fuel gas savings

fg heating value
fuel neergy
boiler eff

230 nm3/hr
25000 btu/nm3
6.0375 mmbtu/hr
0.88

steam
ton/hr
mp steam energy
mmbtu/ton

280
25000
7.35
0.88
6.468

280
25500
7.497
0.88

230
25000
6.0375
0.88

2
2.2
4.4

2.5
2.2
5.5

2
2.2
4.4

154972965.xls.ms_office

1 YANBU REFINERY EMISSION CALCULATIONS - MAY

2
3 SAUDI ARAMCO YANBU REFINERY AIR POLLUTANT EMISSION CALCULATIONS
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48

2001

YANBU REFINERY FUEL CONSUMPTION RATES

SOURCES
CRUDE HEATERS (V04)
103-H1 and 103-H2

AVERAGE CONSUMPTION RATE (FOEB/DAY)

Fuel Gas
Fuel Oil
Feed Charge
218,400.00
276
1,967.76

NHT UNITS (V09)

201-H1
201-H2

55
66.8

188.65
210.87

137.3
67.9
21.3

692.35
345.08
211.19

HDC UNIBON UNITS(V17)

211-H1
211-H2

21.3
32.8

30.59
61.05

KERO-UNIBON CHARGE (V17)

211-FR-15

54.1

91.65

PLATFORMER UNITS (V11)

301-H1
301-H2
301-H3

SATURATED GAS CONCENTRATION

UNIT (SGCU) (V14)
412-FR-37

38,200.00

10,000.00

31,944.97
67

218.43

BOILERS (rated at 300 MMBtu - 100% load - each)

940-B4
163.6
277.02
52.50
940-B5
163.6
138.51
26.25
940-B6
163.6
138.51
26.25
Note that 3 boilers were operating in April - normally only 2 are in service at one time
AMINE UNIT (V12)
412-FR-46

115.48
16.25

H2S INCINERATOR - I don't believe you have to account for the incinerator emissions again already accounted for in this spreadsheet. But have your Process people check to be sure)
MEROX UNIT
LPG Processed
TOTAL CONSUMPTION
RATE:

3,729.00
4,587.91

105.00

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49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95

INPUT DATA:
Weight % Sulfur in Fuel Oil, S
Average H2S Content of Gas, ppm
High Heat Value (H.H.V.) of 1 FOEB of Fuel Gas, Btu
High Heat Value (H.H.V.) of Fuel Gas, Btu/m3 (@ 60F)
H2S Content of LPG of Merox Unit, ppm
RSH Content of LPG of Merox Unit, ppm
Weight of Fuel Oil, lb/gal
Density of LPG
Density of NHT Feed Charge
Sulfur Content of NHT Feed Charge, %
Density of Kero-Unibon Feed Charge
Sulfur Content of Kero-Unibon Feed Charge, %

3.1
20.0
6.00E+06
24000
2512
2647
7.88
0.570
0.732
0.041
0.784
0.110

CALCULATED DATA:
H.H.V. of Fuel Gas, Btu/Nm3(@ 32F)
H.H.V. of Fuel Gas, Btu/SCF (@ 32F)
Volume of 1 FOEB of Fuel Gas, Nm3
Volume of H2S in 1 FOEB of Fuel Gas, Nm3
Weight of H2S in 1 FOEB of Fuel Gas, kg.
SO2 Produced from 1 FOEB of Fuel Gas, kg/FOEB
Actual SO2 Produced from 1 FOEB Fuel Gas, kg/m3
Weight of 1 bbl Fuel Oil, kg.
Weight of Sulfur in 1 bbl Fuel Oil, kg.
Actual SO2 Produced from 1 FOEB Fuel Oil, kg/m3
Weight of 1 bbl. of NHT Feed Charge, kg.
Weight of Sulfur in 1 bbl. of NHT Feed Charge, kg
Weight of 1 bbl. Of Kero-Unibon Charge, kg.
Weight of Sulfur in 1 bbl. of Kero-Unibon Charge, kg
Weight of 1 bbl. of LPG, kg.
Sulfur Content of LPG from H2S, ppm
Sulfur Content of LPG from RSH, ppm
Total Sulfur Content of LPG, ppm
Weight of Sulfur in 1 bbl. of LPG, kg.

22703.4
643.2
264.3
0.0053
0.008
0.015
5.7143E-05
150.1
4.65
9.31
116.30
0.048
124.57
0.137
90.57
2364.24
2647
5011
0.45

Note: Less than USEPA

CONVERSION FACTORS AND EQUIVALENTS:

Standard Temperature, 0K
Standard Temperature for Oil Industry, 0K
Equivalent Volume at 60F, m3
Weight of 1 gallon of Water, lb.
Molecular Weight of H2S
Molecular Weight of Sulfur
Molecular Weight of SO2

273.15
288.75
1.057
8.34
34
32
64

(32F)
(60F)

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96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138

Equivalent of 1 Joule in Btu's

Equivalent of 1 Btu in Joules
Equivalent of 1 Kilogram in nanograms
Equivalent of 1 nanogram in kilograms
Volume of 1 kg-mole of H2S, Nm3 (@ 32F)
Equivalent of 1 kg in lbs.
Equivalent of 1000 gallons in bbls.
Equivalent of 1 bbl. in m3
Equivalent of 1 SCF in m3
Equivalent of 106 SCF in m3
Equivalent of 1 bbl. of Water in kg.

CO
kg/bbl
0.10

NMTOC's
kg/bbl
0.01

TOC's
kg/bbl
0.02

CO
kg/m3
0.000640

NMTOC's
kg/m3
None

TOC's
kg/m3
0.000027

9.4780E-04
1055.06
1.0E+12
1E-12
22.40
2.2046
23.81
0.1589
35.30
28328.61
158.89

USEPA Emission Factors*:

Pollutant

Fuel Oil

Units

Fuel Gas

Units

lb/103 gal
lb/ 106 ft3
SO2**
486.7
0.6
SO3
17.67
"
CO
5
"
40
"
NOX***
67
"
550
"
NMTOC
0.76
"
PARTICULATES****
31.709
"
5
"
TOC
1.04
"
1.7
"
NOTES: The SO2, SO3, and Particulates Emission Factors are based on the weight % of
sulfur in the fuel oil as per the applicable equations found in Table 1.3-1 of the USEPA AP-42
Emission Factors Compilation document. **** Particulates assumed to be < 10 microns.
*** NOX emission factor for a Boiler using on Fuel Gas must be reduced if the Boiler
is operated on a reduced capacity utilization as per the Load Reduction Coefficient vs.
% Load Chart (see below). ** Based on an average sulfur content of 4600 grams/10 6 Nm3.
*Source: USEPA AP-42 "Emission Factors for Air Pollutants for Exteranl Combustion
Sources," Volume I, Chapter 1, Fifth Edition, Table 1.3-1 (English units) for Fuel Oil,
Table 1.4-2 for Natural Gas

FACTORS USED TO DETERMINE FACILITY POLLUTANT EMISSIONS:

AIR POLLUTANTS
Fuel Oil:
SO2
SO3
NOX
Particulates
kg/bbl
kg/bbl
kg/bbl
kg/bbl
9.27
0.34
1.28
0.60
Fuel Gas:
SO2
SO3
NOX ****
Particulates
kg/m3
kg/m3
kg/m3
kg/m3
139
140
0.000010
None
0.003963
0.000080
141 **** NOX Emission Factor based on 55% Load Capacity of Boilers
142

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B
C
D
E
143 TOTAL AIR POLLUTANT EMISSION LOADINGS FOR FACILITY SOURCES
144
AIR POLLUTANT EMISSION RATES, kg/day
145
146
SOURCE
SO2
SO3
NOX
PART.
147
*103-H1/103-H2
29.72
2,060.88
41.63
148
**103-H1/H2/H3
0.00
0.00
0.00
0.00
149
201-H1
2.85
197.58
3.99
150
201-H2
3.18
220.85
4.46
151
NHT CHARGE
3,643.12
152
301-H1
10.46
725.12
14.65
153
301-H2
5.21
361.41
7.30
154
301-H3
3.19
221.18
4.47
155
211-H1
0.46
32.04
0.65
156
211-H2
0.92
63.94
1.29
157
KERO-UNIBON (V17)
1.38
95.98
1.94
158 KERO-UNIBON CHARGE
2,740.47
159 SGCU-V14 (412-FR-37)
3.30
228.77
4.62
160
*940-B4
4.18
290.13
5.86
161
*940-B5
2.09
145.06
2.93
162
*940-B6
2.09
145.06
2.93
163
**940-B4
488.65
17.67
67.01
31.71
164
**940-B5
244.32
8.84
33.51
15.86
165
**940-B6
244.32
8.84
33.51
15.86
166
Amine Unit V12
0.25
17.02
0.34
167
MEROX UNIT
3,384.76
168
169
Total (kg/day):
10,814.9
35.3
4,939.0
160.5

CO
333.07
0.00
31.93
35.69

NMTOC
and/or TOC
14.16
0.00
1.36
1.52

117.19
58.41
35.75
5.18
10.33
15.51

4.98
2.48
1.52
0.22
0.44
0.66

36.97
46.89
23.44
23.44
5.00
2.50
2.50
2.75

1.57
1.99
1.00
1.00
1.80
0.90
0.90
0.12

786.6

36.6

170
Total (ng/J):
171
172 NOTES: Sources 103-H1/H2/H3 and 940-B4/B5/B6 use both fuel oil and fuel gas.
173 Also, normally, only two of the sources, 940-B4/B5/B6 (boilers), are operated at the same time.
174
175 * Fuel Gas Operation
** Based on Actual Sulfur Content of Fuel Oil
176
177
178
179
180
181
182
183
184
185
186
187
188
189

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191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209

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