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Petroleum refining

Generally, crude petroleum is heated and changed into a gas. The hot gases are passed into the bottom of a distillation column and become cooler as they move up the height of the column. As the gases cool below their boiling point, they condense into a liquid. The liquids are then drawn off the distilling column at specific heights, ranging from heavy resids at the bottom, raw diesel fuels in the mid-sections, and raw gasoline at the top. These raw fractions are then processed further to make several different finished products. Although all fractions of petroleum find uses, the greatest demand is for gasoline. One barrel of crude petroleum contains only 30-40% gasoline. Transportation demands require that over 50% of the crude oil be "converted" into gasoline. To meet this demand some petroleum fractions must be converted to gasoline. This may be done by Cracking breaking down large molecules of heavy heating oil and resids; Reforming changing molecular structures of low quality gasoline molecules; and Isomerization rearranging the atoms in a molecule so that the product has the same chemical formula but has a different structure, such as converting normal butane to isobutene. Generally, the simplest refineries consist of crude, vacuum, reforming and some hydrotreating capacity. The next level of complexity adds cat cracking and some additional hydrotreating. The most complex refineries add coking, more hydrotreatingand hydrocracking. Refining separates crude oil into components used for a variety of purposes, from high-performance fuels to plastics.

The Facts About Crude Oil

The refining process begins with crude oil. Crude oil is unrefined liquid petroleum, which ranges in color from yellow to black, and may have a paraffin, asphalt or mixed base. Crude oil is composed of thousands of different chemical compounds called hydrocarbons, all with different boiling points. For example, a typical crude oil may begin to boil at 104 F to produce petroleum gas used for heating and making plastics, and finish boiling at greater than 1112 F to produce residuals such as petroleum coke, asphalt and tar. Crude oil is generally described as sweet or sour according to its sulfur content, and heavy or light according to its API Gravity. The API Gravity index is a relative measure of weight-the lower the number, the heavier the material; the higher the number, the lighter the material. While there are no exacting definitions for these types of crudes, a general rule of thumb is: A heavy crude is less than 30API, while a light crude is greater than 30API. If crude contains a sizable amount of sulfur or sulfur compounds, it is called sour crude; if it has little to no sulfur, it is sweet crude. Sour crude may contain 1%5% sulfur content, while sweet crudes will have less than 1% sulfur content.

Refining Process Definitions Coker Unit: processes vacuum resid, which is heated to over 900 F and put into the coke drums, where it undergoes thermal cracking as the oil decomposes under the extreme heat. Products include butane and lighter material, naphtha for Reforming, turbine and diesel fuel, gas oil for Cat Cracking, and fuel grade petroleum coke. Reformer Unit: using heat, catalyst and moderate pressure, the reformer changes the molecular structure of crude and coker naphthas to produce a high octane primary gasoline blend stock called reformate. Alkylation Unit: uses acid catalyst to combine small molecules into larger ones collectively called alkylate, which has a high octane and is the cleanest burning of the gasoline blendstocks. Fluid Catalytic Cracking Unit: uses heat and catalyst to break or crack large gas oil molecules into a range of smaller ones, specifically gasoline, low quality diesel stocks, and a residual oil called slurry (fuel oil). Desulfurization Unit: a device used to remove sulfur from petroleum oil. Hydrotreating: removes impurities by using hydrogen to bind with sulfur and nitrogen. Hydrocracking: breaks or cracks diesel stock material into gasoline blending stocks using heat, catalyst and hydrogen under very high pressure. Isomerization: rearranges the atoms in a molecule so that the product has the same chemical formula but has a different structure, such as converting normal butane to isobutane.

6 Major Refinery Outputs

The most important refinery product is motor gasoline, a blend of hydrocarbons with boiling ranges from ambient temperatures to about 400 F. The important qualities for gasoline are octane number (antiknock), volatility (starting and vapor lock), and vapor pressure (environmental control). Additives are often used to enhance performance and provide protection against oxidation and rust formation. Kerosene is a refined middle-distillate petroleum product that finds considerable use as a jet fuel and around the world in cooking and space heating. When used as a jet fuel, some of the critical qualities are freeze point, flash point, and smoke point. Commercial jet fuel has a boiling range of about 375525 F, and military jet fuel 130-550 F. Kerosene, with less-critical specifications, is used for lighting, heating, solvents, and blending into diesel fuel. Liquified petroleum gas (LPG) consists principally of propane and butane and is produced for use as fuel and is an intermediate material in the manufacture of petrochemicals. The important specifications for proper performance include vapor pressure and control of contaminants. Distillate fuels such as diesel fuels and domestic heating oils have boiling ranges of about 400-700 F. The desirable qualities required for distillate fuels include controlled flash and pour points, clean burning, no deposit formation in storage tanks, and a proper diesel fuel cetane rating for good starting and combustion. Residual fuels are heavier oils, known as No. 5 and No. 6 fuel oils, that remain after the distillate fuel oils and lighter hydrocarbons are distilled away in refinery operations. Many marine vessels, power plants, commercial buildings and industrial facilities use residual fuels or combinations of residual and distillate fuels for heating and processing. The two most critical specifications of residual fuels are viscosity and low sulfur content for environmental control. A variety of solvents, whose boiling points and hydrocarbon composition are closely controlled, are produced in refineries. These include benzene, toluene, and xylene. Petrochemicals are products derived from crude oil refining, such as ethylene, propylene, butylene, and isobutylene, that are primarily intended for use as chemical feedstocks in the production of plastics, synthetic fibers, synthetic rubbers, and other products. Lubricants are produced in special refining processes. Additives such as demulsifiers, antioxidants, and viscosity improvers are blended into the base stocks to provide the characteristics required for motor oils, industrial greases, lubricants, and cutting oils. The most critical quality for lubricating-oil base stock is a high viscosity index, which provides for greater consistency under varying temperatures.

Coke is a residue high in carbon content and low in hydrogen that is the final product of thermal decomposition in the condensation process in cracking. It is almost pure carbon with a variety of uses from electrodes to charcoal briquets. Asphalt is dark brown-to-black cement-like material obtained by petroleum processing and containing bitumens as the predominant component. It used primarily for road construction and roofing materials, and thus must be inert to most chemicals and weather conditions.