WX (2005-2006 \ Y W W)

New Scheme ( For Students studied during the Year 2005-2006 )

Code No.

34-NS

Total No. of Questions : 39 ]

[ Total No. of Printed Pages : 15

March / April, 2006

CHEMISTRY
( Kannada and English Versions )

( New Syllabus )
Time : 3 Hours ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O.

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR x@ 5
40 - D Y D1 10 D2

B, C

Y XR x@
iv)

Y XRR W

10

O.

WY XR O R .

- A
:

i)

ii)

XR Y WY OR
. X XR O.
10 1 = 10

10

XRR O .

1.

O Y X y ?

2.

Fe3+

Fe2+

E PO. x ?
36

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Code No. 34-NS

3.

X
Q, X x@
O ?

4.

Q } Y ?

5.

X ?

6.

(y) R ?

7.

] T xY ?
| |X| W |X|.

8.

R VL SR
Y Y} |J OR .

9.

E P xY-@R .

10.

Y J Y zW J ?

- B
:

i)

O XRR O.

ii)

X XR R O.
10 2 = 20

11.

X TWy Y R . } .

12.

Y R .
36

3
13.

X X

Code No. 34-NS

30

Q, X

PR .

14.

W W Y} R .

15.

ZX X ? } .

16.

} ? .

17.

xX R x zWR .

18.

X (J) } O xdy } WWR

.

19.

Y x |
}R :
i)

CH3

ii)

NO2

20.

|X R O ?

21.

y O yY ?

} x.

22.

{ ? } x.
36

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Code No. 34-NS

- C
I.

xY XR O :

23. a)

2 5 = 10

XK R Q } XW
R .

b)

24. a)

b)

YW x\R , Z x]R NY x
R .

Z O QM R x.

WX

yQ

O N Q O yO. y x.

25. a)

b)

II.

b)

]R W xR , Xx] R
.

CO NH Cl Cl IUPAC .

(
3 ) 4
2

xY XR O :

26. a)

WXy

3 5 = 15

W | R .

{W R } .

36

5
27. a)

b)
28. a)

SN 1

Code No. 34-NS

X (yW) ? R W|

X Y} .

-D ( )

XxJ R .

b)

"}N # ? XW ?

c)

Y W ?

x X R :

29. a)

i)

yW] V| O yW] {| XR @
J

ii)

L X]

iii)

| X

iv)

X XyY O X TWy Y
X

b)

III.

R ?

xY XR O :
30. a)

LCAO

R .
b)

()

3 5 = 15

WWR .

(-) X
2

36

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Code No. 34-NS

31. a)

pH 46

002 M

XR

500

..

yYx@ y | ||

XWR .

b)

32. a)

Error!= 18 10Error! )

xR :

i)

\ (X|J)

ii)

QMR O
@ xR .

b)

X J ZX O
NY

33. a)

b)

115 kJ

b)

O. Q P

27C

Error! )

R .

X X R .

XxYy

VY

_O. y x.
34. a)

( G )

yY

X X xd O yR
. WR x.

y X{W ?

36

Code No. 34-NS

- D
D 1
IV.

xY XR O :
35. a)

1 10 = 10

|| UR VJ Q M}
Y XR .

b)

W d ?

xYW|Y W dR

c)

WW X ? } x.

d)

298 K

NY

1M CuSO4

1M ZnSO4

X Y O

X Y XR

Wx W R
0

( e.m.f. )

[ EZn=076VO ECu=+034V]
36. a)

b)

c)

] QMR , WX T|Y
X{ O y R .

i)

] XR } .

ii)

yYR R .

27C

NY

10%

Yx X OR

.
Error!molError!)
d)

^ WZY} QM WR
.

36

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Code No. 34-NS

8
D 2

IV.

xY XR O :
37. a)

b)

38.

|-|XR

2 5 = 10

|X

xX x\R .

| T| O | XY N
}R XR .

39.

xJ X
R

( Standard )

5
( 1 dm3

xX|

XR

R . Y
X R x.

36

Code No. 34-NS

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks, Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In Part D D 1

carries 10 marks and D 2

carries

10marks. Each question of D2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the 10 questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

Out of carbon and zinc which is a stronger reducing agent ?

2.

Why is Fe3+ ion more stable than Fe2+

3.

If the rate of the reaction is independent of concentration of the reactant,

ion ?

what is the order of the reaction ?

4.

Which noble gas is not adsorbed by charcoal ?

5.

What is hydronium ion ?

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Code No. 34-NS

10

6.

What is the only factor on which the colligative property value depends ?

7.

Between potassium nitrate and aluminium nitrate which one is required in

minimum concentration to coagulate arsenious sulphide sol ?

8.

Which is the organic product obtained when methyl magnesium iodide

reacts with formaldehyde followed by acid hydrolysis ?

9.

Name the least stable cycloalkane.

10. How many amino acid units are present in insulin ?

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. Justify that concentrated sulphuric acid is a good dehydrating agent with
example.
12. Calculate the bond order in oxygen molecule.
13. The time for half-life of a first order reaction is found to be 30 mins. What
is the rate constant of the reaction ?
14. Define Faradays first law of electrolysis.
15. What is a spontaneous reaction ? Explain with an example.
16. What is Tyndall effect ? Explain.
17. Calculate the number of particles present in the unit cell of BCC.

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Code No. 34-NS

18. Distinguish between inductive effect and electromeric effect.

19. Explain the effect of the following substituents on the acidity of phenol :
i)

CH3

group

ii)

NO2

group.

20. How is ethanamine prepared from ethane nitrile ?

21. What are reducing and non-reducing sugars ? Give one example each.
22. What are biological messengers ? Give an example.

PART C
I.

Answer any two of the following :

23. a)

2 5 = 10

How are noble gases separated by Dewars charcoal adsorption

method ?

b)

With the help of the Ellinghams diagram, explain why silver

oxide can be thermodynamically decomposed at relatively lower
temperature.

24. a)

Give

the

postulates

2
of

compounds.
b)

Werners

theory

of

coordination
3

Copper (I) compounds are white and diamagnetic whereas

Copper(II) compounds are coloured and paramagnetic. Give
reason.

2
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Code No. 34-NS

25. a)

b)

II.

12

Describe

the

manufacture

of

sodium

hydroxide

Nelsonscell.

Write the IUPAC name of CO( NH3) 4Cl2 Cl.

Answer any three of the following :

26. a)
b)
27. a)

b)
28. a)

using

3 5 = 15

Discuss the molecular orbital structure of benzene.

Explain geometrical isomerism with an example.

What is SN 1 mechanism ? Explain it using hydrolysis t-butyl

bromide.

Give any two uses of aniline.

Write the Howarths ring structure for -D ( ) fructopyranose.

2

b)

Define the term iodine value of an oil. Mention its significance.

2

c)
29. a)

What is isoelectric point of amino acids ?

Write the equations for the following reactions :

i)

Mixture of calcium formate and calcium benzoate is dry

distilled

ii)

Acetaldehyde is treated with hydroxyl amine

iii)

Acetone is treated with hydrogen cyanide

iv)

Phenol is heated with a mixture of conc. nitric acid and

conc. sulphuric acid.

b)

How do you convert Methane to Ethane ?

36

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Code No. 34-NS

III. Answer any three of the following :

30. a)

b)
31. a)

3 5 = 15

How are the molecular orbitals formed by the linear combination

of atomic orbitals ?

Distinguish between ideal and non-ideal solutions.

Calculate the mass of

potassium acetate that should be

dissolved in 500 cm3 of 002 M acetic acid solution to prepare

a buffer solution of pH 46.

b)

32. a)

Given Ka = 18 105 .

Define the following terms :

i)

Protective colloid

ii)

Gold number.

Discuss the application of the principles of solubility product

with respect to the analysis of II and IV group basic radicals.

b)

The standard free energy change ( G ) for a reaction is

115 kJ at 27C. Calculate the equilibrium constant ( Kp ).

33. a)

Acetic acid very weakly dissociates in presence of hydrochloric

acid. Give reason.

34. a)

b)

Derive an expression for the velocity constant of a first order

reaction.

b)

With diagram, explain the construction and working of standard

hydrogen electrode. Give two limitations.

Define radius ratio in ionic crystals.

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Code No. 34-NS

14
PART D
D 1

IV. Answer any one of the following :

35. a)

1 10 = 10

Explain the chemical reactions that occur during the extraction

of iron from haematite by smelting in a blast furnace.

b)

What is angle strain ? Calculate the angle strain in cyclobutane.

3

c)

What is a pseudounimolecular reaction ? Give an example.

d)

Calculate the e.m.f.

of

the

cell

prepared

Zn|1M ZnSO4 and Cu|1M CuSO4

0

Given EZn = 076 V and E Cu

36. a)

by

combining

at 298 K.

= + 034 V .

On the basis of Valence bond theory, explain hybridisation,

geometrical shape and magnetic property in Cuprammonium

b)

c)

d)

sulphate.

i)

Explain Perkins reaction with an example.

ii)

How is acetic acid prepared from ethanol ?

Calculate the osmotic pressure of 10% solution of glucose

at27C. Given R = 8314 JK1 mol1 .

Give any two demerits of Arrhenius theory of ionisation.

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Code No. 34-NS

D 2
V.

Answer any two of the following :

37. a)

2 5 = 10

Explain the preparation of m-dinitrobenzene from nitrobenzene.

3

b)

Describe Acrolein test.

38. Describe an experiment to show the effect of temperature on the rate

of the reaction between potassium persulphate and potassium
iodide.

39. Describe the experiment to determine the mass of Mohrs salt

crystals in one dm3

solution by

using standard potassium

dichromate solution. Give the equation for the reaction involved.

36

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