XII(SMS) RT-5 [JEE Mains] Page # 1

CHEMISTRY
XII-SMS REVIEW TEST-5 DATE : 23.09.2012
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.33 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 Which of the following oxide is more basic among them.
(A*) Al
2
O
3
(B) CO
2
(C) B
2
O
3
(D) N
2
O
5
Q.2 Which of the following is exothermic process:
(A)

2
) g ( ) g (
S S (B*)

) g ( ) g (
Cl Cl
(C)

) g ( ) g (
Ne Ne (D)
2
) g ( ) g (
Na Na
+ +

Q.3
H O CCH CH
2 3
O
& CH C O
3 3
CH
O
are
(A) Metamer (B*) Functional isomers
(C) Chain isomer (D) Positional isomers
Q.4 Correct order of acidic streagth of following compounds is
OH
NO
2
OH
NO
2
OH
NO
2
O
2
N
NO
2
OH
NO
2
(I) (II) (III) (IV)
(A) III > I > II > IV (B) IV > I > II > III
(C*) III > II > I > IV (D) III > IV > I > II
Q.5 2 mole of equimolar mixture of Na
2
C
2
O
4
and H
2
C
2
O
4
required V
1
litre of 0.1 M KMnO
4
in acidic
medium for complete oxidatinon. The same amount of the mixture required V
2
litre of 0.2 M NaOH for
neutralization. The ratio of V
1
to V
2
is
(A) 1 : 2 (B) 2 : 1 (C*) 4 : 5 (D) 5 : 4
Sol. eq. of Na
2
C
2
O
4
+ eq. of H
2
C
2
O
4
= eq. of KmnO
4
= V 0.1 5
2 + 2 = 0.5V; V = 8L
eq. of H
2
C
2
O
4
= eq. of NaOH
1 2 = 0.2 V
2
; V
2
= 10L
Hence, V
1
: V
2
= 8 : 10 = 4 : 5
XII(SMS) RT-5 [JEE Mains] Page # 2
CHEMISTRY
Q.6 The vapour pressure of water at 80C is 355 mm of Hg. 1L vessel contains O
2
at 80C, saturated with
water the total pressure being 760 mm of Hg. The contents of the vessel were pumped into 0.3 L vessel
at the same temperature. What is the partial pressure of O
2
in mm of Hg?
(A*) 1350 (B) 2178.3 (C) 121.5 (D) 355
Sol. Volume of O
2
= 1L
and
2
O
p = 760 355 = 405 mm Hg
Since, the temperature is constant, using Boyle's law we get
1L 405 mm 0.3 L
2
O
' p

2
O
' p = 1350 mm Hg.
Q.7 Correct order of basic strength of following compounds
N
H
N
NH
2
(I) (II) (III)
(A) I > II > III (B) III > III > I
(C) II > I > III (D*) II > III > I
Q.8. Which of the following can not show G.I ?
(A) (B*)
(C) (D)
Q.9 Which of the following is incorrect order :
(A) BeO < MgO < CaO : Order of basic nature.
(B*) LiF < LiCl < LiBr < LiI : Order of melting point.
(C) KO
2
< RbO
2
< CsO
2
: Order of thermal stability.
(D) GeCl
2
< SnCl
2
< PbCl
2
: Order of thermal stability.
Q.10 Which of the following is correct statement about the ammonia:
(A) It formed by the decomposition of metal azide.
(B) It's aqueous solution gives deep blue colour with AgCl.
(C) Its decomposition into N
2
& H
2
is an exothermic process.
(D*) Solution of sodium in liquid ammonia is blue coloures.
XII(SMS) RT-5 [JEE Mains] Page # 3
CHEMISTRY
Q.11 I
2
(aq) + I

(aq)

3
I (aq). We started with 1 mole of I
2
and 0.5 mole of I

in one litre flask. After

equilibrium is reached, excess of AgNO
3
gave 0.25 mole of yellow precipitate. Equilibrium constant is:
(A*) 1.33 (B) 2.66 (C) 2.0 (D) 3.0
Q.12 What is [Ag
+
] in a solution made by dissolving both AgX and AgY until saturation is reached with respect
to both salts.
k
sp
(AgX) = 10
11
k
sp
(AgY) = 9 10
11
(A) 10
4
M (B) 10
6
M (C) 10
10
M (D*) 10
5
M
Q.13 Which of the following compounds is not aromatic?
(A) (B) (C*) (D)
Q.14 Which of the following cations is most stable?
(A)
CH
3
C
H C
3
CH
3
(B)
CH
3
C
H C
3
CH
3
OH
(C*)
CH
3
C
HO
CH
3
(D)
CH
3
C
H C
3
OH
Q.15 Which of the following species can acts as a reducing agent.
(A*) I

(B) CrO
3
(C)
+ 4
63
Eu (D) Pb
4+
Q.16 Which of the following elements are generally known as heavy metals.
(A) Elements of 3d-series (B*) Elements of 5d-series
(C) Alkali metals (D) Alkaline earth metals.
Q.17 Find the log of equilibrium constant K [log
10
K], for the reaction at 298 kelvin.
2H
+
(aq) + D
2
(g) H
2
(g) + 2D
+
(aq)
Given
o
D / D
2
E
+ = 2.955 10
3
V
Use
(

0591 . 0
F
303 . 2 RT
(A*) 0.1 (B) 0.2 (C) 1 (D) 2
XII(SMS) RT-5 [JEE Mains] Page # 4
CHEMISTRY
[Sol.
o
cell
E = 0.002955 =
2
0591 . 0
log K ; log K = 0.1]
Q.18 The wave number of third emission line in the atomic spectrum of hydrogen in Balmer series is equal to
[Given R is Rydberg's constant]
(A)
cm
R 7
144
(B)
1
cm
144
R 7

(C)
cm
R 21
100
(D*)
1
cm
100
R 21

[Sol. 3rd line 5 2
(

= v =

2 2
5
1
2
1
R
1
;
1
cm
100
21
R

(

= v
]
Q.19 The appropriate formula of "dichloridobis(ethane-1,2-diamine)platinum (IV) nitrate is
(A*) [PtCl
2
(en)
2
] (NO
3
)
2
(B) [Pt(en)
2
Cl
2
](NO
3
)
2
(C) [Pt(en)
2
Cl
2
] NO
3
(D) [PtCl
2
(en)
2
] NO
3
Q.20 The number of geometrical isomers and optical isomers of [Pt(NH
3
)(Br)(Cl)(Py)] are respectively.
(A) 2, 0 (B) 3, 2 (C*) 3, 0 (D) 2, 2
Q.21 Which of the following molecules has longest C == C bond length?
(A) CH
2
== C == CH
2
(B) CH
3
CH == CH
2
(C)
CH
3
C CH
3
CH
2
CH
CH
3
(D*) C CH
3
CH
2
CH
3
Q.22 Correct order for heat of combustion (HOC) is:
(I) (II) (III)
(A*) III > II > I (B) I > II > III
(C) I > III > I (D) II > I > III
Q.23 Which of the following set of species are paramagnetic?
(A) ClO
2
, O
3
, NO
2
(B*) ClO
2
, O
2
, NO
2
(C) O
3
, O
2
, P
4
(D) N
2
, B
2
, C
2
Q.24 Which of the following does not exist?
(A) Tl(I
3
) (B) PbF
4
(C) FeCl
3
(D*) SCl
6
XII(SMS) RT-5 [JEE Mains] Page # 5
CHEMISTRY
Q.25 Relation between following compunds is
CH
3
F
H D
Cl Ph
Cl Ph
CH
3
H D
F
(A) Identical (B*) Enantiomers (C) Positional isomer (D) Diastereomers
Q.26 Which of the following will act as buffer solution?
(a) 100 ml of 0.1M NaOH + 100 ml of 0.1M acetic acid
(b) 100 ml of 0.1M NaOH + 200 ml of 0.1M acetic acid
(c) 200 ml of 0.1M NH
3
+ 100 ml of 0.1M HCl
(d) 100 ml of 0.1M HCl + 100 ml of 0.1M sodium acetate
Select the correct answer using the codes given below:
(A) a and b (B*) b and c (C) c and d (D) a and c
Sol. [Hint : Acidic buffer = WA + A

, Basic buffer = WB + B
+
]
Q.27 If Al
3+
replaces Na
+
situated at the edge centres of NaCl crystal then calculate cation vacancies in
1 mole NaCl crystal.
(A*) 3.01 10
23
(B) 6.01 10
23
(C) 1.5 10
23
(D) 1.12 10
22
Sol. [Hint : 3 Na+ ions are replaced by one Al3+ ion. Hence number of cation vacancies = 2.]
Q.28 Which of the indicated H in the following is most acidic?
O
N
N
H
(p)
(Z)
H
H
H
(X)
H H
O
(Y)
(A) X (B) Y (C) Z (D*) p
Q.29 Which of the following is planar?
(A) B
2
H
6
(B) Fe
2
Cl
6
(C)

4
FeCl (D*)
2
4
PtCl
Q.30 Reaction : F
2
+ 2ClO
2
2FClO
2
follows the rate law:
V = k[F
2
] [ClO
2
]
Review the following data and evaluate the values of rate X and Y.
[F
2
] [ClO
2
] Rate [mole L1 s1]
0.1 M 0.01 M 1.2 10
3
0.1 M 0.04 M X
0.2 M 0.01 M Y
(A) 4.8 10
1
, 1.2 10
3
(B) 3.5 10
1
, 2.4 10
3
(C*) 4.8 10
3
, 2.4 10
3
(D) 2.4 10
3
, 1.44 10
6
XII(SMS) RT-5 [JEE Mains] Page # 6
CHEMISTRY
Q.31. Which of the following compunds are stereoisomers of each other-
(A*) & (B) &
(C)
Cl
Cl
&
Cl
Cl
(D)
CH
3
H
Me
D
&
H
3
C H
Me
D
Q.32 Give the correct order of True (T) or False (F) statements.
(I) Gas A diffuses twices as fast as gas B. If the vapour density of the gas A is 4, molar mass of gas
B will be 32.
(II)
) ( O H ) s ( O H
2 2
l
Sign A work is +ve.
(III) When a solution is prepared by mixing 90 ml of HCl solution (pH = 3), 10 ml of NaOH solution
(pH=11) & 60 ml of H
2
O, pH will be 3.1
(A*) TTF (B) TFT (C) FFT (D) TTT
Q.33 A reaction has an equilibrium constant of 0.98 at 300 K and 1.2 at 400 K. Select the incorrect option.
(A) The reaction is endothermic
(B) At standard conditions reaction will be non spontaneous at 300 K and spontaneous at 400 K.
(C) Enthalpy change of reaction
98 . 0
2 . 1
ln R 1200 H
o
R
= A
(D*)
98 . 0
2 . 1
ln R 3 S
o
R
= A
[Assume AH and AS to be temperature independent]