Anda di halaman 1dari 3

ALTERNATE SEMESTER Unit No. Topics Lecture No.

1 Sub-topics to be covered Introduction Classification Characteristics Distillation of crude oil and petroleum composition Calorific value Determination of calorific value, Combustion and its calculations Analysis of coal- proximate Ultimate analysis, Flash point Octane number, cetane number Enthalpy of formation Enthalpy of neutralization Enthalpy of combustion Hesss law of constant heat summation and its application, bond energy Introduction Types of solids Types of crystals Elements of symmetry No. of atoms per unit cell Bravice lattice Different crystal structure Structures- AB, AB2, A2B type Braggs equation, diamond, graphite Fullurene Conductance and its types Variation of conductance with dilution Theoritical aspect of electrolysis Galvanic cell, Single electrode potential, Nernst equation ECS and its applications, types of instrumental titrations Conductometry and applications, pHmetry, potentiometry Introduction, dry theory Wet theory, acid theory, types Factors, prevention Introduction, classification Physical properties Types of polymerization Copolymers, vulcanization, PVC, polyurethane, PAN, PET, polyamides Polyethylene, polypropylene, Resins (phenol-formaldehyde), polymethylmethacrylate, References

2 I

FUELS AND 3 THERMOCHEMISTRY 4 5 6 7

3-7

8 9

II

SOLID STATE

10

1,2, 10

11 12 III ELECTROCHEMICAL CELLS 13 14 15 16 17 18 19 20 21 V POLYMERS 22

1-7,10

IV

CORROSION

3-7

3-7,11

23

24

25 VI ORGANIC CHEMISTRY 26 27 28

29 30 31 32 33

Inductive effect Electromeric effect Resonance Hyperconjugation Types of fission Reactive intermediates Carbonium ion Carbanions Free radicals Types of organic reactions Aliphatic nucleophilic substitution-SN1 and SN2, stereochemistry Electrophilic substitution with energy profile- Halogenation Nitration Sulphonation Friedel craft reaction (comparison also) Addition reactions electrophilic and nucleophilic Elimination- E1 and E2 Elimination vs. substitution Baeyer Villiger oxidation Pinacol- pinacolone rearrangement Rate of reaction and rate constant Factors affecting rate of a reaction Order and molecularity of a reaction

8,9,13,14

34 VII CHEMICAL KINETICS 35

36 37 38 39 VIII NANOCHEMISTRY 40

Rate expression for first order, second order and third order reaction Methods of determining order of a 1-7, 10 reaction Steady state approximation Concept of activation energy and energy barrier Limdemann theory of unimolecular reaction Kinetics of complex reactions Introduction Methods of preparation 12 Application areas

S.No. 1

Title Principles of Physical Chemistry

Author B.R .Puri, L.R. Sharma and M.S. Pathania B.S. Bahl, G.D. Tuli and Arun Bahl Jain & Jain Gurtu and Singhal Shashi Chawla Sunita Rattan Mani, Mishra & Singhal Arun Bahl & B.S. Bahl Morrison & Boyd K.L.Kapoor Gwariker, Viswanathan & Sreedhar Sulbha K. Kulkarni O.P.Agarwal Singhal & Singhal

Publisher Vishal Publishing Co.

2 3 4 5 6 7 8 9 10. 11. 12. 13. 14.

Essentials of Physical Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry Engineering Chemistry A Text Book of Organic Chemistry Organic chemistry Physical Chemistry Vol I, III & IV Polymer Chemistry Nanotechnology: Principles and Practices Reaction Mechanism Pharmaceutical Chemistry- II

S. Chand & Co. Ltd. Dhanpat Rai Pragati Prakashan Dhanpat Rai & Company Katson Cengage Learning S. Chand & Co. Ltd. Pearson Education MacMillon New Age International Ltd. Capital Dhanpat Rai Pragati