,4-Benzenediamine, 21, 36 2-Nitro-p-Phenylenediamine, 21, 36
C
Cadmium (Cd), 7, 9, 10, 11, 14, 15, 19, 25, 26, 27, 32, 35, 36, 38, 44 Caffeine, 22, 37 Camphor, 19, 36 Candida albicans, 23 Caprolactam, 16, 35, 44 Captafol, 32 Caramel, 48 Cationic Surfactants, 6, 12, 13, 30, 41 Chlordane, 32 Chlordecone (Kepon), 32 Chlordimerform, 32 Chlorinated Aromatic Hydrocarbons, 6, 8, 30, 41 Chlorinated Bleaching Agents, 29 Chlorobenzenes, 30 Chlorobenzilate, 32 Chlorofluorocarbon propellants, 19, 36 Chloronaphthalenes, 30 Chloroparaffines, 6, 8, 9, 30, 41 Chlorotoluenes, 30 Chloroxylenes, 30 Chromium (Cr), 7, 13, 15, 16, 17, 18, 19, 32, 35, 36, 38, 44 Chromium III (Cr3+), 15, 35, 44 Chromium VI (Cr6+), 6, 8, 11, 15, 18, 19, 25, 26, 31, 35, 36, 41, 44 Chrysene, 33 CI 10316, 46 CI 12085, 46 CI 14700, 46 CI 15510, 46 CI 15800, 46 CI 15850, 46 CI 15880, 46 CI 15985, 46 CI 16035, 46 CI 17200, 47 CI 19140, 47 CI 40800, 47 CI 42053, 47 CI 42090, 47 CI 45350, 47 CI 45370, 47 CI 45380, 47 CI 45410, 47 CI 45425, 47 CI 47000, 47
3
3,3-Dichlorobenzidine, 30 3,3-Dimethoxybenzidine (o-Dianisidine), 30 3,3-Dimethyl-4,4-diaminodiphenylmethane, 30 3,3-Dimethylbenzidine (o-Tolidine), 30
4
4,4-Diaminodiphenylmethane, 30 4,4methylenebis(2-chloraniline) (MOCA), 29, 40 4,4-Methylene-bis-(2-chloroaniline), 30 4,4-Oxydianiline, 30 4,4-Thiodianiline, 30 4-Aminodiphenyl, 30 4-Chloro-o-toluidine, 30 4-Nitro-1,2-Benzenediamine, 21, 36 4-Nitro-o-Phenylenediamine, 21, 36
A
Acenaphthene, 34 Acenaphthylene, 34 Acetanilide, 19, 36 Acid Red 26, 32 Acrylamide, 21, 36 Acrylates, 21 Adenosine, 19, 36 Aerobic Mesophyllic microorganisms, 23 Aldrine, 32 Alkylphenol Ethoxylates / Alkylphenols, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40 Aloe Barbadensis, 19, 36 Aloe Vera Gel, 19 Aluminium (Al), 15, 35, 44 Aminophylline, 22, 37 Anthracene, 34 Anthraquinone Glycosides, 19 Antibacterial, 13 Antimicrobial, 15, 45 Antimony (Sb), 7, 19, 32, 36 AP, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40, 41 APEO, 6, 8, 9, 12, 13, 27, 29, 30, 38, 40, 41 Apricot kernel oil, 21 Arachis Hypogaea Oil/Flour, 19, 36
49(52)
CI 47005, 48 CI 59040, 48 CI 60725, 48 CI 60730, 48 CI 61565, 48 CI 61570, 48 CI 73360, 48 CI 75120, 48 CI 75130, 48 CI 75170, 48 CI 75470, 48 CI 75810, 48 CI 77000, 48 CI 77007, 48 CI 77163, 48 CI 77288, 19, 36 CI 77289, 20, 36 CI 77400, 48 CI 77489, 48 CI 77491, 48 CI 77492, 48 CI 77499, 48 CI 77510, 48 CI 77742, 48 CI 77820, 48 CI 77891, 48 CI 77947, 48 Cinnamyl Anthranilate, 20, 36 Cobalt (Co), 7, 8, 14, 20, 32, 35, 36, 44 Cobalt Dichloride, 28 Colorants, 24, 46 Colour Fastness, 15 Copper (Cu), 7, 32 Crystal, 12 Cyclomethicone, 20, 36 Cyclopentasiloxane, 20, 36
Discolouration, 13, 28 Disperse Blue 1, 31 Disperse Blue 102, 31 Disperse Blue 106, 31 Disperse Blue 124, 31 Disperse Blue 26, 31 Disperse Blue 3, 31 Disperse Blue 35, 31 Disperse Blue 7, 31 Disperse Brown 1, 31 Disperse Dyes, 6, 31, 41 Disperse Orange 1, 31 Disperse Orange 11, 31 Disperse Orange 149, 31 Disperse Orange 3, 31 Disperse Orange 37, 31 Disperse Orange 76, 31 Disperse Red 1, 31 Disperse Red 11, 31 Disperse Red 17, 31 Disperse Yellow 1, 31 Disperse Yellow 23, 31 Disperse Yellow 3, 31 Disperse Yellow 39, 31 Disperse Yellow 49, 31 Disperse Yellow 9, 31 Distearyldimethyl ammouniumchloride (DSDMAC), 30 Ditallowdimethyl ammoniumchloride (DTDMAC), 30 DMDM Hydantoin, 20, 36 DMF, 10, 27, 29, 31, 38, 40 DMFu, 13, 28, 31, 38 DnDP, 16 DnOP, 16 DNOP, 33, 36, 39 DOT, 7, 9, 10, 12, 27, 32, 38 DTTB-(Timiperone), 33
D
DBP, 16, 33, 36, 39, 43 DBT, 7, 9, 10, 12, 27, 32, 38 DDD, 32 DDE, 32 DDT, 32 DEHP, 16, 33, 36, 39 DEP, 36 Di(ethylhexyl) phthalate, 33, 36, 39 Diazolidinyl Urea, 20, 36 Dibenzo(a,h)anthracene, 34 DIBP, 15, 45 Dibromochloropropane (DBCP), 33 Dibutyl phthalate, 33, 36, 39 Dibutyltin, 7, 9, 10, 12, 27, 32, 38 DIDP, 16, 33, 36, 39 Dieldrine, 7, 9, 33 Diethyl Phthalate, 21, 36 Dihydrogenated tallowdimethyl ammouniumchloride (DHTDMAC), 30 Di-isobutyl Phthalate, 15, 45 Di-iso-decyl phthalate, 33, 36, 39 Di-isononyl phthalate, 33, 36, 39 Diisopropylnaphthalene, 15, 35, 45 Dimethylacetamide (DMAC), 29, 40 Dimethylformamide, 10, 27, 29, 31, 38, 40, 41 Dimethylfumarate, 13, 28, 31, 38, 41 Di-n-octyl phthalate, 33, 36, 39 Dinoseb, 33 DINP, 16, 33, 36, 39 Dioctyltin, 7, 9, 10, 12, 27, 32, 38 Diphenylmethane diisocyanate (MDI), 32, 38 DIPN, 15, 45 Direct Black 38, 32 Direct Blue 6, 32 Direct Brown 95, 32 Direct Red 28, 32
E
Endosulphane, 33 Endrine, 33 Ethyl acrylate, 36 Ethylene dibromide, 33 Ethylene glycol monoethyl ether, 29, 40 Extractable Matter, 17, 45
F
Feather and Down, 12 Flame Retardants, 6, 8, 10, 12, 24, 31, 42 Fluoranthene, 34 Fluorene, 34 Folic acid, L-Glutamic acid, 37 Formaldehyde, 6, 8, 10, 11, 12, 15, 16, 17, 18, 20, 26, 28, 31, 35, 36, 38, 42, 44, 45 Fragrance Allergens, 20 Fragrance Oils, 23 Fumigation, 28
G
Glass, 12, 14, 26 Glues, 29 Glyoxal, 15, 35, 45 Good Manufacturing Practice (GMP), 14, 23
H
Hafnium (Hf), 17, 35, 44 Halogenated biphenyls, 33 Halogenated naphthalenes, 33 Halogenated terphenyls, 33 Heptachlor, 33 Heptachloroepoxide, 33
50(52)
Hexabromocyclododecane, 31, 42 Hexachlorobenzene, 33 Hexamethylene diisocyanate (HMDI), 32, 38 Hexamethylenetetramine, 18, 35, 44
I
Imidazolidinyl Urea, 20, 36 Indeno(1,2,3-c,d)pyrene, 34 Inhalation, 24 Isocyanates, 10, 12, 17, 27, 32, 38, 42, 45 Isodrin, 33 Isophorone diisocyanate (IPDI), 32, 38
Odour, 13, 28, 42 ODP, 16 o-Phenylphenol, 7, 9, 10, 27, 33, 38 OPP, 7, 9, 10, 27, 33, 38, 43 Organoleptic, 15, 45 Organotin Compounds, 7, 9, 10, 12, 17, 27, 32, 38, 42, 44, 45 Other Dyes, 6, 8, 32, 41 o-Toluidine, 30
P
PAH, 10, 16, 33, 43, 44, 45 p-Aminoazobenzene, 30, 41 Pantothenic acid, Vitamin B3/B5, 37 Parathion, 33 Parathion-methyl, 33 PBB, 25, 31 PBDE, 25, 31 PCB, 8, 9, 10, 15, 27, 34, 35, 39, 43, 45 p-Chloroaniline, 30 PCP, 7, 9, 10, 11, 15, 18, 26, 27, 33, 35, 38, 43, 45 p-Cresidine, 30 PCT, 8, 9, 10, 27, 34, 39 Pentachlorophenol, 7, 9, 10, 11, 15, 18, 26, 27, 33, 35, 38, 45 Perfluoro Compounds, 7, 9, 11, 26, 32, 38, 43 Perfluorooctane Sulfonate, 7, 9, 11, 26, 32, 38 Perfluorooctanoic Acid, 7, 9, 11, 18, 26, 32, 35, 38, 44 Peroxide, 16, 17, 18, 45 Perthane (Ethylane), 33 Pesticides, 7, 9, 32, 43 PFOA, 7, 9, 11, 18, 26, 32, 35, 38, 44 PFOS, 7, 9, 11, 26, 32, 38 pH, 7, 43 Phenanthrene, 34 Phenol, 29, 40 Phenolic Substances, 18, 44 Phenols, 7, 9, 10, 11, 26, 27, 33, 38, 43 Phenyl Salicylate, 21, 36 Phenylmercuric salts, 21, 36 Phosphamidone, 33 Phthalates, 7, 10, 12, 16, 21, 27, 33, 36, 39, 43, 44 Plasticizers, 24 Polyaromatic Hydrocarbons, 10, 33, 43, 44, 45 Polybrominated Biphenyls, 25, 31 Polybrominated Diphenyl Ethers, 25, 31 Polychlorinated Biphenyls, 8, 9, 10, 15, 27, 34, 35, 39, 45 Polychlorinated Compounds, 34, 39 Polychlorinated Triphenyls, 8, 9, 10, 27, 34, 39 Polyvinylchloride, 8, 10, 11, 27, 34, 39 Polyvinylidenchloride, 8, 10, 11, 27, 34, 39 p-Phenylenediamine, 32 Preservatives, 24 Primary Aromatic Amines, 15, 16, 17, 18, 24, 44, 45 Primary container/package, 28 Product Information files (PI-files), 23 Prunus Armeniaca Kernel Oil, 21, 36 Pseudomonas aeruginosa, 23 PVC, 8, 10, 11, 27, 34, 39, 43 Pyrene, 34 Pyrrolizidine Alkaloids, 21
K
Kathon CG, 20, 36 Kelevane, 33
L
Lead (Pb), 7, 9, 10, 11, 12, 14, 15, 17, 20, 25, 26, 27, 32, 35, 36, 38, 44 Lindane (-Hexachlorcyclohexane), 33 Lithium (Li), 18, 35, 44
M
Medium chained (MCCPs) C14-C17, 6, 8, 9, 30 Melaleuca Alternifolia Oil, 20, 36 Melamine, 16, 35, 44 Mercury (Hg), 7, 9, 10, 11, 15, 20, 25, 26, 27, 32, 35, 36, 38, 44 Metal containers/packages, 26 Metals, 7, 8, 9, 10, 11, 13, 24, 26, 27, 32, 38, 42, 44 Metamidophos, 33 Methoxychlor, 33 Methyl acrylate, 36 Methyl Salicylate, 21, 36 Methylchloroisothiazolinone, 20, 36 Methylene chloride, 29, 40 Methylisothiazolinone, 20, 36 Methylsilanol, 22, 37 Mica, 48 Microbiological Quality, 23 Migration, 15, 16, 17, 18, 24, 44, 45 Mineral Oils, 13, 42 Mirex, 33 Monocrotophos, 33 Monomers, 24 Monomethyldibromodiphenylmethane, 33 Monomethyldichlorodiphenylmethane, 33 Monomethyltetrachlorodiphenylmethane, 33 Mould, 13, 28, 42
N
Naphthalene, 34 n-Hexane, 29, 40 Niacin, Vitamin B5, 37 Nickel (Ni), 7, 8, 11, 15, 21, 32, 35, 36, 44 Nitrosamines, 21, 36 Nonylphenol (NP), 6, 8, 9, 12, 27, 30, 38, 40 Nonylphenol Ethoxylates (NPE), 6, 8, 9, 12, 21, 27, 30, 36, 38, 40
Q
Quintozene, 33
O
o-Aminoazotoluene, 30 o-Anisidine, 30 Octamethylcyclotetrasiloxane, 7, 32, 42 Octylphenol (OP), 6, 8, 9, 12, 27, 30, 38, 40 Octylphenol Ethoxylates (OPE), 6, 8, 9, 12, 21, 27, 30, 36, 38, 40
R
REACH SVHC, 13, 14, 24, 25, 28 Residual Monomers, 21, 36 Residual Solvents, 21, 36 Retinol (Vitamin A), 21, 36 Retinyl Palmitate (Vitamin A), 21, 36
51(52)
S
Salicylic Acid, 21, 36 Sand Blasting, 29 Sensory, 14, 44 Short chained (SCCPs) C10-C13, 6, 8, 9, 30 Solvent Yellow 1, 32 Solvent Yellow 2, 32 Solvent Yellow 3, 32 Solvents, 24, 29, 40, 43 Stability test, 23 Staphylococcus aureus, 23 Strobane, 33 Sucralfate, 21, 36 Symphytum Officinale (Comfrey), 21, 37
-Hexachlorcyclohexane, 33
-Hexachlorcyclohexane, 33
-Hexachlorcyclohexane, 33
T
Talc, 21, 37 TBT, 32, 38 TCyHT, 32, 38 Tea Tree Oil, 20 TeCP, 7, 9, 10, 27, 33, 38, 43 Telodrin (Isobenzan), 33 Tetrabromobisphenol A (TBBP A), 31 Tetrachloroethylene (PERC), 29, 40 Tetrachloromethane, 29, 40 Tetrachlorophenol, 7, 9, 10, 27, 33, 38 Tetramethylxylene diisocyanate (TMXDI), 32, 38 Theobromine, 22, 37 Theophylline, 22, 37 Thimerosal, 21, 37 Thioctic Acid, 22, 37 Toluene, 21, 22, 29, 36, 37, 40 TOT, 32, 38 Toxaphene (Camphechlorine), 33 TPhT, 32, 38 TPT, 32, 38 Tributyltin, 32, 38 Trichloroethylene (TRIS), 29, 40 Triclosan, 8, 10, 22, 27, 34, 37, 39, 43 Tricyclohexyltin, 32, 38 Tri-o-cresyl phosphate, 31, 42 Trioctyltin, 32, 38 Triphenyl phosphate (TPhP), 31 Triphenyltin, 32, 38 Tripropyltin, 32, 38 Tris(1,3-dichloroisopropyl)phosphate (TDCP), 31 Tris(2,3-dibromopropyl)phosphate (TRIS), 31 Tris(2-chloroethyl)phosphate (TCEP), 31 Tris-(aziridinyl)-phosphineoxide (TEPA), 31
V,W
Vanadium (V), 16, 17, 35, 44 Viscum Album, 22, 37 Vitamin B1, thiamine, 37 Vitamin B12, 37 Vitamin B2, riboflavin, 37 Vitamin B6, adermine, 37 Vitamin E, tocopherol, 37 Vitamin K, 37 Vitamins, 22, 37 Volatile Organic Matter (VOM), 16, 17, 18, 45
X
Xanthin derivatives, 22
Z
Zinc (Zn), 16, 17, 18, 35, 44 Zirconium (Zr), 17, 35, 44
52(52)