Faculty of Chemical Engineering CPE553 Chemical Engineering Thermodynamics

Semester March-July 2013 29 March 2013

TUTORIAL 4

1. The general form of summability relation of molar properties for a binary solution is given by

=

i
i
i
M x M


By using above equation, prove that partial molar properties
1
M and

2
M for a binary systems at
constant T and P are


= + 1
2
1
dM
M M x
dx
and
= 2
1
1
dM
M M x
dx


2. The molar volume (cm
3
mol
-1
) of a binary liquid mixture at T and P is given by

( ) = + + +
1 2 1 2 1 2
120 70 15 8 V x x x x x x

(a) Find expressions for the partial molar volumes of species 1 and 2 at T and P.
(b) Show that when these expressions are combined in accord with eq. (11.11) the given
equation for V is recovered.
(c) Show that these expressions satisfy eq. (11.14), the Gibbs/Duhem equation.
(d) Show that

= =
| | | |
= =
| |
\ . \ .
1 1
1 1 2 1
1 0
0
x x
dV dx dV dx .
(e) Plot values of

1 2
, , and V V V calculated by the given equation for V and by the equations
developed in (a) vs. x
1
. Label points


1 2 1 2
, , , and V V V V , and show their values.

3. Figure 1 shows a plot of
1 2
, and H H H vs. x
1
(J/mol) at constant T and P for a binary liquid
mixture. Label the below points and show their values on the plot.
(a) Enthalpy of pure species 1.
(b) Enthalpy of pure species 2.
(c) Partial enthalpy of pure species 1.
(d) Partial enthalpy for pure species 2.
(e) Partial enthalpy at infinite dilution of species 1.
(f) Partial enthalpy at infinite dilution of species 2.
(g) Enthalpy of the mixture that contains 22 mole % species 2.
(h) Partial enthalpy of species 2 if the mixture contains 64 mole % species 1.
(i) Partial enthalpy of species 1 if the mixture contains 52 mole % species 2.

4. Figure 2 shows a plot of entropy (kJ/kg.K) vs. x
1
at constant T and P for a binary liquid mixture.
Explain how to obtain the below points from the plot and show the values. Then, label and show
their values on the plot.
(a) Partial entropy of pure species 1 at 60 mole % species 1.
(b) Partial entropy of pure species 2 at 60 mole % species 1.
(c) Partial entropy at infinite dilution of species 1.
(d) Partial entropy at infinite dilution of species 2.


Faculty of Chemical Engineering CPE553 Chemical Engineering Thermodynamics

Semester March-July 2013 29 March 2013




Figure 1
0
50
100
150
200
250
300
350
400
450
500
550
600
650
700
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
x1
H
Faculty of Chemical Engineering CPE553 Chemical Engineering Thermodynamics

Semester March-July 2013 29 March 2013




Figure 2
0
20
40
60
80
100
120
140
160
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
S
(
k
J
/
k
g
.
K
)

x1