BTAE 404
Recommended Books:
1) 2)
Kohli P.L., Automotive Electrical Equipment ", Tata McGraw-Hill. W.H. Crouse, Automobile Electrical Equipment ", McGraw Hill Book Co. Inc.
3)
Lecture by : Jagwant Singh Assistant Professor Department of Automobile Engineering Gulzar College of Engineering , Khanna
Storage Battery
Introduction 1
A battery is a device that converts chemical energy into electrical energy. 2. A cell is the small basic electrochemical unit. 3. A battery consists of one or more cells connected in series, or in parallel, or both. 4. Batteries, in general, are classified as:
1.
Zinc-manganese dioxide, alkaline cells are primary batteries. Lead-acid batteries are secondary batteries. Advanced secondary batteries include nickel metal hydride and lithium ion.
Introduction 2
The storage battery is the heart of the automobile electric circuit . It is an electrochemical device for storing electricity. A vehicle battery has several important functions, which are as follows:
i.
It must operate the starting motor, ignition system, electronic fuel injection system, and other electrical devices for the engine during engine cranking and starting. It must supply ALL of the electrical power for the vehicle when the engine is not running. It must help the charging system provide electricity when current demands are above the output limit of the charging system. It must act as a capacitor (voltage stabilizer) that smooth current flow through the electrical system. It must store energy (electricity) for extended periods.
ii.
iii.
iv.
v.
The ability to power the starter to enable minimum starting speed under very cold conditions. 2. The expected use of the battery for running accessories when the engine is not running.
2.
1. 2. 3. 4. 5. 6.
Lead-acid batteries
Principle
The lead acid battery comprises of two chemically dissimilar lead based plates in a dilute sulphuric acid solution. The positive plate contains lead dioxide PbO2, and the negative plate pure lead in a spongy form. When immersed in dilute sulphuric acid, the nominal electric potential between the two plates is 2 volt. This voltage is universal for all lead acid batteries.
Construction
The basic construction of a nominal 12 V lead-acid battery consists of six cells connected in series. Each cell, producing about 2V, is housed in an individual compartment within a polypropylene case or similar other case. The grids, connecting strips and the battery posts are made from a lead alloy. For many years this was lead antimony (PbSb) but this has now been largely replaced by lead calcium (PbCa). These newer materials cause less gassing of the electrolyte when the battery is fully charged. This has been one of the main reasons why sealed batteries became feasible, as water loss is considerably reduced.
Construction
Plates:
The leadacid cell can be demonstrated using sheet lead plates for the two electrodes. The positive plates are the chocolate brown color of lead dioxide, and the negative plates are the slate gray of "spongy" lead at the time of manufacture.
Separators:
Separators between the positive and negative plates prevent short-circuit through physical Separators obstruct the flow of ions between the plates and increase the internal resistance of the cell. Wood, rubber, glass fiber mat, cellulose, and PVC or polyethylene plastic have been used to make separators.
Working
During discharge, the sulphite ions in the electrolyte interact with the negative and positive plates, forming lead sulphate on both. The loss of sulphite ions in the electrolyte reduces its specific gravity in proportion Group to the charge delivered. During recharge, the electric current converts the plates back to their charged state, and the sulphate back to sulphuric acid. The specific gravity of the electrolyte rises again as a result.
Working
Battery Rating
In simple terms, the characteristics or rating of a particular battery are determined by how much current it can produce and how long it can sustain. This current.
The rate at which a battery can produce current is determined by the speed of the chemical reaction. This is determined by a number of factors:
1. 2. 3. 4.
The actual current supplied therefore determines the overall capacity of a battery. The rating of a battery has to specify the current output and the time.
AH
This is unit used to describes how much current the battery is able to supply for how much time . For example, a battery quoted as being 44Ah (ampere-hour) will be able, if fully charged, to supply 2.2 A for 20 hours before being completely discharged (cell voltage below 1.75 V is taken as battery discharge condition).
Reserve capacity
A system used now on all new batteries is Reserve Capacity. This is quoted as a time in minutes for which the battery will supply 25 A at 25 C to a final voltage of 1.75 V per cell. This is used to give an indication of how long the battery could run the car if the charging system was not working. Typically, a 44 Ah battery will have a reserve capacity of about 60 minutes.
It is also termed as Short Time. This Rating is the number of minutes that a battery will deliver 300A of current at a starting temperature of -18C before the cell voltage fall below 1.0 V . It indicates the ability of battery during cold weather starting. A 100 Ah Battery may deliver 300 A for a period of 3.6 min, at -18C
Battery Efficiency
The efficiency of a battery can be calculated in two ways, either as the ampere-hour efficiency or the power efficiency.
Battery Efficiency =
x100
It may be noted that a battery is far more efficiency when discharged at a slow rate then when it is discharge rapidly
The lower the temperature ,the lower will be the battery efficiency, this is because when the battery is being discharge rapidly
Self-discharge
All batteries suffer from self-discharge, which means that even without an external circuit the state of charge is reduced. The rate of discharge is of the order of 0.21% of the Ah capacity per day. This increases with temperature and the age of the battery. It is caused by two factors.
1.
The chemical process inside the battery changes due to the material of the grids forming short circuit due to Impurities in the electrolyte. A leakage current across the top of the battery, particularly if it is in a poor state of cleanliness, also contributes to the self-discharge.
2.
Specific Gravity
Specific gravity is the ratio of the weight of a solution to the weight of an equal volume of water at a specified temperature. Specific gravity is used as an indicator of the state of charge of a cell or battery. However, specific gravity measurements cannot determine a battery's capacity. During discharge, the specific gravity decreases linearly with the amperehours discharged. Cell open circuit voltage = Specific gravity + 0.845
Battery hydrometer
The hydrometer works on the principle that a floating body displaces a volume of liquid whose weight is equal to its own, the lighter the liquid (that is, the less its specific gravity), the deeper the body sinks because a greater amount of liquid is required to equal the body's weight.
Battery Tests
Battery leakage test Battery terminal test Battery voltage test Cell voltage test Battery drain test
The cell voltage test will let you know if the battery is discharged or defective. Like a hydrometer cell test, if the voltage reading on one or more cells is .2 volts or more lower than the other cells, the battery must be replaced. To perform a cell voltage test use a low voltage reading voltmeter with special cadmium (acid resistant metal) tips. Insert the tips into each cell, starting at one end of the battery and work your way to the other. Test each cell carefully. If the cells are low, but equal, recharging usually will restore the battery. If cell voltage readings vary more than .2 volts, the battery is BAD.
For example, if the battery is rated at 60 amp-hours, test the battery at 180 amps (60 x 3 = 180). Connect the battery load tester. Turn the control knob until the ammeter reads the correct load for your battery. After checking the battery charge and finding the amp load value, you are ready to test battery output. Make sure that the tester is connected properly. Turn the load control knob until the ammeter reads the correct load for your battery. Hold the load for 15 seconds. Next, read the voltmeter while the load is applied. Then turn the load control completely off so the battery will not be discharged. If the voltmeter reads 9.5 volts or more at room temperature, the battery is good. If the battery reads below 9.5 volts at room temperature, battery performance is poor.
It is a meter with a high wattage resistor connected parallel with the meter that drains power from the battery while it is measuring the voltage it is used to test the condition of the battery if the condition is good there will not be a large voltage drop while testing the battery
There are several methods for charging batteries, only direct current is used with each method. If only alternating current is available, a rectifier must be used to convert to direct current. The two principal methods of charging are (1) constant current and (2) constant voltage (constant potential). Constant current charging is be used on a single battery or a number of batteries in series. Constant voltage charging is used with batteries connected in parallel. (A parallel circuit has more than one path between the two source terminals, a series circuit is a one-path circuit). You should know both methods.
Alkaline batteries1
Lead-acid batteries traditionally required a considerable amount of servicing to keep them in good condition, although this is not now the case with the advent of sealed and maintenance-free batteries. However, when a battery is required to withstand a high rate of charge and discharge on a regular basis, or is left in a state of disuse for long periods, the lead-acid cell is not ideal. Alkaline cells on the other hand require minimum maintenance and are far better able to withstand electrical abuse such as heavy discharge and over-charging. The disadvantages of alkaline batteries are that they are more bulky, have lower energy efficiency and are more expensive than a lead-acid equivalent. When the lifetime of the battery and servicing requirements are considered, the extra initial cost is worth it for some applications.
1. 2. 3.
Alkaline batteries used for vehicle applications are generally the nickel-cadmium type. The main components of the nickel-cadmium or NiCad cell for vehicle use are as follows: positive plate nickel hydrate (NiOOH); negative plate cadmium (Cd); electrolyte potassium hydroxide (KOH) and water (H2O).
Alkaline batteries2
The process of charging involves the oxygen moving from the negative plate to the positive plate, and the reverse when discharging. When fully charged, the negative plate becomes pure cadmium and the positive plate becomes nickel hydrate. A chemical equation to represent this reaction is given: 2NiOOH + Cd + 2H 2O + KOH 2Ni(OH)2 + CdO 2 + KOH
Alkaline batteries3
These batteries do not suffer from over-charging because once the cadmium oxide has changed to cadmium, no further reaction can take place. The cell voltage of a fully charged cell is 1.4V but this falls rapidly to 1.3 V as soon as discharge starts. The cell is taken as discharged at a cell voltage of 1.1V in these type of batteries.