SAMPLE PAPER-I ClassXII Chemistry Time :3 Hrs.

General Instructions : 1. 2. 3. 4. 5. 6. 1. All question are compulsory. Questions no. 1 to 8 are very short answer type questions and carry 1 mark each. Question no. 9 to 18 are short answer type question and carry 2 marks each. Question no. 19 to 27 are short answer question of 3 marks each. Question no. 28 to 30 are long answer question of 5 marks each. Use of log table if necessary : calculators are not allowed. Write the structure of : 4-Mehylpent 3 en 2 one. 2. 3. 4. 5. Name the monomer of PHBV. what is meant by isoelectric point ? Why are liquid propellants fevoured over solid propellants ? Give IUPAC name of linkage isomer of [Pt (NH3)3 NO2] Cl. Explain the mechanism of acidic dehydration of ethyl alcohol Give one example of water in oil emulsion. How can you convert amide into amine having same carbon atoms as starting compound ? 9. Analysis show that nickel oxide has formula Ni0.98 O1.00. . What fractions of nickel exist as NI ion and Ni3+ion.
2+

M.M. 70

6. 7. 8.

10. 11.

Calculate the molarity of KI if density of solution is 1.202 g/ml and it is 20% by mass. There is a rection between NO2 and CO to from CO2 & NO NO2(g)+ CO(g) and rate law Rate = K[NO2] . find the mechanism of reaction
2

NO(g)+CO2 (g)

12.

Give resons for the following : (a) (b) Transition metals have high enthalpies of atomization. Among the lanthanoids, Ce (III) is easily oxidised to Ce(iv).

13.

How would you account for the following : (a) (b) [Ti (H2O6)] is coloured while [Sc(H2O)6]
3+ 3+

is colourless.
2

NI (CO)4 posses tetrahedral geometry while [NI (CN)4] is square planar. (b) BHC

14. 15.

Give uses of (a) DDT

What is a step growth polymer ? Which of the following is a step growth polymer : P.V.C. Terylene, Teflon.

16.

(a) (b)

What is tincture of lodine ? what is its use ? Which forces are involved in holding its drugs to the active sites of enzymes ?

17.

Name the stoichiometric defect, which (a) (b) Decreases the density of solid. Do not effect the density of solid.

18.

Write the formula of main product formed in the following chemical section Na CH3 Br+AgF (i) (CH3)2 CHCl dry ether (ii) Estimate the b.p of a solution of 25.0 g urea (NH2 CO NH2) plus 25.0 g of thiourea (NH2CSNH2) in 500 g of chloroform. the b.p of pure chloroform is 61.2 C Kb of Chloroform =3.63 Km .
-1 o

19.

20.

(a) (b)

Distinguish between rate of reaction and rate constant.

The activation energy of a reaction is zero. Will the rate of reaction depend upon temperature ? Give reason.

21.

Define

(a) (c)

Peptization

(b)

Electrophoresis

Brownian Movement

22.

(a)

Give the reaction, which take place in b last furnace during the extraction of iron from halmatite.

(b)

Why is zinc and not copper used for recovery of metallic silver from its cyanide complex [Ag (CN) ] ?
2

23.

Give reason (a) (b) (c) Ammonia is a good complexing agent. PCl5 is ionic in solid state. SO3 has zero dipole moment. Write down the chemical equation of preparation of KMnO4 From Pyrolusite ore. What will be the main products when KI react with KMnO4 medium. in acidic and basic

24.

(a) (b)

25.

An organic compound (A) having molecular formula (C6H6O) gives a characteristic colour with aqueous FeCl3 solution. A on treatment with CO2 and NaOH at 400K under pressure gives B. Which on acidification gives a compound (C)2 reacts with acetyl chloride to give (D) Which is a popular pain killer. identify A,C, and D.

26.

(a) (b)

Alkyl amine are stronger bases than arylamines why ? Illulustrate the following with example (i) (ii) Hoffmann bromamide reaction Coupling reaction.

27. (b) 28. (a)

(a)

Enumerate the structural difference between DNA & RNA

(2+1)

Write down one example of non-reducing sugar Calculate the Equilibrium constant for the reaction Cu(s) +2Ag+ (aq)
0 o

Cu

2+ (aq)

+2Ag (S).

Given that E0 Ag+ /ag=0.80V E0 cu++/cu= +0.34 v

Write cell representation also. (b) Write short note on fuel cell. OR (a) Calculate emf of the following cell at 298K Fe /Fe
(s) 2+ (0.1m)

II Ag+
(0.1m)

/Ag(s)
0 Ag+/Ag

Given E = 0.44V E Fe2+/Fe (b) 29. (a) (b)

= 0.80 v

Define conductivity and molar conductivity for the solution of an electrolyte What are interhalogen compounds ? Why are they more reactive than their parent halogens ? Complete the following equations (i) (ii) Xe F6+H2O NaClO3+SO2

1+1

(2 +3=5)

(iii)

CaOCl2 + HCl OR

(a)

Draw the structure of following (i) (II) H2SO5 HClO4 .

(b)

Arrange the following in the increasing order of chanciest (i) (ii) (iii) HClO, F2, PH3, HClO3, Cl2, NH3, HClO2, Br2, SbH3, HClO4 I2 AsH3 (Acidic) (Bond dissociation Energy) (Abric Chonoctu)

30.

(a)

Write chemical equations for the following conversions : (not more than 2 steps) (i) (ii) (iii) Ethyl. benzene to benzene Acetaidehyde to butane-1, 3 diol Acetone to propane

(b)

Distinguish the following pentanone -2 (i) (ii) Pentanone - 1 and pentanone - 2 formic acid and acetic acid OR

Identify the unknown organic compounds (A) and (E) in the following series of chemical reactions. (i) (ii) A+B CH1C6H5 (i) O3 (ii) Zn/H2O Dil NaOH (i) O3 (ii) Zn/H2O H2/Ni A+B C+H 2O A+D E

(iii) (iv)

C D

SAMPLE PARER-1 Class XII MARKING SCHEME CHEMISTRY

1. HC3C=CHCCH3 CH3 2. o 1/2+1/2

Hyd roxy butyric acid Hydroxy valeric acid

3.

The pH at which a particular aminoacid does not migrate to any electrode under the influence of an electric field. 1 1 1

4. 5.

Biliquid propellents provide greater thrust than solid propellants Linkage isomer [Pt(NH3)3 ONO] Cl Triammine nitrito o platinum (II)
H H+

CH3CH2OH

C
H

+ CH2OH
H

1/2+1/2

H20 CH2=CH2

7. 8. 9.

Cold cream or butter or any other example

CH3 C NH2 LiAlH4 O

1 1

CH3CH2NH2

Let Ni2+ be x Ni3+ will be 98-x 2x+3(98-x) = 200 x=94

% of Ni 2+ = 94/98x100 = 96% % of Ni 3+ = 4% 10. M=

% by mass x d x1000 Molecular Wt. X 100 20 x 1.202 x 10 (39+127) 240.4 = 166 = 1.44 M (Slow step) (Fast step) (1+1)

1/2

1/2+1/2 1/2+1/2

11.

NO2+ NO2 NO3+ CO

NO+NO3 CO2+NO2

or any other correct mechanism 12. (a) due to strong interatomic forces (Metallic and covalent bonds.)
4+

1/2+1/2

(b)

C : [Xe] 4f1 5d1 6S2

58 58

Ce: [Xe] 4f1

58

Ce: [Xe]

13.

(a)

Due to presence of one unpaired e in [Ti(H2O)6]

3+

(1/2+1/2)

(b)

Ni in [Ni(CO)4] is sp hybridised & [NI(CN)4] is dsp2 bybridised. Powerful insecticide Agricultural pesticides

2-

(1/2+1/2)

14.

(a) (b)

1 1 1/2 1/2

15.

Correct definition Terylene

16.

(a) (b)

I2 dissolved in alcohol used as antiseptic H-bonding, ionic bonding, bipole-dipole interaction or vander waal's interaction (any two) +

17.

(a) (b)

Schottky defects Frenkel defects CH3CHCHCH3 CH3 CH3 (II) CH3F

18.

(i)

19.

Moles of Total moles

urea

= = = =

25/60 = 0.42 mol 25/76 = 0.33 mol (0.42 + 0.33) moles 0.75 mol

Moles of theonea

Moles of solute x 1000 Molality = Mass of solvent(g) = 0.75 x 1000 500 =1.5

Tb = = = Tb = =

KbM 3.63 x 1.5 5.445 k = 5.445 o c 5.445 o C + Tb 5.445 o C + 61.2 66.645 o C

1+1
- Ea/RT - O/RT

20.

(a) (b)

Any two points Does not depend K = = = Ae

Ae A

1 1+1+1

21.

Correct definition of each

22.

(a)

C+02 CO2 + C CaCO3

Co2 CO Ca O +O2 CaSIO3 2FeO+CO2 Fe+CO

Ca O + SiO2 Fe2 O3+ CO Fe O + C (b) solution.

Zn s more electropositive than silver and therefore Zn displaces silver from its 1

23.

(a) (b)

Because of presence of ione pair of electron on nitrogen In solid state PCl3 exists as [PCl4]+[PCl6 ]

(c)

SO3 has trigonal planar structure

O S
120

24.

(a)

MnO4 + KOH + O2 2K2 MnO4 + Cl2

K2MnO4+ 2H2O 2KMnO4 +2KCl

1 1

(b)

In acidic medium + KI+ KMnO4

H Alkalinemeau OH COONa

I2
KIO 3 OH COONa H3O (B) (C) COCOH3 COOH H CH3 COCl Aspirin (D)
+

25.
(A)

CO2 +NaOH 400 K HIGH P

(1+1+1)

26.

In Alkyl, amine

NH2

NH2 +

I effect

(1/2+1/2)

Ring with draw (I effect) lone paing 'N' (b) (i) CH3 CNH2 + Br2 +4KOH
O

CH3 NH2 + K2CO3 + 2KBr +2H2O (1) OH OH N N OH

(ii) 27. (a) (b)

+ N

N+ Cl +

Any two point differences sucrose or any other example

2 1

(a) Log K = nE

o 0.0591

28.
= 0.92 0.0591

[E

=E -E
cell
R

0 L

0.46 V

= 15.5668 K = ANTILOG 15.5668 = 3.688 X 10 15 Cell representation Cu(s)/Cu+1

(1m)

II Ag+

/Ag(s) (1m)

(b)

for correct answer

0.591 log [Ag +]2 2 0.1 .0591 log 1 2 (0.1) 2 [Fe 2+]

2 OR

Ecell = E cell Ecell = E cell

= 1.24 v - 0.0295 = 1.2105 v (b) 29. (a) (b) For Correct Definitions 1+1

Compound containing two or more hologens. more reactive due to difference in electro negativity (i) (ii) XeF6 + H2O CaOCl2 + HCl XeO3 +6HF CaCl2 + H2O+Cl2
O

1 1 1

(III) NaClO3 +SO2 (a)

2ClO2+Na2SO4 OR

O S OH

O
Cl

(1+1)

(b)

(i) (II)

HClO < HClO2 < HClO3 <HClO4 I2 < Br2 < F2 < Cl2

(III) 3bH3 < AsH3 < PH3 <NH3