Gravimetric analysis 1. A 0.

5662 g sample of an ionic compound containing chloride ions and an unknown metal is dissolved in water and treated with excess AgNO3. If 1.0882 g of AgCl precipitates forms, what is the % by mass of Cl in the original compound? A. 24.72 B. 26.90 C. 47.51 D. 53.49 Stoichiometry 2. The depletion of ozone in the stratosphere has been a matter of great concerns among students in recent years. It is believed that ozone can react with nitric oxide that is discharged from the high altitude jet plane, the SST. If 0.740 g of O3 reacts with 0.670 g of NO, how many grams of
NO2 will be produced? (b) Which compound is the limiting reagent? (c) Calculate the number of grams of the excess reagent remaining at the end of the reaction. A. 0.7086g, O3, 0.0069mol B. 1.0260g, NO, 0.0069mol C. 0.8076g, O3, 0.0069mol D. 1.0620g, NO, 0.0069mol

Empirical formula 3. A sample of compound of Cl and O reacts with an excess of H2 to give 0.233g of HCl and 0.403g H2O. Determine the empirical formula of the compound. A. Cl2O7 ClO3.34 B. C. Cl7O2 D. ClO Gravimetric analysis 4. The ion that cannot be precipitated by both HCl and H2S is A. Pb2+ B. Ag+ C. Cu+ D. Sn2+ Acid 5. the compound that is not a Lewis acid is:

A. BF3

B. AlCl3 C. BeCl2 D. SnCl4 Quantum numbers 6. Which one of the following sets of quantum numbers(n,l,ml, ms) represents as impossible arrangement? A. 3,2,-2,1/2 B. 4,0,0,1/2 C. 3,2,-3,1/2 D. 5,3,0,-1/2 Titration 7. A supply of NaOH is known to contain the contaminants NaCl and MgCl2A 4.955 g sample of this material is dissolved and diluted to 500.00 mL with water. A 20.00 mL sample of this solution is titrated with 22.26 mL of a 0.1989 M solution of HCl. What percentage of the original sample is NaOH? Assume that none of the contaminants react with HCl. A. 89.35% B. 98.35% C. 10.65% D. 65.10% Formula mass 8. 5.2g of compound X was dissolved in 250cm3 of water. A 25.0cm3portion of the solution required 20.0cm3 of a 0.20 mol dm-3 of potassium dichromate (VI) solution in a titration. The reacting ratio is: 5 1Cr2O7 2 What is the formula mass, Mr, of X ? A. 28 B. 27 C. 26 D. 25 Back titration 9. A student was asked to determine the concentration of ammonia, a volatile substance, in a commercially available cloudy ammonia solution used for cleaning. First the student pipetted 25.00mL of the cloudy ammonia solution into a 250.0mL conical flask. 50.00mL of 0.100M HCl(aq) was immediately added to the conical flask which reacted with the ammonia in solution. The excess (unreacted) HCl was then titrated with 0.050M Na2CO3(aq). 21.50mL of Na2CO3(aq) was required. Calculate the concentration of the ammonia in the cloudy ammonia solution. A. 0.411

B. 0.114 C. 0.00114 D. 0.0411 Chemical equilibrium 10. A ten fold increase in pressure on the reaction N2(g) + 3H2(g) 2NH3(g) at equilibrium results in _____________ in Kp. A. 10 times increase B. 5 times increase C. Cannot be determined D. No change