2008 CropProtection Newsroom Brochures CropProtectionProductRange

Functional Chemicals Division
Product Range
Crop Protection
Edition 2008
Auxiliaries for Crop Protection Formulations

Product range anionic emulsifiers
Introduction
emulsifiers
Alkylbenzene sulfonates
adjuvants
24
Fatty alcohol ethoxylates Special emulsifiers Tristyrylphenol (TSP) ethoxylates Castor oil ethoxylates EO/PO block copolymers EO/PO alkoxylation products Nonylphenol ethoxylates Tributylphenol ethoxylates
disPersing agents
6 10 10 12 12 14 16 18
Amine ethoxylates Special adjuvants

blends
26 28
Emulsifier blends Performance blends Clariant matched pairs

other Products
30 30 30
Anionic condensation products Other dispersing agents Tristyrylphenol (TSP) ethoxylates, phosphated
20 20 22
Sulfosuccinates Solvents, crystallization inhibitors Glymes glycol diethers Polyethylene glycols
32 32 34 34
introduction
clariant is a market leader in formulation inerts, serving the agrochemical industry for several decades. our goal is to make agrochemical formulations more efficient and safe for the mutual benefit of manufacturers, consumers and the environment. We are continuously expanding our product range with new surfactants, focusing on safe and sustainable chemistry. clariant offers a complete range of additives for each formulation type and problem. this comprehensive brochure gives an overview of the various products by function. the following table shows the different product groups and their main applications by formulation type.
the aim of this publication is to support our customers in selecting the most suitable clariant product for their formulation needs. it contains the basic information, brand name, composition, active substance content, appearance, hlb value, basic specification, important physical data, and registration information. this information is not intended to replace technical data sheets or safety data sheets.
sYstematic overvieW of the most imPortant Product grouPs and their trade names
ProDuCt rANgE
Description Page
ProDuCt grouP
EC SC SE EW ME OD SL WG, SP WG, WP genapol C genapol LA genapol o genapol oX genapol t genapol uD
EC = Emulsifiable concentrate
Coconut fatty alcohol ethoxylates Lauryl fatty alcohol ethoxylates Oleyl alcohol ethoxylates Alcohol ethoxylates based on C12/C15 oxo alcohol C16/C18 fatty alcohol ethoxylates Alcohol ethoxylates based on C11 oxo alcohol Iso-tridecyl alcohol ethoxylates Iso-tridecyl alcohol ethoxylates methyl ethers Tristyryl phenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alcohol alkoxylates Nonylphenol ethoxylates Tri-sec.-butylphenol ethoxylates Dispersing agents of different types Anionic emulsifiers (Ca alkylbenzene sulfonates) Coconut fatty amine ethoxylates Oleyl amine ethoxylates Tallow amine ethoxylates Adjuvants and bio-enhancers Fatty acid dimethylamides
6 6 6 6 8 8 8 10 10 12 12 14 16 18 20 / 22 24 26 26 26 28 32
Fatty alcohol ethoxylates tristyrylphenol ethoxylates Castor oil ethoxylates Eo/Po block copolymers Eo/Po alcohol alkoxylates Nonylphenol ethoxylates tributylphenol ethoxylates Dispersing agents tSP ethoxylates, phosphated Alkylbenzene sulfonates Fatty amine ethoxylates Nonionic / anionic blends Sulfosuccinates Solvents / Crystallization inhibitors
genapol X genapol XM Emulsogen tS Emulsogen EL genapol PF, ED genapol EP

SC = Suspension concentrate SE = Suspo-emulsion EW = Emulsion (oil-in-water) ME = Microemulsion OD = Oil dispersion SL = Soluble concentrate WG, SP = Water-soluble granules, powder WG, WP = Water-dispersible granules, powder
Arkopal N Sapogenat t Dispersogen Phenylsulfonat, Calsogen genamin C genamin o genamin t Synergen genagen
Nonylphenol / nonylphenol ethoxylate Directive 2003/53/EC in general all products mentioned in the brochure are free of nonylphenols and nonylphenol ethoxylates. exceptions are marked as nPe-containing in the comments column and their use is restricted according to directive 2003/53/ec effective from 17th january 2005. see also: http://eur-lex.europa.eu/pri/en/oj/dat/2003/l_178/l_17820030717en00240027.pdf
NPE = nonylphenol ethoxylate, APE = alkylphenol ethoxylate
rEACH according to regulation (ec) no. 1907/2006 (reach), the manufacture or import of chemical substances in volumes exceeding 1 ton per year must be registered at the european chemicals agency (echa) in helsinki. reach registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a reach-substance will be restricted to those uses evaluated in its registration dossier. the reach process starts with preregistration (1st june 2008 until 1st december 2008), which ensures the availability of preregistered substances to the registration date. the date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to reach requirements, pre-register all substances manufactured by clariant functional chemicals division in the eu or imported in the eu, that are relevant for the products listed in this brochure. however, no guarantee can be given that clariant will offer all listed products in the future, particularly over the 11 year phase of the reach implementation. if reach registration requirements lead to unacceptable costs, clariant will contact its customers to find an appropriate solution.
genapol, emulsogen, arkopal, sapogenat, dispersogen, calsogen, genamin, synergen, genagen are registered trademarks of clariant.
in this brochure a selection of clariants most important alkoxylates for crop Protection applications is shown. other types which are not mentioned here may be available locally or on request as well as aqueous emulsifier solutions of certain products (typically 80% or 90% active content) with improved handling properties.
emulsifiers
FAttY ALCoHoL EtHoXYLAtES

Composition Active cont. (%); Appearance 100; liquid 100; liquid 100; pasty, wax-like 100; pasty 100; pasty, wax-like 100; pasty, wax-like Cloud Point (C) ca. 73,0 ca. 50,5 ca. 90,5 ca. 67,0 ca. 77,0 ca. 60,0 mPas (50C) ca. 54,0 ca. 65,0 ca. 57,0 ca. 64,0 ca. 86,0 ca. 48,5 mg KOH/g ca. 68,5 ca. 80,5 ca. 50,0 ca. 58,0 ca. 72,0 ca. 75,0 ca. 64,0 ca. 73,0 ca. 77,0 ca. 63,5
A: 1% a.i. in water B: 5g / 25g / 25% BDG C: 1g / 100ml / 10% NaCl
Method B
HLB (calc.) 10 12 14
EPA *
Comments
genapol C 050 genapol C 070 genapol C 100 genapol C 120 genapol C 200 genapol C 250
Coconut fatty alcohol polyglycol ether with 5 EO Coconut fatty alcohol polyglycol ether with 7 EO Coconut fatty alcohol polyglycol ether with 10 EO Coconut fatty alcohol polyglycol ether with 12 EO Coconut fatty alcohol polyglycol ether with 20 EO Coconut fatty alcohol polyglycol ether with 25 EO
910, 930 910, 930 910, 930 910, 930 910, 930 910, 930
Genapol C 100 also shows adjuvant properties and enhances cuticular penetration (for details see Pesticide Formulations and Application Systems: 20th volume, ASTM STP 1400).
14,5 16,5 17
Product specified by viscosity.
genapol LA 030 genapol LA 040 genapol LA 070 genapol LA 080 genapol LA 100 genapol LA 230
C12/14 fatty alcohol polyglycol ether with 3 EO C12/14 fatty alcohol polyglycol ether with 4 EO C12/14 fatty alcohol polyglycol ether with 7 EO C12/14 fatty alcohol polyglycol ether with 8 EO C12/14 fatty alcohol polyglycol ether with 10 EO C12/14 fatty alcohol polyglycol ether with 23 EO
100; liquid 100; liquid 100; liquid 100; liquid 100; pasty 100; waxy solid
8 9 12 13 14 17
910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 Product specified by OH number.
genapol o 050 genapol o 080 genapol o 100 genapol o 120 genapol o 150 genapol o 200 genapol oX 050 genapol oX 070 genapol oX 080 genapol oX 100
Oleyl alcohol polyglycol ether with 5 EO Oleyl alcohol polyglycol ether with 8 EO Oleyl alcohol polyglycol ether with 10 EO Oleyl alcohol polyglycol ether with 12 EO Oleyl alcohol polyglycol ether with 15 EO Oleyl alcohol polyglycol ether with 20 EO C12/C15 oxo alcohol polyglycol ether with 5 EO C12/C15 oxo alcohol polyglycol ether with 7 EO C12/C15 oxo alcohol polyglycol ether with 8 EO C12/C15 oxo alcohol polyglycol ether with 10 EO
100; liquid 100; liquid-pasty 100; pasty, wax-like 100; pasty 100; wax-like 100; wax-like 100; liquid 100; liquid-pasty 100; liquid-pasty 100; pasty
9 11 12 13 14 15,5 10 12 13 14
910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930
* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx
FAttY ALCoHoL EtHoXYLAtES

Composition Active cont. (%); Appearance 100; powder Cloud Point (C) ca. 60,0 mPas (70C) ca. 105,0 mPas (70C) ca. 60,0 ca. 68,0 ca. 53,5 ca. 53,5 ca. 63,5 ca. 63,5 ca. 40,0 ca. 60,5 ca. 65,5 ca. 75,5 ca. 63,5 ca. 83,0 ca. 70,0
Method B
HLB (calc.) 16
EPA *
Comments
genapol t 250 Powder
C16/C18 fatty alcohol polyglycol ether with 25 EO
910, 930
Product specified by viscosity.
emulsifiers
genapol t 500 Powder genapol t 800 Powder genapol uD 050 genapol uD 070 genapol uD 079 genapol uD 080 genapol uD 110 genapol X 030 genapol X 050 genapol X 060 genapol X 080 genapol X 090 genapol X 100 genapol X 150
C16/C18 fatty alcohol polyglycol ether with 50 EO C16/C18 fatty alcohol polyglycol ether with 80 EO C11 oxo alcohol polyglycol ether with 5 EO C11 oxo alcohol polyglycol ether with 7 EO C11 oxo alcohol polyglycol ether with 7 EO C11 oxo alcohol polyglycol ether with 8 EO C11 oxo alcohol polyglycol ether with 11 EO Iso-tridecyl alcohol polyglycol ether with 3 EO Iso-tridecyl alcohol polyglycol ether with 5 EO Iso-tridecyl alcohol polyglycol ether with 6 EO Iso-tridecyl alcohol polyglycol ether with 8 EO Iso-tridecyl alcohol polyglycol ether with 9 EO Iso-tridecyl alcohol polyglycol ether with 10 EO Iso-tridecyl alcohol polyglycol ether with 15 EO
100; powder 100; powder 100; liquid 100; liquid 90; liquid 100; liquid 100; pasty 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; wax-like
18 19 11 13 13 13 15 7 10 11 13 13 14 15
910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930 910, 930
Product specified by dropping point.
Besides their high emulsifying performance, the iso-tridecanol based Genapol X types are also excellent wetting agents.
FAttY ALKoHoL EtHoXYLAtES

Composition Active cont. (%); Appearance ca. 100; liquid ca. 100; liquid ca. 100; liquid Cloud Point (C) ca. 70,5 ca. 67,0 ca. 86,0 A Method B C HLB (calc.) 9 9 11 EPA * Comments
Emulsogen LP Emulsogen M Emulsogen MC
Oleyl alcohol polyglycol ether Oleyl alcohol polyglycol ether Oleyl alcohol polyglycol ether
910, 930 910, 930 910, 930
Emulsogen LP and Emulsogen M are preferred emulsifiers for mineral oils. Both are characterized by a low pour point (ca. 0C) and remain homogeneous down to ca. 12C. Emulsogen MC is mainly used as an emulsifier for vegetable oils and leads to improved low temperature stability of the formulation.
EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx
emulsifiers
SPECIAL EMuLSIFIErS
Composition Active cont. (%); Appearance 100; liquid 100; wax-like OH number (mg KOH/g) max. 11 HLB (calc.) 11 EPA * Comments
genapol XM 060
Iso-tridecyl alcohol ethoxylate methyl ether with 6 EO
not r.
Methylation of iso-tridecanol ethoxylates leads to the Genapol XM types which combine emulsifying as well as wetting power and chemical inertness, e.g. for hydrolytically sensitive active ingredients.
genapol XM 150
Iso-tridecyl alcohol ethoxylate methyl ether with 15 EO
max. 7
15
not r.
tSP-EtHoXYLAtES
Composition Active cont. (%); Appearance 100; liquid 100; liquid 100; liquid-pasty 100; wax-like 100; wax-like 100; wax 100; wax Cloud Point (C) ca. 67,0 A Method B C HLB (calc.) 10 EPA * Comments
Emulsogen tS 100
2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 10 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 16 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 20 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 29 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 40 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 54 EO 2,4,6-Tri(1-phenylethyl)-phenol polyglycol ether with 60 EO
920
Emulsogen tS 160
ca. 60,0
13
920
Emulsogen tS 200
ca. 57,5
13,5
920
Emulsogen tS 290
ca. 68,0
15
920
Emulsogen tS 400
ca. 71,0
17
920
Emulsogen tS 540
ca. 73,0
17
920
Emulsogen tS 600
ca. 19 mg KOH/g
17,5
920
Product specified by OH number.
10
11
CAStor oIL EtHoXYLAtES

Composition Active cont. (%); Appearance 100; liquid 100; liquid 100; liquid 100; pasty 100; pasty Saponification number (mg KOH/g) 87,0 97,0 Cloud point ca. 72,5C (1% in 20% acetic acid) 64,0 69,0 60,0 64,0 49,0 53,0 HLB (calc.) 10,5 12,5 13,5 14 15 EPA *
Emulsogen EL 200
Castor oil ethoxylate with 20 EO Castor oil ethoxylate with 30 EO Castor oil ethoxylate with 36 EO Castor oil ethoxylate with 40 EO Castor oil ethoxylate with 54 EO
960 960 960 960 960

emulsifiers
Emulsogen EL 300 Emulsogen EL 360 Emulsogen EL 400 Emulsogen EL 540
Eo / Po BLoCK CoPoLYMErS
Composition Active cont. (%); Appearance 100; pasty 100; wax-like 100; wax-like Cloud Point (C) ca. 72,9 ca. 69,0 ca. 775 mPas (70C)* ca. 35,4 ca. 56,8 ca. 67,8 A Method B C HLB (calc.) 6 17,5 17,5 EPA* Comments
Emulsogen V 1816 Emulsogen 4084 genapol V 5008
EO/PO block copolymer EO/PO block copolymer EO/PO/EO block polymer
960 960 960
genapol PF 10 genapol PF 20 genapol PF 40
Block copolymer of EO/PO containing 10% EO Block copolymer of EO/PO containing 20% EO Block copolymer of EO/PO containing 40% EO
100; liquid 100; liquid 100; liquid
13,5 14 16
960 960 960
Low molecular weight EO/POs typically have a molecular weight below 1000 g/mol. These surfactant molecules are small and flexible and can quickly adhere to newly formed surfaces. Medium molecular weight EO/POs typically cover molecular weights from about 1000 3000 g/mol. As a consequence of the increased molecular weight, these products tend to exhibit higher viscosity and/or waxier consistency. Their main application fields are as emulsifiers and dispersants in EC and SC formulations. High molecular weight EO/ POs have molecular weights typically above 3000 g/mol and are mostly waxy, only a few being liquid. They are used as co-emulsifiers or dispersants in EC or SC formulations.
genapol PF 80 Powder
Block copolymer of EO/PO containing 80% EO
100; powder
ca. 1200 mPas (70C)* ca. 1200 mPas (70C)* ca. 1200 mPas (70C)* ca. 73,0 (10% a.m. in water) ca. 53,6 ca. 28,6
19
960
genapol PF 80
100; wax-like
19
960
genapol PF 80 FP
100; powder
19
960
Genapol PF 80 FP is a finely powdered version of Genapol PF 80.
genapol ED 1616
Ethylene diamine EO/PO block copolymer
100; liquid
16
960
genapol ED 3030 genapol ED 3060
Ethylene diamine EO/PO block copolymer Ethylene diamine EO/PO block copolymer
100; viscous liquid 100; viscous liquid
16 15
960 960
* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx * Product specified by viscosity.
12
13
emulsifiers
Eo / Po ALKoXYLAtIoN ProDuCtS
Composition Active cont. (%); Appearance 100; wax-like 100; wax-like 100; liquid 100; liquid 100; viscous liquid 100; viscous liquid 100; viscous liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid Cloud Point (C) ca. 67,0 ca. 85,0 ca. 73,5 ca. 29,0 ca. 72,5 ca. 72,5 ca. 72,5 ca. 36,5 ca. 51,0 ca. 59,0 ca. 26,0 ca. 44,0 ca. 32,0 ca. 40,0 ca. 30,0 ca. 40,5
Method B
HLB (calc.) 11 11 16,5 14 16 16 15,5 11 12,5 13,5 9 12 10 10,5 11 12
EPA*
Comments
Emulsogen V 2436 Emulsogen 3510 Emulsogen EP 4901 genapol EP 4103 Emulsogen NPA 200 Emulsogen ItA 200 Emulsogen tBA 200 genapol EP 0244 genapol EP 0858 genapol EP 1182 genapol EP 2424 genapol EP 2464 genapol EP 2544 genapol EP 2552 genapol EP 2564 genapol EP 2584
Fatty alcohol alkoxylate n-Butanol alkoxylate n-Butanol alkoxylate n-Butanol alkoxylate Nonylphenol alkoxylate Iso-tridecyl alcohol alkoxylate Tributylphenol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate Fatty alcohol alkoxylate
not reg. 960 960 960 not reg. 960 not reg. not reg. not reg. 910 not reg. 910, 930 920 not reg. 920 920
Emulsogen EP 4901 is a liquefied alternative to Emulsogen 3510 for easier handling.
NPE-containing. Emulsogen ITA 200 is an APE-free alternative to Emulsogen NPA 200 and Emulsogen TBA 200.
Genapol EP 1182 exhibits excellent spreading/wetting properties and a very good cold water solubility.
14
15
emulsifiers
NoNYLPHENoL EtHoXYLAtES
Composition Active cont. (%); Appearance 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid-pasty 100; pasty 100; pasty 100; pasty Cloud Point (C) ca. 37,0 A Method B C HLB (calc.) 9 EPA* NPEcontaining Comments
Arkopal N 040
Nonylphenol polyglycol ether with 4 EO
910 930
Arkopal N 060
ca. 62,0
11
910 930
Arkopal N 080
ca. 33,0
12,5
910 930
Arkopal N 090
ca. 53,0
13
910 930
Arkopal N 100
ca. 63,5
13,5
910 930
NPE replacements: As substitutes for Arkopal N 090 and N 100 we recommend ethoxylates based on synthetic alcohols, e.g. Genapol OX 070, 080, 100 Genapol UD 070, 080 Genapol X 080.
Arkopal N 110
ca. 72,5
14
910 930
Arkopal N 130
ca. 84,5
15
910 930
Arkopal N 150
ca. 62,0
15,5
930
Arkopal N 200
ca. 71,5
16,5
not reg.
Arkopal N 230
ca. 74,0
17,0
not reg.
Arkopal N 300
ca. 76,5
18
910 930
16
17
emulsifiers
trIButYLPHENoL EtHoXYLAtES
Composition Active cont. (%); Appearance 100; liquid 100; liquid 100; liquid 100; liquid 100; liquid-pasty 100; wax-like 100; wax-like 100; wax-like Cloud Point (C) ca. 27,5 A Method B C HLB (calc.) 8 EPA* Comments
Sapogenat t 040
Tri-sec-butylphenol polyglycol ether with 4 EO
not reg.
Sapogenat t 060
ca. 54,7
10
not reg.
Sapogenat t 080
ca. 67,0
11
not reg.
4-Nonylphenol ethoxylates (NPEs) and 4-Octylphenol ethoxylates (OPEs) as well as the underlying phenols are listed in the EU SEC (2004) Document as substances with evidence of endocrinedisrupting effects (Category 1) whereas 2,4,6-Tri-sec.-butylphenol as well as its ethoxylated derivatives (Sapogenat T types) are not listed. Based on the structural elements of known endocrine disrupters (EDs), it is likely that the endocrine-disrupting effect of alkylphenols and derived ethoxylates is associated with - a para-substituted alkyl group on the aromatic ring with at least 3 carbon atoms - no polyalkylation on the aromatic ring Supporting evidence was obtained using three different in vitro receptor binding tests with Sapogenat T 130 and 2,4,6-Tri-sec.- butylphenol in which both molecules did NOT show endocrine- disrupting effects in any of these tests. In these test models the known EDs estradiol and 4-Octylphenol clearly showed endocrine-disrupting effects demonstrating the suitability of the test models. Based on available scientific facts published in literature as well as on the results from 3 different in vitro tests it can be concluded in a weight of evidence approach that it is unlikely that 2,4,6-Tri-sec.-butylphenol and the ethoxylated derivatives (Sapogenat T types) exhibit endocrine-disrupting effects.
Sapogenat t 110
ca. 43,0
13
not reg.
Sapogenat t 130
ca. 63,0
14
not reg.
Sapogenat t 180
ca. 62,5
15
not reg.
Sapogenat t 300
ca.70 mPas (70C)* ca. 140 mPas (70C)*
17
not reg.
Sapogenat t 500
18
not reg.
* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx * Product specified by viscosity.
18
19
disPersing agents
ANIoNIC CoNDENSAtIoN ProDuCtS

Composition Active cont. (%); Appearance ca. 80; powder ca. 35; liquid ca. 35; liquid ca. 62; powder Type Water solubility EPA* Comments
Dispersogen 1494
Sodium salt of a cresol-formaldehyde condensation product Sodium salt of a cresol-formaldehyde condensation product Sodium salt of a cresol-formaldehyde condensation product Combination of anionic surfactants mixed with a carrier
anionic
yes
not reg.
Dispersogen 1494 liq.
anionic
yes
not reg.
rapidaminreserve CL
anionic
yes
not reg.
Dispersogen SI
anionic
no
910, (920), 930
otHEr DISPErSINg AgENtS

Composition Active cont. (%); Appearance ca. 60-65; powder ca. 100; pasty ca. 80; liquid ca. 70; liquid ca. 100; powder ca. 97; wax Type Water solubility EPA* Comments
Hostapon tPHC
Fatty acid methyl tauride sodium salt
anionic
yes
910, 930, (950)
All products displayed under Other dispersing agents are APE-free. Clariant has recently extended its range of dispersing agents for agro formulations with new and environmentally friendly products. These dispersing agents are polymers and are available as highly concentrated products.
Dispersogen PSL 100
Polyacrylate graft copolymer
non-ionic
yes
not reg.
Dispersogen 4387
Anionic polymeric ester
anionic
yes
not reg.
Dispersogen S-r
Nonionic polyester
non-ionic
yes
not reg.
Dispersogen S-rA
Anionic modified polyester
anionic
yes
not reg.
Dispersing Agent 3618
Phosphate ester of EO-PO-EO blockpolymer
anionic
yes
920, 960
20
21
disPersing agents
tSP-EtHoXYLAtES, PHoSPHAtED
Composition Active cont. (%); Appearance ca. 97; liquid ca. 96; viscous liquid ca. 60; viscous liquid ca. 97,5; viscous liquid ca. 97,5; viscous liquid ca. 60; liquid ca. 85; viscous liquid Type Water solubility EPA* Comments
Dispersogen LFH
2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester ammonium salt 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester triethanolamine salt 2,4,6-Tri-(1-phenylethyl)-phenol polyglycol ether phosphoric acid ester ammonium salt
anionic
yes
920
Dispersogen LFS
anionic
yes
not reg.
Dispersogen LFA *
anionic
yes
920
Phosphated TSP ethoxylates are anionic emulsifiers and dispersing agents. Dispersogen TP and LF types differ in their degree of ethoxylation (TP: 16 moles EO, LF: 20 moles EO) and their mono-/diester ratio. The LF types are stand-alone products that offer better electrolyte stability compared to the TP types as well as higher dispersing power at low dispersion viscosity.
Dispersogen tP 160
anionic
yes
920
Dispersogen tP 160 t
anionic
yes
not reg.
Dispersogen tP 166 t *
anionic
yes
not reg.
Dispersogen tP 169 A *
anionic
yes
920
* Development product; samples available
22
23
ALKYLBENzENE SuLFoNAtES
Composition Solvent Type Active content (%); Appearance ca. 70; viscous liquid ca. 62; viscous liquid ca. 70; viscous liquid ca. 40+10; liquid ca. 40+10; liquid ca. 40+10; liquid ca. 40+10; liquid ca. 50+7; liquid ca. 58; viscous liquid ca. 58; viscous liquid Flash point (C) 33C EPA* Water content K.F. (%) max. 0,5 Comments
Phenylsulfonat CA
iso-C12 alkyl benzene sulfonate calcium salt
Isobutanol
branched
910, (920), 930 910, (920), 930 910, (920), 930 910, 930
anionic emulsifiers alkYlbenzene sulfonates
The ND types (Naphthalene Depleted) are alkylbenzene sulfonates in a solvent with a low content of naphthalene (max. 0,9 %).
Phenylsulfonat CA 62
Isobutanol
branched
33C
max. 0,5
Phenylsulfonat CAL
n-C12 alkyl benzene sulfonate calcium salt
Isobutanol
linear
33C
max. 0,5
Calsogen Ar 100
Solvesso 200
branched
> 100C
max. 0,5
Calsogen Ar 100 ND
Solvesso 200 ND
branched
> 100C
910, 930
max. 0,5
Calsogen Ar 62 ND
Solvesso 150
branched
ca. 62C
910, 930
max. 0,5
Calsogen ArL 100 ND
Solvesso 200 ND
linear
> 100C
910, 930
max. 0,5
Calsogen ArL 48
Solvesso 100
linear
ca. 48C
910, 930
max. 0,5
Calsogen EH
2-Ethylhexanol
branched
> 60C
910, (920), 930 910, (920), 930
max. 0,5
Calsogen 4814
2-Ethylhexanol
linear
> 60C
max. 0,5
Solvesso is a registered trademark of Exxon.
24
25
AMINE EtHoXYLAtES
Composition Appearance Alkaline number (mg KOH/g) 190 205 EPA* Comments
genamin C 020
Cocos fatty amine ethoxylate with 2 EO
liquid
920
Clariant offers a broad range of fatty amine ethoxylates based on different fatty amines and with different degrees of ethoxylation. For amine ethoxylates containing a solubilizer, refer to Special Adjuvants.
genamin C 050
liquid
129 137
920
genamin C 100
liquid
85 89
920
genamin C 150
liquid
63 67
920
adjuvants
genamin C 200
liquid
50 53
920
genamin o 050
Oleyl amine ethoxylate with 5 EO
liquid
111 117
920
genamin o 200
Oleyl amine ethoxylate with 20 EO
liquid
47 57
920
genamin t 050
Tallow fatty amine ethoxylate with 5 EO
liquid
110 118
920
genamin t 100
liquid
77 81
920
genamin t 150
liquid
60 61
920
genamin t 200
liquid
47 50
920
genamin t 250
pasty, wax-like
39 42
920
26
27
SPECIAL ADJuVANtS
Composition Appearance EPA* Application Comments
genamin 267
Amine ethoxylate containing a solubilizer
liquid
910, 920, 930 910, 920, 930 910, 930
Formulated adjuvant for Glyphosate SL formulations, easily dissolves in water without gelation. Formulated adjuvant for Glyphosate SL formulations.
genamin 700
Amine ethoxylate containing a solubilizer
liquid
Special Adjuvants are tailor-made products for dedicated types of active ingredients with a proven performance as bio-enhancers. Benefits are formulations with the highest efficacy, minimizing the usage level of pesticides saving costs and increasing environmental compatibility. Please enquire for additional information about our Special Adjuvants range or guide recipes.
Synergen gL 5
Copolymer of glycerol, esterified
viscous liquid
Proprietary polyglycerol-based adjuvant which is derived from natural starting materials, showing excellent performance with Glyphosate. Environmentally friendly; very favorable tox / ecotox properties, no hazard labeling required. Due to its structure, it also has excellent dispersing properties. Adjuvant for Glyphosate.
Synergen g2D
Aqueous solution of an amphoteric adjuvant
liquid
not reg.
Synergen 9903
Aqueous solution of an amphoteric adjuvant
liquid
not reg.
Adjuvant for Glyphosate.
Synergen HY
Aqueous solution of a quaternary ammonium salt Specialty silicone
liquid
not reg.
Adjuvant for Glyphosate.
Synergen SW-100
liquid
910
Silicone-based superwetter, enhances spreading and penetration. Suitable as tank-mix or in-can adjuvant. Proprietary polyglycerol-based adjuvant for bentazone with very favorable tox / ecotox properties, no hazard labeling required. For further information see our Newsletter on Bentazone. Proprietary polyglycerol-based adjuvant with increased hydrophobic character and very good dispersing properties. Suitable as tank-mix or in-can adjuvant. Efficient adjuvant blend for fungicides (e.g. Tebuconazole and Azoxystrobin). Proven performance as tank-mix or in-can adjuvant. Proprietary high performance adjuvant blend for Glyphosate highload formulations, efficient at low dosages. Suitable as tank-mix or in-can adjuvant. Proprietary adjuvant for Glyphosate solid formulations.
Synergen BB
liquid
910, 930
adjuvants
Synergen IB 775
liquid
910, 930
Synergen KN
Adjuvant blend
liquid
910, 920, 930
Synergen g-HL
Amine alkoxylates containing a solubilizer
liquid
not reg.
Synergen g-S
Amine alkoxylate
solid
not reg.
28
29
EMuLSIFIEr BLENDS
Description Active content (%); Appearance ca. 70,5; viscous liquid ca. 78,0; viscous liquid ca. 85; liquid EPA* APE-free Comments
Emulsogen IC
Blend of anionic and nonionic surfactants
blends
910, (920), 930 910, (920), 930 910, (920), 930, 960 910, (920), 930, 960 910, (920), 930 not reg. not reg.
Emulsogen ICL
Emulsogen It
Emulsogen ItL
ca. 80; liquid
Emulsogen t
ca. 100; liquid
Emulsogen T is an excellent emulsifier for natural oils.
Emulsogen PSI 100 Emulsogen PSI B
Blend of anionic and nonionic surfactants Blend of anionic and nonionic surfactants
ca. 100; liquid ca. 80; liquid
PErForMANCE BLENDS
Description Active content (%); Appearance ca. 90; liquid EPA* NPE-free Comments
Emulsogen B 350
Blend of anionic and nonionic surfactants in organic solvent for Endosulfan EC Blend of anionic and nonionic surfactants in organic solvent for Tebuconazole EC Blend of anionic and nonionic surfactants in organic solvent for Propiconazole EC Blend of anionic and nonionic surfactants in organic solvent for Methyl-Parathion Blend of anionic and nonionic surfactants for Paraquat
not reg.
Emulsogen tB 200
ca. 25; liquid
920
Clariants Performance Blends include everything which is needed for easy and successful formulation: A well balanced combination of emulsifiers and adjuvants. Performance Blends are available for specific formulations of major active ingredients. Please enquire for Performance Blends for additional formulations.
Emulsogen P 250
ca. 52; liquid
920
Emulsogen MPB Synergen PW
ca. 74; liquid ca. 46; liquid
910, (920), 930, 960 910 930
CLArIANt MAtCHED PAIrS

Description Active content (%); Appearance ca. 100; liquid EPA* APE-free Comments
Emulsogen MP 1
910, (920), 930, 960 910, (920), 930, 960 910, (920), 930
Emulsogen MP 2
ca. 100; liquid
The matched pairs emulsifiers are a versatile, APE-free system containing only a few components for multiple active ingredient solutions. Matched pairs are emulsifier blends with optimized performance. So numerous active ingredients can be formulated with only a few (up to three) blends, saving space and time. Guide recipes for formulations are available on request.
Emulsogen MP 3
ca. 100; liquid
30
31
other Products
SuLFoSuCCINAtES
Composition Active content (%); Appearance ca. 50; liquid ca. 60; liquid ca. 64; liquid ca. 58; liquid EPA* Water content K.F. (% ) ca. 48,5 Flash point (C) > 100 Comments
Emulsogen SF 8
Aqueous solution of sodium dioctyl sulfosuccinate Sodium dioctyl sulfosuccinate in aromatic solvent, naphthalene-depleted Sodium dioctyl sulfosuccinate in aromatic solvent Sodium dioctyl sulfosuccinate in white oil
910, 930
Synergen W 02
910, 930
< 0,1
> 100
Dioctyl sulfosuccinates are versatile surfactants, having outstanding wetting power (fast wetters) and dispersing properties. The broad choice of different solvents makes it possible to find a grade which is suitable for many different formulation types. Synergen W 02 and W 03 are very suitable for hydrolytically unstable active ingredients due to their very low water content.
Synergen W 03
910, 930
< 0,1
ca. 63
Synergen W 09*
910, 930
< 0,1
> 100
* Development product; samples available
SoLVENtS, CrYStALLIzAtIoN INHIBItorS

Composition Active content (%); Appearance ca. 100; liquid ca. 100; liquid ca. 100; liquid EPA* Water content K.F. (% ) < 0,5 Comments
genagen 4166
Dimethylamide of C8/C10 fatty acid
920
Genagen types are versatile solvents, co-solvents and crystallization inhibitors.
genagen 4231
Dimethylamide of C8/C10 fatty acid
920
< 0,5
genagen 4296
Dimethylamide of C10 fatty acid
920
< 0,5
32
33
gLYMES gLYCoL DIEtHErS

Composition Active content (%) Water content K.F. (% ) max. 0,2 EPA* Flash point (C) 141 Kinematic viscosity at 20C (mm 2/s) 4,1 Water solubility at 20C (% w/w) 100 Comments
tetraglyme
Tetraethylene glycol dimethyl ether
> 99
not reg.
Glymes are versatile solvents with varying properties, depending on the degree of condensation and type of alkyl groups. Dipropylene glycol DME can also be used as an NMP replacement. All products selected here are non-toxic and require no hazard labeling. For more glymes and further information see also Clariants brochure Your functional fluid, Glymes Glycol Diethers.
Dipropylene glycol DME
Dipropylene glycol dimethyl ether
> 99
max. 0,05
not reg.
65
1,1
35
Polyglycol DME 500
Polyethylene glycol dimethyl ether
> 98
max. 0,3
not reg.
220
29
100
other Products
Butyldiglyme
Diethylene glycol dibutyl ether
> 99
max. 0,05
not reg.
120
2,4
0,3
Polyglycol BB 300
Polyethylene glycol dibutyl ether
> 99
max. 0,2
not reg.
151
45
PoLYEtHYLENE gLYCoLS
Composition Appearance Water content K.F. (%) max. 0,5 EPA* OH number (mg KOH/g) 356 394 Viscosity at 20C (mPas) 88 96 Comments
Polyglykol 300
Polyethylene glycol with MM 300, PEG-6
liquid
910, 930
Polyglykol 400
liquid
max. 0,5
910, 930
267 295
112 124
Polyglykol 600
wax
max. 0,5
910, 930
178 197
17 18 (50% in water) 24 28 (50% in water) 50 58 (50% in water) 114 142 (50% in water) 210 262 (50% in water)
Polyethylene glycols are used in agrochemical formulations as humectants, compatibilizers, and to increase low temperature stability. Additionally, certain PEGs also increase the bio-availability of active ingredients. For more polyethylene glycols and further information see also Clariants Polyalkylene / polyethylene glycols brochure.
Polyglykol 1000
wax / melt
max. 0,5
910, 930
107 118
Polyglykol 2000 S
flakes
max. 0,5
910, 930
51 62
Polyglykol 4000 S
flakes
max. 0,5
910, 930
25 30
Polyglykol 6000 S
flakes
max. 0,5
910, 930
17 20
34
35
Clariant International Ltd. Functional Chemicals Division marketing crop Protection 4132 muttenz switzerland Phone +41 61 46 977 67 fax +41 61 46 975 12 Clariant Produkte (Deutschland) gmbH functional chemicals division research & development crop Protection 65926 frankfurt am main germany Phone +49 69 305 80 234 fax +49 69 318 435 Internet or Email: http://www.clariant.com cropprotection @ clariant.com
trademark of clariant registered in numerous countries. 2008 clariant international ag, rothausstrasse 61, 4132 muttenz, switzerland
fuenfWerken.com
this information is based on our present state of knowledge and is intended to provide general notes on our products and their uses. it should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. any existing industrial property rights must be observed. the quality of our products is guaranteed under our general conditions of sale.

2008 CropProtection Newsroom Brochures CropProtectionProductRange

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Functional Chemicals Division

Auxiliaries for Crop Protection Formulations

Amine ethoxylates Special adjuvants

Emulsifier blends Performance blends Clariant matched pairs

Sulfosuccinates Solvents, crystallization inhibitors Glymes glycol diethers Polyethylene glycols

genapol X genapol XM Emulsogen tS Emulsogen EL genapol PF, ED genapol EP

FAttY ALCoHoL EtHoXYLAtES

Product specified by viscosity.

FAttY ALCoHoL EtHoXYLAtES

genapol t 250 Powder

C16/C18 fatty alcohol polyglycol ether with 25 EO

Product specified by viscosity.

Product specified by dropping point.

FAttY ALKoHoL EtHoXYLAtES

Emulsogen LP Emulsogen M Emulsogen MC

910, 930 910, 930 910, 930

A: 1% a.i. in water B: 5g / 25g / 25% BDG C: 1g / 100ml / 10% NaCl

EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx

Iso-tridecyl alcohol ethoxylate methyl ether with 6 EO

Iso-tridecyl alcohol ethoxylate methyl ether with 15 EO

* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx

Product specified by OH number.

* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx

CAStor oIL EtHoXYLAtES

960 960 960 960 960

Emulsogen EL 300 Emulsogen EL 360 Emulsogen EL 400 Emulsogen EL 540

Emulsogen V 1816 Emulsogen 4084 genapol V 5008

EO/PO block copolymer EO/PO block copolymer EO/PO/EO block polymer

960 960 960

genapol PF 10 genapol PF 20 genapol PF 40

100; liquid 100; liquid 100; liquid

960 960 960

Block copolymer of EO/PO containing 80% EO

Block copolymer of EO/PO containing 80% EO

Block copolymer of EO/PO containing 80% EO

Genapol PF 80 FP is a finely powdered version of Genapol PF 80.

Ethylene diamine EO/PO block copolymer

genapol ED 3030 genapol ED 3060

100; viscous liquid 100; viscous liquid

HLB (calc.) 11 11 16,5 14 16 16 15,5 11 12,5 13,5 9 12 10 10,5 11 12

Emulsogen EP 4901 is a liquefied alternative to Emulsogen 3510 for easier handling.

Nonylphenol polyglycol ether with 4 EO

Nonylphenol polyglycol ether with 6 EO

Nonylphenol polyglycol ether with 8 EO

Nonylphenol polyglycol ether with 9 EO

Nonylphenol polyglycol ether with 10 EO

Nonylphenol polyglycol ether with 11 EO

Nonylphenol polyglycol ether with 13 EO

Nonylphenol polyglycol ether with 15 EO

Nonylphenol polyglycol ether with 20 EO

Nonylphenol polyglycol ether with 23 EO

Nonylphenol polyglycol ether with 30 EO

A: 1% a.i. in water B: 5g / 25g / 25% BDG C: 1g / 100ml / 10% NaCl

* EPA: Exempted from tolerance under EPA regulation 40 CFR 180.xxx

Tri-sec-butylphenol polyglycol ether with 4 EO

Tri-sec-butylphenol polyglycol ether with 6 EO

Tri-sec-butylphenol polyglycol ether with 8 EO

Tri-sec-butylphenol polyglycol ether with 11 EO

Tri-sec-butylphenol polyglycol ether with 13 EO

Tri-sec-butylphenol polyglycol ether with 18 EO

Tri-sec-butylphenol polyglycol ether with 30 EO

ca.70 mPas (70C)* ca. 140 mPas (70C)*

Tri-sec-butylphenol polyglycol ether with 50 EO