A sudden jump between the values of second and third ionization energies of an element would be associated with the electronic configuration. (A) 1s2, 2s2 2p6, 3s1 (C) 1s2, 2s2 2p6, 3s2 3p2
(B) 1s2, 2s2, 2p6, 3s2, 3p1 (D) 1s2, 2s2 2p6, 3s2
1
2 . Which of the following sets represents the collection of isoelectronic species (A) Na
, Mg 2 , Al3 , Cl 1
1
(B) Na
Ca 2 , Sc 3 , F 1
2
(C) K , Cl
, Mg 2 , Sc 3
(D) K , Ca
, Sc 3 , Cl 1
4.. The lowest pH is associated with (A) 0.01 M, HCl (B) 0.001 M, HNO3 (C) 0.05 M, H2SO4 (D) 0.01 M, NaOH
5..After balancing the following reaction; the number of reactants molecules i.e. Cu and HNO3 respectively will be ; Cu + HNO3 Cu(NO3)2 + H2O + NO (A) 2, 5 (B) 1, 2 (C) 3, 5 (D) 3, 8
6.. The correct IUPAC name of CH3 CH2 CO OCH3 is (A) Methoxy propanone (B) Methoxypropanal. (C) Methyl propanoate (D) Methoxy ethyl ketone.
7.. Which is not correct order for the stated property ? (A) Ba > Sr > Mg : atomic radius (C) Cl > F > I : electron affinity
(B) F > O > N : first ionisation energy (C) O > Se > Te : electronegativity
8.. In the given compound, identify the type of hybrid orbitals used by carbon atoms labelled 1, 2 and 3
O H3C
1
3
C
2
C
3
N
(B) sp , sp , sp
2 2
(A) sp , sp , sp
(C) sp , sp , sp
(D) sp , sp , sp
19. Which of the following elements will gain one electron more readily in compression to other elements of their group ? (A) S(g) (B) Na(g) (C) O(g) 11. Members of a homologous series have (A) same general formula (C) similar methods of preparation neumerical 1. How many (B) same molecular mass (D) similar chemical properties (D) Cl(g)
CH 2
CH
2. 3. 4. 5.
Mn ,
+2
Fe ,
+3
+2
(R)
Electron affinity
(D)
M g energy M g e
(S) (T)
Column I (A) (B) (C) (D) Lewis acid 0.02 mol dm H2SO4 Conjugate acid 0.01 M Ca(OH)2
-3