PRESENTATION OUTLINE
What is Mercury
Mercury In The Oil and Gas Industry Managing Mercury in PETRONAS PRSB Hg Research Team
What is Mercury
Mercury occurs in hydrocarbons as a natural occurring geological contaminant Distribution of mercury species depends on the type of medium.
A toxic contaminant, dangerous to personnel, can affect HSE and also the integrity of plant equipments Harmful to health, process equipment and environment
HgR2
Elemental Mercury (Hg) - Vapor and Metallic Liquid - Natural Gas and Air
Inorganic Mercury (HgCl2, HgS) - Soil, Sludge and Water - Solid and Ionic Liquid
Organic Mercury (R2Hg) - Natural Gas, Air, Liquid Hydrocarbon - Water and Biomasses - Vapour and Organic Liquid
Sources of Mercury
Natural sources Anthropogenic sources
Volcanoes.
Weathering of rocks.
Paints industries
Electrical industries
Petroleum industries
Bio Accumulates
Harmful to Health
Harmful to Environment
Hg accumulation
Minamata Incident
Al Heat Exchanger
Environ. Hg Cycle
Birth defects/retardation
(Minamata Children)
Memory Loss
Source: USEPA Health Effects of Mercury DISCLAIMER: Symptoms not solely caused by Hg poisoning. May also be caused by other toxic substances/diseases. Symptoms of Hg posoning may also display in other forms.
PRESENTATION OUTLINE
What is Mercury Mercury In The Oil and Gas Industry
Managing Mercury in PETRONAS PRSB Hg Research Team
Men at work
Elemental Mercury
Catalyst deactivation
Mercury In Malaysia
LA JE
Lawit
Jerneh
Talisman
Hg Concern
Beranang
Guntong D
Angsi
Bekok C
Sotong Collector
Duyong
Liquefaction
LNG
Export
Upstream
End User
Mercury is being distributed along our pipelines, process units and final products
PRESENTATION OUTLINE
What is Mercury
Mercury In The Oil and Gas Industry
Mercury Management is the Niche Technology as in PETRONAS Technology Agenda approved by PETRONAS MC
Aspiration/ Vision A Leading Oil & Gas Multinational of Choice by Businesses Technology Vision E&P Integrated Seismic Technology Integrated Basin Analysis Reservoir Characterisation Focus Areas & Modeling for Future Oil Positioning Enhanced Recovery (Water Alternating Gas) CO2 Management GAS Leadership in selective technology; leveraging new technology for future positioning OIL PETCHEM NEW ENERGY RESOURCE Unconventional Hydrocarbons Heavy Oil Oil Shale Methane Hydrates Oil Sands Solar Biomass Clean Coal Technology New Energy Resources FRONTIER TECHNOLOGY Nanotechnology Hydrogen Green Technologies
Refining Catalysis Technology Development of Top Tier/ OEM Lubes Treatment of Low Quality Crudes Biofuels Biolubes
Bio-Polymers Nano Polymer Compounds Alternative Feedstock Technology New Value Added Derivatives
Develop highly qualified technical leaders to spearhead development of key, pacing and emerging technologies by driving technology initiatives from concept until implementation Triple Plus Targets Build strong capabilities in technology focus areas in E&P, Gas, Oil and Petchem in line with the Corporate Agenda as well as to position PETRONAS for future competitive advantage Build conviction that Technology creates Value
Ver 3 - approved on 3 March 2008
2010
Niche player in Hg Management
2009
N LO G
R TE
2008 2007
M UM I ED RM E T
Operate Hg removal technologies Operate Hg removal technologies Bench-scale Task Specific Ionic Bench-scale Task Specific Ionic Liquids developed Liquids developed
2006
M ER T 2005 RT O SH
Short-listing Short-listingviable viabletechnologies technologiesand and development of new technologies development of new technologies Piloting of new technologies Piloting of new technologies Embark on research Embark on researchprojects: projects:Removal Removal Ionic Ionic Liquids, Measurement OMMS Liquids, Measurement OMMS Setting Settingup upHg HgManagement Management Committee Committee Preliminary Study Preliminary Study Baseline BaselineStudy Study& &Mercury MercuryMapping Mapping Control Diagnostic Control Diagnostic
2003
y First research project on Hg for PGB y Develop anal. technique Conventional & Unconventional
y Most comprehensive Hg analytical facilities in Malaysia y Develop inhouse methods: - Total Hg y New Hg analyser Analyzer* & Hg y Provide support & Speciation (PhD) technical consultancy y Evaluation of MRU services for OPUs & Adsorbent third parties y Establish anal. & y Establish linkage with monitoring Prog for other lab & OPUs & third parties companies outside Malaysia y Provide technical support for OPUs
BEFORE coalescer
AFTER coalescer
600
AFTER MRU
500
400
300
200
100
Ti me ( d a t e : hr s)
*Technique has won the first prize: Innovative Category by Royal Society of Chemistry (RIC), UK (March 2000) & technique is adopted by PSA latest analyser.
2007 - beyond
y Hg bed performance and verification for PGB Miri y Development of Hg Mgmt precedure for Peninsular Malaysia Operation(PMO) begain y Develop Hg Hazmat handling for PMO y Hg awareness for PGB and PCSB y Develop Hg Hazmat procedure for Pigging and cleaning y Develop Hg Specific Health Risk assessment for PMO
Measurement
Treatment
Hg removal from raw condensate Online Hg Measurement Hg removal from produced water: System 9 SAAMS filters 9 Bentonite based adsorbent
The JDS MRU successfully removed Mercury with a removal efficiency of > 96%
The RDS MRU successfully removed Mercury with a removal efficiency of > 99%
Self-assembled monolayers
PECO + DIALOG, INTERTEK, PRSB
Above chart indicate the performance of the adsorbent. Testing lasted > 25 days. As the throughput (flowrate) into the test skid increased, the mercury concentration at the outlet test skid will increased. The lowest concentration (0-2 ppb) was achieved at 4.8 GPM (series), while the highest concentration (18-25 ppb) was achieved at 9.7 GPM.
Test rig
SAMMS filters
Troubleshooting
Sampling
Analysis
Mercury Removal from Produced Water Resak Platform (Bentonite based adsorbent)
3. Hg Removal in Produce Water (RESAK Platform) Bentonite (organoclay) MR Media Ability to remove organic and elemental mercury. Carrier: Sodium Bentonite coated with Quaternary Amine (avoid swelling due to H2O). Impregnated with sulfur.
MR (+) Media Ability to remove all types of mercury compounds. Carrier: Sodium Bentonite coated with Quaternary Amine Made utilizing silane (silicone + alkane) chemistry. Impregnated with sulfur.
Mercury Removal from Produced Water Resak Platform (Bentonite based adsorbent)
Although operating at high flow rate, the adsorbent is still able to remove Hg effectively (< 2ppb).
Current practice
Laborious & may lead to personnel exposure as well as inaccurate results. Hg monitoring is expensive.
Automates entire monitoring process Acquisition of real-time mercury levels Minimizes, if not eliminates personnel exposure during monitoring Will be the first online Hg measurement system for high pressure liq. hydrocarbons
OMMS
Manual Sampling
Manual Analysis
Manual approach
Sample Treatment
Detection System
Treatment
Development of Task Specific Ionic Liquids for Mercury Removal for applications in the Petroleum Industry Allows for custom designed IL that exhibit the necessary chemical, physical and toxicological attributes needed to remove mercury.
Task Specific ILs
Removal of various species of mercury from various hydrocarbon streams. Portrays PETRONAS as being distinctive in the area of mercury management.
Onshore
Offshore
Phytoremediation*
Hg Removal (PPMSB)
Biological/Chemical
Sludge farm
Lead
Sampling Lab analysis
8 Chapter collection
Worlds first Mercury Management Guideline. Championed by GBU. Contains 8 Chapters. Covers everything from sampling, analysis, engineering, HSE, waste handling, and more.
PETRONAS Mercury Management Guideline (PHgMG) Area Coverage in PHgMG CHAPTER 0 CHAPTER 1 CHAPTER 2 CHAPTER 3 CHAPTER 4 CHAPTER 5 CHAPTER 6 CHAPTER 7 CHAPTER 8 Preface Background Hg Sampling in Various Mediums Hg Measurement Hg Risk Management Hg Removal System Hg Decontamination Guidelines Hg Waste Management Hg Emergency Response Plan (ERP) AREA COVERAGE
Development of task specific ionic liquid mercury removal for various streams 2007-2010 On-line mercury measurement system for high pressure condensate 2007-2010 Jointly developed PETRONAS first guideline Hg on management 2007-2008 Mercury removal for produced water 2006-2007 Mercury speciation study for GPP including flaring system 2006 Mercury speciation study for Resak 2006 Mercury removal project for high pressure raw NG condensate 2005-2006 Mercury removal for naphtha stream (PPMSB) 2002 Development of mercury management procedure 2004 Mercury removal Bed Profiling 2003-2005 Development of Mercury Speciation for light liquid hydrocarbon 1998-1999 Development of Rapid method for total mercury for NG condensate 1996-1999 Mercury base line study for various PETRONAS OPUs 1997, 2002, 2004, 2005, 2006 Mercury Removal in Malaysian Natural Gas pilot plant study 1989 Achievements Ongoing project/s
PRESENTATION OUTLINE
What is Mercury
Mercury In The Oil and Gas Industry Managing Mercury in PETRONAS
PETRONAS Research SDN. BHD. 2006 Petroleum Research & Scientific Services 1992 Petroleum Research Institute 1988 Laboratory Service Dept. 1978
Mahpuzah Bt Abai
PSA Sir Galahad - Mercury vapour analyser FIMS - Cold Vapour Atomic Adsorption Spectrometry Mercury Speciation -GC-AFS
Service Entities
Technology Entities
Universities
Thank You