Code No.

Total No. of Questions : 39 ]

34

Total No. of Printed Pages : 16 ]

March, 2010

CHEMISTRY
( Kannada and English Versions )
Time : 3 Hours 15 Minutes ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O.

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR
x@ 5 40 - D Y D 1 10
D2 Y XR x@ 5 10 O.

iv)

WY XR O R .

B, C

Y XRR W

- A
:

i)

ii)

XR Y WY OR
. X XR O.
10 1 = 10

10

XRR O.

y R O ?

1.

Zn2+

2.

S Q } Y XK }
Y R .
[ Turn over

Code No. 34
3.

Y UR QM

600C

NY

X R .
4.

WXR pH = 1 XY

25C

NY Q.

WX J ?
5.

X } 2. ?

6.

x () R QM R . y x.

7.

x Y W SR
( CH3COO) 2 Ca

(B)

R .

@J

NH2OH

8.

X XR .

9.

yd Y_ ""xdy## }R .

10. CH3 N CH3

IUPAC

R .

CH3

- B
:

i)

O XRR O.

ii)

X XR R O.
10 2 = 20

11.

Wy x] } YW zx\R . YW
x\ Wy x]R R .

Code No. 34

12.

R } .

13.

X TWy Y xY O | xX|
X O ? x.

14.

W xX XR .

15.

{W R y R .

16.

W ? }N W Z ?

17. SN 1

18. 25C

Y X KO O }

SN 2

X W WWR x.

100 kJ

Q,

Y X P PR @ .
19.

xY x R . TY X
Z zW J ?

20.

zWR WzW. O J zW J ?

21. i)

ii)

J ] O \ x R .
X ?
n+

22. M1 | M1

n+

M2

M2

WZy xR O.

xY x X O x XR .
[ Turn over

Code No. 34

- C
I.

xY XR O :

23. a)

b)

24. a)

2 5 = 10

R S ?

J x R } .

QMR , WX
O { yR .

b)

25. a)

b)

O W XK XR
XWO ?

x@ ""yd QM##R X .

W (R)

} x.

II.

xY XR O :

3 5 = 15

T XXR .

b)

|XY ?

c)

W-@R @ |X

26. a)

R .

X
1

5
27. a)
b)

c)
28. a)

Code No. 34

x ? xY|Y x R @ .

y Y O y Y \ YR,
y xJ .

J ?

x }R
:
i)

-X

Y LR y]y Y

O @ X
|R Xy

X W ?

ii)
b)
29. a)

b)

xR ?
i)

ii)

y]y YR @ |X

Yx 5 X] R
XR x.

III.

xY XR O :
30. a)

1
3 5 = 15

K WX O yR X
.

b)

WOR

3
20

T| X

J }_O ?
( XW

= 3286)

[ Turn over

Code No. 34
31. a)

X X

x_.

b)

32. a)

20%

60%

c)

33. a)

""J{## ? }R x.

ZL XW X XR
2

] R . ] R
X X WR ?

XWY ?

W } O QM ZR
XWY W OxR .

b)

34. a)

b)

x_ @ .

R .
b)

WzW :
i)

ii)

y {

X X X SJR SR.
25C

Y O

xXR (

238

.. ,

100X

= 342)

.X Y |

O xR @ .

Code No. 34

- D
D 1
IV.

xY XR O :
35. a)

i)

Cr3+

ii)

Sc3+

( zW

1 10 = 10

zW
= 24)

21)

, Y N

O x ?

Y yd WR .

b)

YQ R XW ?

c)

i)

pH = 57

PR ||

O y Y SOR .
(y Y Ka

36. a)

= 18 105

ii)

|XR WzW.

i)

X TWy Y | X

O .
ii)

b)

|| UR QM XR
.

i)

X XR .

ii)

Y P_ yd Y

c)

i)

yd J ?

^ WZW QM XKR
.

ii)

25C NY
X

pH

0125

R .

001 M

y Y
2
[ Turn over

Code No. 34

8
D 2

V.

xY XR O :
37. a)

p-X|R

2 5 = 10

XY

R .
b)

|R x\R x. x\
?

38.

| T| O | XY
X N }R XR .

39.

XY T|
R K | xX| XR
R . Y X R x.

Code No. 34

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks. Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In Part D D 1

carries 10 marks and D 2

carries

10marks. Each question of D2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the 10 questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

What type of magnetic behaviour is shown by Zn2+

2.

Name the noble gas which is not adsorbed by coconut shell charcoal in

ion ?

Dewars charcoal adsorption method.

3.

Write the equation for the chemical reaction taking place at 600C in the
extraction of iron by blast furnace.

4.

The hydrogen electrode is dipped in a solution of pH = 1 at 25C. What is

the potential of the electrode ?

[ Turn over

Code No. 34

10

5.

Temperature coefficient of a reaction is 2. What does it mean ?

6.

Alum is used in the clarification of the muddy water. Give reason.

7.

Name the end product ( B ) of the following reaction :

( CH3COO)

Ca

drydistillation

NH2OH

8.

Write the structural formula of proline.

9.

Name an electromeric effect which involves partial displacement of

electrons.

10. Give the IUPAC name of

CH3 N CH3
CH3

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. Draw Ellingham diagram for the formation of mercuric oxide. With the
help of Ellingham diagram, suggest a method for the reduction of mercuric
oxide.
12. Explain linkage isomerism with an example.
13. How does concentrated sulphuric acid react with a mixture of sodium
chloride and potassium dichromate crystals ? Give the equation.

11

Code No. 34

14. Write Haworths structure for sucrose.

15. Mention the conditions for a molecule to show geometrical isomerism.

16. Define iodine value. What is the significance of iodine value of an oil ?

17. Give any two differences between SN 1 and SN 2 mechanisms.

18. The standard free energy change of a chemical reaction is 100 kJ at 25C.
Calculate the equilibrium constant of the chemical reaction at the same
temperature.

19. Sketch the unit cell structure of

caesium chloride.

What is the

coordination number of each ion in the crystal ?

20. Define the term Gold number. What are the Gold numbers of gelatin and
starch?

21. i)

ii)

State Raoults law of relative lowering of vapour pressure.

What is an ideal solution ?

n+

22. A galvanic cell is represented as M1 | M1

n+

M2

M2 .

Write the half-cell reactions and cell reaction for the above cell.

[ Turn over

Code No. 34

12
PART C

I.

Answer any two of the following questions :

23. a)
b)
24. a)

2 5 = 10

How is ammonia manufactured by Habers process ?

Explain with an example Nernsts distribution law.

With the help of valence bond theory, explain the hybridisation

and geometrical shape of cuprammonium ion.

b)

25. a)
b)
II.

How is a mixture of noble gases isolated from air by Ramsay

and Rayleigh method ?

Explain, with a diagram, electron gas theory of metallic bond.

What is a ligand ? Give an example of a bidentate ligand.

Answer any three of the following questions :

26. a)

3 5 = 15

Explain the mechanism of sulphonation of benzene.

b)

What are triglycerides ?

c)

Write chemical equation with conditions for the formation of

alkane nitriles from haloalkanes.

27. a)

What is angle strain ? Calculate the angle strain in cyclopentane.

2

b)

c)

Giving reason, explain the relative acidity of ethanoic acid and

methanoic acid.

What is a peptide bond ?

13
28. a)

Code No. 34

Explain with equations how to convert

i)

aldehyde containing no -hydrogen to a mixture of sodium

salt of the carboxylic acid and alcohol

ii)

b)

29. a)

b)

ketone into hydrocarbon.

What is denaturation of proteins ?

How are the following prepared ?

i)

Ethanol from methanol

ii)

Carboxylic acid from alkane nitrile.

Give a chemical reaction to show that a molecule of glucose

contains five hydroxyl groups.

III. Answer any three of the following questions :

30. a)

3 5 = 15

With a neat diagram, explain the construction and working of

standard hydrogen electrode.

b)

Calculate the mass of zinc metal deposited from zinc sulphate

solution by passing a current of 4 amperes for 20 minutes.

( Equivalent mass of zinc = 3286 )

[ Turn over

Code No. 34
31. a)

14
A first order reaction takes 5 seconds for 20% completion.
Calculate the time required for 60% completion of the reaction.
3

b)
32. a)

What is peptization ? Give one example.

Explain Ostwalds isolation method for the determination of the

order of a reaction.

b)

c)
33. a)

Write Gibbs equation. How do you predict the feasibility of a

reaction using Gibbs equation ?

What are Lewis bases ?

Explain the application of common ion effect and principles of

solubility product in the precipitation of second group basic
radicals.

b)

34. a)

Define :
i)

Osmotic pressure

ii)

Space lattice.

Derive an expression for the velocity constant of a first order

reaction.

b)

Calculate the lowering of vapour pressure caused by addition of

100g of sucrose ( molecular mass = 342 ) to 1 kg of water if the
vapour pressure of water at 25C is 238 mm of mercury.

15

Code No. 34

PART D
D 1
IV. Answer any one of the following :
35. a)

i)

Among

Sc3+

1 10 = 10
Atomic

number

21

and

Cr3+ (Atomic number = 24 ) , which ion is coloured and

ii)

why ?

Write the electronic configuration of oxygen molecule.

b)

How is phenol isolated from coal tar ?

c)

i)

What is the ratio of concentration of sodium acetate to

acetic acid while preparing a buffer solution of pH = 57 ?

( Kaofaceticacidis18 10

36. a)

ii)

Define the term entropy.

i)

Explain with equation how concentrated sulphuric acid

reacts with potassium bromide.

ii)

Name the flux used

in the extraction of

haematite.
b)

2
iron from
1

i)

Explain with equation of Hoffmanns bromamide reaction. 2

ii)

How many electrons are present in the delocalised

electron cloud in a benzene molecule ?

c)

i)

Write any two merits of Arrhenius theory of electrolytic

dissociation.

ii)

Calculate the pH of a 001 M solution of acetic acid if the

degree of dissociation at 25C is 0125.

2
[ Turn over

Code No. 34

16
D 2

V.

Answer any two of the following :

37. a)

b)

Explain

the

laboratory

2 5 = 10
method

of

preparation

of

p-bromoacetanilide from acetanilide.

Give a test to detect ketoses. What is the name of the test ?

38. Describe an experiment to show the effect of temperature on the rate

of a reaction between potassium persulphate and potassium iodide.
5
39. Describe the experiment to determine the mass of ferrous ammonium
sulphate crystals present in one

dm3

of its solution by using

standard potassium dichromate solution. Give the equation for the

reaction involved.