12

th
ABCD (Date: 21-08-2011) Review Test-4
PAPER-2
Code-A
ANSWER KEY
PHYSICS
SECTION-2
PART-A
Q.1 C
Q.2 C
Q.3 A
Q.4 A
Q.5 B
Q.6 B
Q.7 A
Q.8 A
Q.9 B
Q.10 A,B
Q.11 A,B,D
Q.12 A,C
Q.13 A,B
PART-B
Q.1 (A) Q,R
(B) P
(C) T
(D) S
PART-C
Q.1 0005
Q.2 0004
Q.3 0004
Q.4 4800
Q.5 0007
MATHS
SECTION-1
PART-A
Q.1 D
Q.2 B
Q.3 B
Q.4 B
Q.5 A
Q.6 C
Q.7 C
Q.8 A or B
Q.9 D
Q.10 A,B,D
Q.11 A,B
Q.12 A,C
Q.13 A,B
PART-B
Q.1 (A) P
(B) T
(C) S
(D) Q
PART-C
Q.1 0002
Q.2 0121
Q.3 0016
Q.4 0008
Q.5 0003
CHEMISTRY
SECTION-3
PART-A
Q.1 B
Q.2 C
Q.3 D
Q.4 B
Q.5 D
Q.6 B
Q.7 B
Q.8 D
Q.9 A
Q.10 A,B,C,D
Q.11 A,C,D
Q.12 A,D
Q.13 B,C
PART-B
Q.1 (A) P,R,S,T
(B) Q,R,S,T
(C) R,S,T
(D) R,S,T
PART-C
Q.1 0005
Q.2 6720
Q.3 0034
Q.4 3115
Q.5 0375
MATHEMATICS
Code-A Page # 1
PART-A
Paragraph for Question 1 to 3
[Sol. P(x) = x
4
8x
3
+ 22x
2
24x
Now procced.]
Paragraph for Question 4 to 6
[Sol.
(i) Clearly, area (||
gm
AA
1
BB
1
)
= (AB)(AA
1
) = 4 sec u cosec u
=
u 2 sin
8
, which is least for u =
4
t

B
B
1
C
A
D
A
1
L
2
L
1
u
u
L
P(4, 3)
The equation of line L, is
(y 3) =
7
1
(x 4)
x 7y + 17 = 0 Ans.(i)
(ii) Obviously
(iii) Obviously]
Q.12
[Sol. We have
( )
( )
2
2
x 2
x 1
e . 1 x
) x ( f
+

= f ' (x) =
( )( )
( )
x
3
2
2 3
e .
1 x
1 x 5 x 3 x 1 x
+
+ +
f(x) has two points of local extremum.
i.e. x = 1 and x = o where a e ( 1, 0) ]
Q.13
[Sol. Think !]
PART-B
Q.1
[Sol.
(A) Put x
2
= t proceed. ]
PART-C
Q.1
[Sol. Put n = 2 and verify.]
Q.3
[Sol. f(x) =
60
kx
3
(10x
3
24x
2
+ 15x 40), now proceed. Ans.]
MATHEMATICS
Code-A Page # 2
Q.4
[Sol. Points of maxima are
t
t t
and
4
,
4
3
points of minima are
2
,
2
,
t t
t
and global minimum value occurs at
2
t
which is zero. ]
Q.5
[Sol. a =
2
1
, b =
2
3
, c = 1
Hence, (b
2
+ c
2
a
2
) = 3. Ans.]
PHYSICS
Code-A Page # 1
PART-A
Q.1
[Sol. i =
R R
g
+
c
]
Q.2
[Sol. 10 10
3
=
R 20
1
+
R = 80O ]
Q.3
[Sol. I =
100 80 20
1
+ +
= 5 mA ]
Q.4
[Sol. T = 2t
g
R
= 84.6 min. ]
Q.5
[Sol. V = e
2 2
x A
=
4
R
R
R
g
2
2
=
R
GM
4
3
]
Q.6
[Sol. Force is maximum at extreme point and minimum at centre. ]
Q.10
[Sol. Since for axle v > re ]
Q.11
[Sol.
o o' 3o
0
2
3
2
'
2
0 0 0
=
e
o
+
e
o

e
o

o' = + 2o ]
Q.12
[Sol. When r = 0
R
eq
=
5 . 1
2
3
4
3
4
3
= = +
when r =
R
eq
= 2R ]
PHYSICS
Code-A Page # 2
PART-C
Q.1
[Sol. C
eq
=
0
0
0
0
C
6
C 5
C
6
C 5
+

=
0
C
11
5
B
A
C
0
C
0
C
0
C
0
C
0
V
0
C
0
1 2
Q = C
eq
55 = 25 C
0
V
12
= 55 25 = 30V
V
B
V
A
= 15 10 = 5V ]
Q.2
[Sol. J =
2
1
40 (0.5 + 1.5) = 40 NS
V
4
= 40 40 = 0 velocity is exchanged.
m
1
= m
2
]
Q.3
[Sol. W
ext
+ W
g
= 4K = 0
W
ext
m
4
V = 0
Wext = 2
2
4
= 4 J ]
Q.4
[Sol.
r
kq
= 3 q =
k
r 3
3
4
tr
3
N =
3
4
t R
3
N =
3
r
R
|
.
|

\
|
=
3
2
80
|
.
|

\
|
= 64 10
3
Q = N
q
=
k
r 3
64 10
3
V' =
R
kQ
=
R
r
3 64 10
3
=
40
3
64 10 = 4800 V ]
Q.5
[Sol. P
A
=
t
10
p (10
3
)
2
0.1 = 10
6
WW
P
B
=
t
10
t (2 10
3
)
2
0.1 = 4 10
6
W
P = P
A
+ P
B
+ 2
B A
P P cos A|
PHYSICS
Code-A Page # 3
A| =

t 2
(n 1) t
=
7
10 6
2

t
0.5 2 10
7
=
3
t
= 4 10
6
+ 10
6
+ 4 10
6

2
1
= 7 10
6
W = 7 W ]
Code-A Page # 1
CHEMISTRY
PART-A
Q.1
[Sol.
(A)
(D)
O
3
Zn
KOH KOH, Cannizaro Aldol
O
O
O
(B) (C)
(E) (F)
+
+
CH
CH OH
2
C OK
+
CH CCH CCH
3 2 3
O O
CH
3
CH
3
O
CH C=CHCCH
3 3
]
Q.2
[Sol. HO

+
H . conc
H

o = 8
(no rearrangement)

Minor
+
Major
so it is not a good method.
Br
Br

O Et
Mg
2

]
Q.3
[Sol. and few more compound can be the answer.]
Paragraph for question nos. 4 to 6
[Sol.(i) A
t
=
0
9
4
A
A
t
=
45000
9
4

= 20,000 Unit
(ii) Ans. (D)
(iii) Pd
+2
in Coordination number 4 is square planar. ]
Code-A Page # 2
CHEMISTRY
Q.7
[Sol. On increasing the temperature, due to increase in effective collision, rate of reaction increases and it is
found that for most of the reaction, 10C increase in temperature causes increase of rate by 2 to 3
times.It is true that collision frequency (A) also increases but it does not have major contribution for
increased reaction. Major contribution comes from
) e (
RT / E
a

factor due to increased temperature.]

Q.8
[Sol. Cl CH
3
C
O
NaOH


HCOH + CCl
3
HCO + CHCl
3
O O
]
Q.10
[Sol. From the given option, complete the chain reaction
89
A
230


o
87
B
226


|
88
C
226


o
88
D
222

87
E
222


o
85
F
218
* D undergoe |-decays
* Atomic number of A is 89 while E has 87
* Mass number of F is 218 while mass number of B is 226.
* Number of neutron in C is 138 and correspondingly A is
89
A
230
. ]
Q.11
[Sol. (A)
O
| |
COOH CH C Me
2


A

O
| |
CH C Me
3
+ CO
2
(B)
O
| |
H SO CH C Ph
2 2


A
O
| |
CH C Ph
3
+ SO
2
(C)
OH
COOH


A

OH
+ CO
2
(D) CH
2
= CHCH
2
COOH

A
CH
3
CH = CH
2
+ CO
2
]
Q.12
[Sol. In adiabatic free expansion, work done is zero, also the temperature remains same T = 127C and
during expansion pressure reduces, but for finite volume of gas, pressure will be greater than zero
P
2
=
8
P
V
V P
2
1 1
=
Only A and D is wrong statement. ]
Code-A Page # 3
CHEMISTRY
Q.13
[Sol.

4 2
SO H . dil

OH

HBO

OH



H dil

OH

HBO

OH



H dil
HO

HBO
HO



H dil
OH

HBO
OH
]
PART-C
Q.1
[Sol.
H
2
He
Other gases
Z
P
Normal Temperature
(1) Z > 1 (from graph)
(2) At T < T
C
, attraction will be present and for He and H
2
also Z < 1
(3) Z > 1 (from graph)
(4) Z > 1 ( from graph)
(5) Z > 1 ( from graph)
(6) same as (2) Z < 1
(7) Z < 1 (from graph)
Code-A Page # 4
CHEMISTRY
(8) Z
CC
=
8
3
(9) Z
CC
=
8
3
(10) Z = 1 +
terms . neg .........
V
1
RT
a
b
m
+ |
.
|

\
|

= Z > 1 ]
Q.2
[Sol. + Cl
2

nation Monochlori
h

v

Cl
(P2)
Number of H = 8, which is 2 Relative amount = 8 3.8 = 30.4
+ Cl
2

nation Monochlori
h

v

Cl
(P3)
Number of H = 2, which is 3 Relative amount = 2 4.5 = 9
+ Cl
2

nation Monochlori
h

v

Cl
(P1)
Number of H = 6, which is 1 Relative amount = 1 6 = 6
Total = 45.4
% of P2 =
100
4 . 45
4 . 30

= 67 %
% of P3 =
100
4 . 45
9

= 20 % ]
Code-A Page # 5
CHEMISTRY
Q.3
[Sol. (i) [Co(NH
3
)
6
] [Co(CN)
6
]
Donar Atom C N
6 0
5 1
4 2
3 3
2 4
1 5
0 6
= 7
(ii) [Co(NH
3
)
5
CN] [Co(CN)
5
NH
3
]
Donar Atom C N
5 0
4 1
3 2
2 3
1 4
0 5
= 6 2 = 12
(iii) [Co(NH
3
)
5
(CN)
2
] [Co(CN)
4
(NH
3
)
2
]
Donar Atom C N
2 0
1 1
0 2
4 0
3 1
2 2
1 3
0 4
= 5 3 = 15
= 7 + 12 + 15 = 34 Ans.]
Q.4
[Sol. AG = 18.6 10
3
ln 10 = 2 300 ln K
eq
=
2 3
6 . 18

ln 10 = ln K
eq
= ln 10
31
= ln K
eq
K
eq
= 10
31
ab = 31
N
2
+ O
2
2NO
1 10 0
1x 10x 2x
K
eq
=
31
2
10
) x 10 ( ) x 1 (
) x 2 (

=

4x
2
= 10
30
Code-A Page # 6
CHEMISTRY
2x = 10
15
P
NO
= 2x = 10
15
cd = 15 ]
Q.5
[Sol.
dt
dB
= K[A]
2
[B]
from set 1 and set 2

[A
0
] >> [B
0
]
Order will be dependent on [B] only
hence first order reaction half life is independent of [B] x = 62.5 sec.
[If rate constant remains same]
from set 3 and set 4

[B
0
] >> [A
0
]
Order will be dependent only on [A]
hence second order reaction
half life is inversely dependent on [A
0
]

|
.
|

\
|
10
5
=
|
.
|

\
|
625
y
y =
2
625
= 312.5
x + y = 312.5 + 62.5
375 ]