Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

Date : 16-03-2013 Duration : 1 Hour Max. Marks : 80

CHEMISTRY (THERMOD : SECOND AND THIRD LAWS)
TEST - 14
INSTRUCTIONS
A. General :
1. This Question Paper contains 22 questions.
2. No additional sheets will be provided for rough work.
3. Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
in any form are not allowed.
4. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
5. Do not Tamper / mutilate the ORS or this booklet.
6. Do not break the seals of the question-paper booklet before instructed to do so by the invigilators.
7. Write your Name, Roll No. and Sign in the space provide on the back page of this booklet.
B. Filling the bottom-half of the ORS :
Use only Black ball point pen only for filling the ORS. Do not use Gel / Ink / Felt pen as it might smudge the ORS.
8. Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken
the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS
in the space provided (if the ORS is both side printed).
9. Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball
point pen.
10. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be
displayed and 5 marks will be deducted (paper wise) from the total.
11. Since it is not possible to erase and correct pen filled bubble, you are advised to be extremely careful while
darken the bubble corresponding to your answer.
12. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not
scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the
ORS.
13. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will
be taken as final.
C. Question paper format and Marking scheme :
14. The question paper consists of 1 parts. The part consists of Two Sections.
15. For each question in SectionI, you will be awarded 3 marks if you darken the bubble(s) corresponding to
the correct choice for the answer and zero mark if no bubbled is darkened. In case of bubbling of incorrect
answer, minus one (1) mark will be awarded.
16. For each question in SectionII, you will be awarded 5 marks if you darken the bubble corresponding to the
correct answer and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus
one (1) mark will be awarded.
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COURSE NAME : VIKAAS (JA) & VIPUL (JB) COURSE CODE : CLINIC CLASSES
TARGET : JEE (IITs) 2014
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-1
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Straight Objective Type
This section contains 15 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONLY ONE is correct.
1. The equilibrium constant for
A(g) + B
2
(g) AB
2
(g) k
p
= 100 at 522 K.
Structure of AB
2
is like H
2
O. If bond energy of AB bond is 200 kJ/mol and that of BB bond is 100 kJ/mol, the
find AS of above reaction :
(A) 0.53 J/mol-K (B) 536 J/mol-K (C) 550 J/mol-K (D) 5.36 J/mol-K
2. At 0C, AH
fus
= 6 kJ/mol, change of entropy for freezing of one mole of ice will be :
(A) (B) 0 (C) 21.98 J/mol-K (D) 13.6 J/mol-K
3. The change in free energy accompanied by the isothermal reversible expansion of 1 mol of an ideal gas when
it doubles its volume is AG
1
The change in free energy accompanied by sudden isothermal irreversible
doubling volume of 1 mole of the same gas is AG
2
Ratio of AG
1
and AG
2
is
(A) 1 (B)
2
1
(C) 1 (D)
2
1
4. For a perfectly crystalline solid C
p.m.
= aT
3
, where a is constant. If C
p.m.
is 0.42 J/Kmol at 10 K, molar entropy
at 10 K is
(A) 0.42 J/K-mol (B) 0.14 J/K-mol (C) 4.2 J/K-mol (D) zero
Space for Rough Work
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-2
Space for Rough Work
5. When 1 mole of an ideal gas at 20 atm pressure and 15 L volume expands such that the final pressure
becomes 10 atm and the final volume becomes 60 L. Calculate entropy change for the process (C
p,m
= 30.96
J mole
1
K
1
)
(A) 80.2 J.k
1
mol
1
(B) 62.42 kJ.k
1
mol
1
(C) 120 10
2
Jk
1
mol
1
(D) 27.22 J.k
1
mol
1
6. Which of the following graphs best illustrates the variation of entropy of a substance with temp.
(A) (B)
(C) (D)
7. Assertion : Diamond is thermodynamically less stable than its allotrope graphite
Reason : Molar entropy of graphite is greater than that of diamond under similar conditions.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-3
Space for Rough Work
8. Which diagram represents the large value of equilibrium constant for the reversible reaction
(A) (B)
(C) (D)
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-4
Space for Rough Work
9. For a reaction M
2
O
(s)
2M
(s)
+
2
1
O
2

(g)
, AH = 30 KJ/mol and AS = 0.07 KJ/mol /K at 1atm. The reaction
would not be spontaneous at temperatures
(A) > 429 K (B) < 429 K (C) < 100 K (D) > 100 K
10. For the change H
2
O (s), (273 K, 2 atm)

H
2
O (), (273K, 2 atm), choose the correct option.
(A) AG = 0 (B) AG < 0 (C) AG > 0 (D) None
11. For the synthesis of ammonia at 300 K :
N
2
(g) + 3H
2
(g) 2NH
3
(g)
Calculate the value of AG ?
N
2
H
2
NH
3
AH

(Kcal/mole) 0 0 10
S (Cal/K-mole) 40 30 45
(A) 8 Kcal (B) 12 Kcal (C) 16 Kcal (D) 20 Kcal
12. The direct conversion of A to B is difficult, hence it is carried out by the following shown path:
AS(A C) = 50 ; AS(C D) = 30; AS(B D) = + 20
The entropy change for the process A B is
(A) 100 (B) 60 (C) 100 (D) + 60
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-5
Space for Rough Work
13. The value of log
10
K for a reaction A B is :
(Given :

A
K 298 r
H = 54.07 kJ mol
1
,

A
K 298 r
S = 10 JK
1
mol
1
and R = 8.314 JK
1
mol
1
; 2.303 x 8.314 x 298
= 5705)
(A) 5 (B) 10 (C) 95 (D) 100
14. When two mole of an ideal gas
|
.
|

\
|
= R
2
5
C
m , p heated from 300 K to 600 K at constant pressure. The change
in entropy of gas (AS) is :
(A)
2
3
R ln 2 (B)
2
3
R ln 2 (C) 5R ln 2 (D)
2
5
R ln 2
15. Calculate the total entropy change for the transition at 368 K of 1 mol of sulphur from the monoclinic to the
rhombic solid state and AH = 401.7 J mol
1
for the transition. Assume the surroundings to be an ice-water.
Both at 0C :
(A) 1.09 JK
1
(B) 1.47 JK
1
(C) 0.38 JK
1
(D) 0.76 JK
1
SECTION - II
Multiple Correct Answer Type
This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of
which ONE OR MORE is/are correct.
16. Which of the following statement(s) is/are false ?
(A) A
r
S for
2
1
Cl
2
(g) Cl(g) is positive
(B) AE < 0 for combustion of CH
4
(g) in a sealed container with rigid adiabatic system.
(C) AG is always zero for a reversible process in a closed system
(D) AG for an ideal gas reaction is a function of pressure
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-6
Space for Rough Work
17. For which of the following phase transformation AG is not +ve.
(A) H
2
O (, 1 atm, 373 K)

H
2
O (g, 1 atm, 373K)
(B) H
2
O (, 0.9 atm, 373 K)

H
2
O (g, 1 atm, 373K)
(C) H
2
O (s, 1 atm, 273 K)

H
2
O (, 1 atm, 273K)
(D) H
2
O (s, 0.9 atm, 273 K)

H
2
O (, 0.9 atm, 273K)
18. AS =
T
q
rev
, incorrect statements are :
(A) AS is defined only for reversible process.
(B) For irreversible process, AS is calculated by considering the irreversible.
(C) For irreversible process and same process taking place reversibly, AS is same.
(D) AS
sys
is always the for irreversible process.
19. Among the following false statements are :
(A) Unit of molar entropy of a substance is SI system is Joule / Kelvin
(B) Molar entropy of vapourisation of ice is ve.
(C) In adiabatic free expansion, heat involved is zero and therefore entropy change will be zero.
(D) At absolute zero temperature, entropy of a perfectly crystalline substance is zero.
CHEMISTRY
RESONANCE
JA&JBTEST14160313C0-7
Space for Rough Work
20. Quick lime (CaO) is produced by heating limestone (CaCO
3
) to drive off CO
2
gas.
CaCO
3
(s)

CaO (s) + CO
2
(g), AH = 180 KJ, AS = 150 J/K.
Assuming that variation of enthalpy change and entropy change with temperature to be negligible, choose
the incorrect options :
(A) Decomposition of CaCO
3
(s) is never spontaneous.
(B) Decomposition of CaCO
3
(s) becomes spontaneous when temperature is less than 900C.
(C) Decomposition of CaCO
3
(s) becomes non-spontaneous when temperature is greater than 1000C
(D) Decomposition of CaCO
3
(s) becomes spontaneous when temperature is greater than 927C.
21. The feasibility of a chemical reaction can be explained based on AH, AS and AG, for 2O
3
(g) 3O
2
(g)
answer the following :
(A) AS = +ve (B) AG = +ve (C) AH = ve (D) AG = ve
22. Identify the incorrect statement regarding a spontaneous process :
(A) Exothermic processes are always spontaneous.
(B) Lowering of energy in the reaction process is the only criterion for spontaneity.
(C) For a spontaneous process in an isolated system, the change in entropy is positive.
(D) Endothermic processes are never spotaneous.